Computational Modelling — In Situ Growth of Conductive Metal-Organic Framework onto Cu2O for Highly Selective and Humidity-Independent Hydrogen Sulfide Detection in Food Quality Assessment

Measurement evidence

Computational Modelling

In Situ Growth of Conductive Metal-Organic Framework onto Cu2O for Highly Selective and Humidity-Independent Hydrogen Sulfide Detection in Food Quality Assessment · Zhang F., Jiao C., Shang Y. et al. · ACS Sensors · 2024 · 1310-1320

1 measurement group · 7 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Spin-polarised DFT in VASP 6.1.0; PBE GGA; DFT-D3; cutoff 420 eV

Cu2O@CuHHTP-3 powder · Powder

H2O adsorption configurations and adsorption energies on Cu2O and CuHHTP; Cu2O (111) slab and MOF molecule model.

Atmosphere
computational vacuum model
Geometry
Cu2O(111) model and CuHHTP molecule model
Context
Mechanistic comparison of Cu2O vs CuHHTP water adsorption
Measurement source
p002 / S-1 · Computational details
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
DFT plane-wave cutoff energy420 eVText
Exact Reported
p002 / S-1 · Computational details
H2O-surface distance on Cu2O1.976 AText
Exact Reported
p008 / 1317 · Results and Discussion · Figure 8a
H2O-surface distance on CuHHTP2.081 AText
Exact Reported
p008 / 1317 · Results and Discussion · Figure 8a
H2O adsorption energy on Cu2O-3.34 eVText
Exact Reported
p008 / 1317 · Results and Discussion · Figure 8a
H2O adsorption energy on CuHHTP0.27 eVText
Exact Reported
p008 / 1317 · Results and Discussion · Figure 8a
Cu2O work function used in band alignment4.48 eVText
Exact Reported
p008 / 1317 · Mechanism · Figure 7a
CuHHTP work function used in band alignment4.52 eVText
Exact Reported
p008 / 1317 · Mechanism · Figure 7a