Spectroscopy — In Situ Growth of Conductive Metal-Organic Framework onto Cu2O for Highly Selective and Humidity-Independent Hydrogen Sulfide Detection in Food Quality Assessment

Measurement evidence

Spectroscopy

In Situ Growth of Conductive Metal-Organic Framework onto Cu2O for Highly Selective and Humidity-Independent Hydrogen Sulfide Detection in Food Quality Assessment · Zhang F., Jiao C., Shang Y. et al. · ACS Sensors · 2024 · 1310-1320

3 measurement groups · 9 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

EDX elemental mapping and integrated STEM-EDX spectrum

Cu2O@CuHHTP-3 powder · Powder

Elemental composition after Cu2O cubes reacted with HHTP and Cu2+.

Geometry
single composite particle/cube
Context
Composite Cu2O@CuHHTP
Measurement source
p004 / 1313 · Results and Discussion · Figure 3a,b
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
EDX atomic percent C45 atomic %Figure Axis
Rounded Reported
p004 / 1313 · Results and Discussion · Figure 3b
EDX atomic percent Cu44.02 atomic %Figure Axis
Rounded Reported
p004 / 1313 · Results and Discussion · Figure 3b
EDX atomic percent O10.98 atomic %Figure Axis
Rounded Reported
p004 / 1313 · Results and Discussion · Figure 3b

Post-H2S XPS, Cu-AES, SEM-EDX, XRD, and FTIR

Cu2O@CuHHTP-3 interdigital electrode sensor · Electrode

Cu2O@CuHHTP exposed to 50 ppm H2S for 100 s at room temperature; powder scraped for immediate XPS testing.

Temperature
298
Atmosphere
50 ppm H2S exposure, then characterisation
Geometry
sensor powder from electrode/test vessel
Context
Target composite sensor after H2S sensing
Measurement source
p003 / S-2 · XPS measurement
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Sulfur after H2S sensingNo S element detected by XPS/EDXQualitative
Qualitative
p007 / 1316 · Mechanism · Figures S16-S17
Copper sulfide formation after H2S sensingNo Cu-based sulfides generatedQualitative
Qualitative
p007 / 1316 · Mechanism · Figures S16-S19

Cu 2p XPS

Cu2O@CuHHTP-3 powder · Powder

Cu valence states in Cu2O@CuHHTP after redox-etching process compared with Cu2O.

Geometry
powder sample
Context
Composite vs Cu2O control
Measurement source
p004 / 1313 · Results and Discussion · Figure 3c
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Cu2+ 2p1/2 XPS peak953.5 eVText
Exact Reported
p004 / 1313 · Results and Discussion · Figure 3c
Cu2+ 2p3/2 XPS peak934.3 eVText
Exact Reported
p004 / 1313 · Results and Discussion · Figure 3c
Cu+ 2p1/2 XPS peak952.0 eVText
Exact Reported
p004 / 1313 · Results and Discussion · Figure 3c
Cu+ 2p3/2 XPS peak932.1 eVText
Exact Reported
p004 / 1313 · Results and Discussion · Figure 3c