An Y., Tian Y., Li Y. et al. · Chemical Engineering Journal · 2020 · 125843
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
Li@NOCA@CF enables stable carbonate-electrolyte Li symmetric cells and improved LNMO/NCM full-cell cycling.
Caveat: LCO/LMO/LFP full-cell data are supplied only as SI figure captions without numeric text values in the text layer.
11 · 3.4. Electrochemical performance in carbonate-based electrolyte · Fig. 7 · Linked to 8 structured results
NOCA@CF also functions as a binder-free self-standing lithium-ion battery anode with high reversible capacity, rate capability, and long-term cycling stability.
Caveat: SI provides text-reported values but no rendered SI pages were supplied for visual verification.
rendered SI text · Figs. S17-S20 narrative · Figs. S17-S20 · Linked to 3 structured results
The rendered SI comparison tables contain apparent source-label inconsistencies in the this-work Li symmetric rows, so table-derived Li@NOCA@CF comparison values should be used with their raw labels and caveats rather than as independent electrolyte identity proof.
Caveat: Table S2 and S3 this-work rows visibly print Zn@NOCA@CF; Table S3 also prints 1M LiTFSI DD despite being headed as carbonate electrolyte.
SI p26; SI p28 · Tables S2-S3 · Table S2; Table S3 · Linked to 2 structured results
The paper asserts high electronic conductivity for NOCA@CF but does not report a direct electrical conductivity measurement.
Caveat: Conductivity is inferred from graphitization and electrochemical performance rather than measured as a transport value.
7 · 3.1. Synthesis and characterization of NOCA@CF · Fig. 2d · Linked to 1 structured result
NOCA@CF retains the nanorod morphology of the ZIF-8@CF precursor and becomes a porous N/O-doped carbon nanosheet/nanorod array.
6 · 3.1. Synthesis and characterization of NOCA@CF · Fig. 1d-m · Linked to 4 structured results
NOCA@CF stabilizes Li plating/stripping in ether electrolyte, yielding higher CE and longer symmetric-cell cycling than CF.
10 · 3.3. Electrochemical performance in ether-based electrolyte · Fig. 5; Fig. 6 · Linked to 7 structured results
NOCA@CF improves aqueous Zn plating reversibility and suppresses Zn dendrites relative to bare CF.
Caveat: Some morphology support is visual/qualitative.
9 · 3.2. Electrochemical performance of NOCA@CF for Zn metal anode · Fig. 3; Fig. 4 · Linked to 7 structured results
Vacuum distillation converts ZIF-8@CF into NOCA@CF while evaporating/recycling Zn, avoiding additional acid etching and helping carbonization/graphitization.
Caveat: Main text contains a 12 h versus 24 h inconsistency for ZIF-8 growth time.
6 · 3.1. Synthesis and characterization of NOCA@CF · Scheme 1 · Linked to 2 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| Copper foam | Cu | 3D · PristineCommercial porous copper foam current collector used as control substrate. | 5 · 2.5. Electrochemical measurement |
| Li deposited on NOCA@CF | Li@NOCA@CF | 3D · CompositeLithium metal anode hosted by the MOF-derived NOCA@CF scaffold. | 3 · Introduction |
| Lithium manganese oxide cathode | LiMn2O4 | 3D · PristineSpinel LiMn2O4 cathode material for aqueous Zn full-cell testing. | 4 · 2.3. Zn||LiMn2O4 full cells |
| N/O dual-doped carbon array grown on copper foam | N/O-doped porous carbon on Cu foam | 3D · DerivedMOF-derived nanorod/nanosheet porous carbon array supported by conductive copper foam. | 4 · 2.2. N/O dual-doped carbon array grown on Cu foam · Scheme 2 |
| ZIF-8 grown on copper foamBrowse family: ZIF-8 / Zn(mIm)₂ | Zn(mIm)2 on Cu foamZn · 2-methylimidazole | 3D · CompositeZIF-8 nanorod array precursor tightly grown on copper foam. | 3 · 2.1. ZIF-8 grown on Cu foam · Scheme 1; Fig. 1a-c |
| Zn deposited on NOCA@CF | Zn@NOCA@CF | 3D · CompositeZinc metal anode hosted by the MOF-derived NOCA@CF scaffold. | 3 · Introduction |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| CF controlresearch_0318__mat__mat_cf | Electrode · Pristine Control · Unknown | Cleaned commercial copper foam used without NOCA layer.Cu foam | 5 · 2.5. Electrochemical measurement · Fig. 3; Fig. 5 |
| Li@CF controlresearch_0318__mat__mat_cf | Electrode · Pristine Control · Composite | Lithium metal plated/stripped on bare copper foam.Cu foam | 5 · 2.5. Electrochemical measurement · Fig. 6; Fig. 7 |
| Li@NOCA@CFresearch_0318__mat__mat_li_noca_cf | Electrode · Target Sample · Composite | Lithium metal plated/stripped on NOCA@CF in ether or carbonate electrolyte.NOCA@CF | 5 · 2.5. Electrochemical measurement · Fig. 6; Fig. 7 |
| LiMn2O4 cathoderesearch_0318__mat__mat_lmn | Powder · Paper Level Unspecified · Unknown | Synthesised LiMn2O4 powder blended into cathode for Zn full cells. | 4 · 2.3. Zn||LiMn2O4 full cells |
| NOCA@CFresearch_0318__mat__mat_noca_cf | Electrode · Target Sample · Derived Carbon | Vacuum carbonised ZIF-8@CF, freestanding flexible electrode.Cu foam | 4 · 2.2. N/O dual-doped carbon array grown on Cu foam · Fig. 1d-m |
| ZIF-8@CF precursorresearch_0318__mat__mat_zif8_cf | Electrode · Composite Component · Composite | Solvothermal ZIF-8 nanorod array grown on cleaned copper foam.Cu foam | 3 · 2.1. ZIF-8 grown on Cu foam · Fig. 1a-c |
| Zn@CF controlresearch_0318__mat__mat_cf | Electrode · Pristine Control · Composite | Zinc metal plated/stripped on bare copper foam.Cu foam | 5 · 2.5. Electrochemical measurement · Fig. 4 |
| Zn@NOCA@CFresearch_0318__mat__mat_zn_noca_cf | Electrode · Target Sample · Composite | Zinc metal plated/stripped on NOCA@CF in aqueous Zn cells.NOCA@CF | 5 · 2.5. Electrochemical measurement · Fig. 4 |