Electrochemistry Application — Heteroatom-doped 3D porous carbon architectures for highly stable aqueous zinc metal batteries and non-aqueous lithium metal batteries

22 measurement groups · 78 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Li plating/stripping Coulombic efficiency in carbonate electrolyte

NOCA@CF · Electrode

NOCA@CF or Cu working electrode, Li foil counter/reference; 1 M LiPF6 in carbonate cosolvent.

Atmosphere: carbonate electrolyte
Geometry: 2032 coin half-cell
Context: Target NOCA@CF versus Cu/CF control
Measurement source: 5 · 2.5. Electrochemical measurement · Fig. 7a-b

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Stable Li Coulombic-efficiency duration on NOCA@CF in carbonate electrolyte at 1 mA cm-2	relatively stable over 300 cycles	—	over	Text Rounded Reported	10 · 3.4. Electrochemical performance in carbonate-based electrolyte · Fig. 7a
Stable Li Coulombic-efficiency duration on NOCA@CF in carbonate electrolyte at 2 mA cm-2	stable up to 250 cycles	—	up to	Text Rounded Reported	10 · 3.4. Electrochemical performance in carbonate-based electrolyte · Fig. 7b

Li nucleation overpotential from voltage profile in carbonate electrolyte

NOCA@CF · Electrode

CF and NOCA@CF at 1 mA cm-2 in carbonate-based electrolyte for Li metal anode.

Atmosphere: carbonate electrolyte
Geometry: half cell
Context: NOCA@CF versus CF control
Measurement source: SI p13 · Fig. S12 caption · Fig. S12

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Li nucleation overpotential on CF in carbonate electrolyte	22.6 mV	—	—	Figure Axis Rounded Reported	SI p13 · Fig. S12 annotation · Fig. S12a
Li nucleation overpotential on NOCA@CF in carbonate electrolyteMarked as a best value within this paper	8.4 mV	—	—	Figure Axis Rounded Reported	SI p13 · Fig. S12 annotation · Fig. S12b

Li||Li symmetric-cell cycling in carbonate electrolyte

Li@NOCA@CF · Electrode

Li@NOCA@CF or Li@CF anodes at 1 mA cm-2 in carbonate-based electrolyte.

Atmosphere: carbonate electrolyte
Geometry: symmetric cell
Context: Target Li@NOCA@CF versus Li@CF control
Measurement source: 9 · Fig. 7 caption · Fig. 7e

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Li\|\|Li symmetric cycling life with Li@NOCA@CF in carbonate electrolyte	stable cyclability up to 400 h	—	up to	Text Rounded Reported	11 · 3.4. Electrochemical performance in carbonate-based electrolyte · Fig. 7e

Li||Li carbonate symmetric-cell comparison table entry

Li@NOCA@CF · Electrode

This-work row in Table S3; table context is carbonate-based electrolyte, but the row is internally inconsistent and printed as Zn@NOCA@CF / 1M LiTFSI DD.

Atmosphere: carbonate electrolyte context; raw row says 1M LiTFSI DD
Geometry: symmetric cell
Context: This-work comparison-table value with source typo
Measurement source: SI p28 · Table S3 · Table S3

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
NOCA@CF carbonate-table cycle life at 1 mA cm-2 / 0.5 mAh cm-2	400 h	—	—	SI Table Rounded Reported	SI p28 · Table S3 · Table S3
NOCA@CF carbonate-table overpotential at 1 mA cm-2 / 0.5 mAh cm-2	~18 mV	—	—	SI Table Approximate	SI p28 · Table S3 · Table S3

Li plating/stripping Coulombic efficiency in ether electrolyte

NOCA@CF · Electrode

NOCA@CF or Cu working electrode, Li foil counter/reference; 1 M LiTFSI in DME/DOL.

Atmosphere: ether electrolyte
Geometry: 2032 coin half-cell
Context: Target NOCA@CF versus Cu/CF control
Measurement source: 5 · 2.5. Electrochemical measurement · Fig. 6a-b

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Li Coulombic-efficiency failure of CF in ether electrolyte at 1 mA cm-2	cell fails only after 145 cycles	—	after	Text Rounded Reported	10 · 3.3. Electrochemical performance in ether-based electrolyte · Fig. 6a
Li Coulombic efficiency on NOCA@CF in ether electrolyte at 1 mA cm-2Marked as a best value within this paper	98.2% even after 600 cycles	—	—	Text Exact Reported	10 · 3.3. Electrochemical performance in ether-based electrolyte · Fig. 6a
Li Coulombic efficiency on NOCA@CF in ether electrolyte at 2 mA cm-2	96.7% after 600 cycles	—	—	Text Exact Reported	10 · 3.3. Electrochemical performance in ether-based electrolyte · Fig. 6b

Li nucleation overpotential from voltage profile in ether electrolyte

NOCA@CF · Electrode

CF and NOCA@CF at 1 mA cm-2 in ether-based electrolyte for Li metal anode.

Atmosphere: ether electrolyte
Geometry: half cell
Context: NOCA@CF versus CF control
Measurement source: SI p12 · Fig. S11 caption · Fig. S11

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Li nucleation overpotential on CF in ether electrolyte	22.1 mV	—	—	Figure Axis Rounded Reported	SI p12 · Fig. S11 annotation · Fig. S11a
Li nucleation overpotential on NOCA@CF in ether electrolyteMarked as a best value within this paper	10.5 mV	—	—	Figure Axis Rounded Reported	SI p12 · Fig. S11 annotation · Fig. S11b

Li||Li symmetric-cell cycling and rate testing in ether electrolyte

Li@NOCA@CF · Electrode

Li@NOCA@CF or Li@CF symmetric cells in 1 M LiTFSI DME/DOL.

Atmosphere: ether electrolyte
Geometry: symmetric cell
Context: Target Li@NOCA@CF versus Li@CF control
Measurement source: 5 · 2.5. Electrochemical measurement · Fig. 6e-g

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Li@NOCA@CF Li\|\|Li rate-test overpotential at 10 mA cm-2	lower than 327.1 mV	—	—	Text Approximate	10 · 3.3. Electrochemical performance of NOCA@CF in Ether-Based electrolyte · Fig. 6f
Li@NOCA@CF Li\|\|Li rate-test overpotential at 1 mA cm-2	34.5 mV	—	—	Text Exact Reported	10 · 3.3. Electrochemical performance of NOCA@CF in Ether-Based electrolyte · Fig. 6f
Li@NOCA@CF Li\|\|Li rate-test overpotential at 2 mA cm-2	72.2 mV	—	—	Text Exact Reported	10 · 3.3. Electrochemical performance of NOCA@CF in Ether-Based electrolyte · Fig. 6f
Li@NOCA@CF Li\|\|Li rate-test overpotential at 3 mA cm-2	106.1 mV	—	—	Text Exact Reported	10 · 3.3. Electrochemical performance of NOCA@CF in Ether-Based electrolyte · Fig. 6f
Li@NOCA@CF Li\|\|Li rate-test overpotential at 4 mA cm-2	137.5 mV	—	—	Text Exact Reported	10 · 3.3. Electrochemical performance of NOCA@CF in Ether-Based electrolyte · Fig. 6f
Li@NOCA@CF Li\|\|Li rate-test overpotential at 5 mA cm-2	159.9 mV	—	—	Text Exact Reported	10 · 3.3. Electrochemical performance of NOCA@CF in Ether-Based electrolyte · Fig. 6f
Li@NOCA@CF Li\|\|Li rate-test overpotential at 6 mA cm-2	202.1 mV	—	—	Text Exact Reported	10 · 3.3. Electrochemical performance of NOCA@CF in Ether-Based electrolyte · Fig. 6f
Li@NOCA@CF Li\|\|Li rate-test overpotential at 7 mA cm-2	233.4 mV	—	—	Text Exact Reported	10 · 3.3. Electrochemical performance of NOCA@CF in Ether-Based electrolyte · Fig. 6f
Li@NOCA@CF Li\|\|Li rate-test overpotential at 8 mA cm-2	264.9 mV	—	—	Text Exact Reported	10 · 3.3. Electrochemical performance of NOCA@CF in Ether-Based electrolyte · Fig. 6f
Li@NOCA@CF Li\|\|Li rate-test overpotential at 9 mA cm-2	294.8 mV	—	—	Text Exact Reported	10 · 3.3. Electrochemical performance of NOCA@CF in Ether-Based electrolyte · Fig. 6f
Li\|\|Li symmetric instability with Li@CF in ether electrolyte at 1 mA cm-2	severe fluctuations after only 160 h	—	after only	Text Rounded Reported	10 · 3.3. Electrochemical performance in ether-based electrolyte · Fig. 6e
Li\|\|Li symmetric cycling life with Li@NOCA@CF in ether electrolyte at 10 mA cm-2	stable cycling property over 400 h	—	over	Text Rounded Reported	10 · 3.3. Electrochemical performance in ether-based electrolyte · Fig. 6g
Li\|\|Li symmetric cycling life with Li@NOCA@CF in ether electrolyte at 1 mA cm-2Marked as a best value within this paper	steady cycling even after 800 h	—	after	Text Rounded Reported	10 · 3.3. Electrochemical performance in ether-based electrolyte · Fig. 6e
Li@NOCA@CF symmetric-cell overpotential at 10 mA cm-2	lower than 327.1 mV	—	upper bound	Text Rounded Reported	10 · 3.3. Electrochemical performance in ether-based electrolyte · Fig. 6f

Li||Li ether symmetric-cell comparison table entry

Li@NOCA@CF · Electrode

This-work rows in Table S2 for NOCA@CF-based Li metal anode in 1 M LiTFSI DD electrolyte.

Atmosphere: 1 M LiTFSI in DOL+DME
Geometry: symmetric cell
Context: This-work comparison-table values
Measurement source: SI p26 · Table S2 · Table S2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Li@NOCA@CF ether-table cycle life at 10 mA cm-2 / 10 mAh cm-2	400 h	—	—	SI Table Rounded Reported	SI p26 · Table S2 · Table S2
Li@NOCA@CF ether-table cycle life at 1 mA cm-2 / 0.5 mAh cm-2	800 h	—	—	SI Table Rounded Reported	SI p26 · Table S2 · Table S2
Li@NOCA@CF ether-table overpotential at 10 mA cm-2 / 10 mAh cm-2	~185 mV	—	—	SI Table Approximate	SI p26 · Table S2 · Table S2
Li@NOCA@CF ether-table overpotential at 1 mA cm-2 / 0.5 mAh cm-2	~14 mV	—	—	SI Table Approximate	SI p26 · Table S2 · Table S2

Li||LiCoO2 (LCO) full-cell cycling

Li@NOCA@CF · Electrode

Li@NOCA@CF or Li@CF anode; LiCoO2 (LCO) cathode; carbonate electrolyte; 100 mA g-1; 3.0-4.3 V.

Atmosphere: carbonate electrolyte
Geometry: full cell
Context: Target Li@NOCA@CF versus Li@CF control
Measurement source: SI p15 · Fig. S14 caption · Fig. S14

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Li-LCO full-cell Li@CF capacity after failure	near 0 mAh g-1 after ~90 cycles	—	—	Visual Estimate Approximate	SI p15 · Fig. S14b visual read · Fig. S14b
Li-LCO full-cell capacity with Li@NOCA@CF after 200 cyclesMarked as a best value within this paper	~130 mAh g-1	—	—	Visual Estimate Approximate	SI p15 · Fig. S14b visual read · Fig. S14b

Li||LiFePO4 (LFP) full-cell cycling

Li@NOCA@CF · Electrode

Li@NOCA@CF or Li@CF anode; LiFePO4 (LFP) cathode; carbonate electrolyte; 100 mA g-1; 2.5-3.8 V.

Atmosphere: carbonate electrolyte
Geometry: full cell
Context: Target Li@NOCA@CF versus Li@CF control
Measurement source: SI p16 · Fig. S15 caption · Fig. S15

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Li-LFP full-cell Li@CF capacity after failure	near 0 mAh g-1 after ~110 cycles	—	—	Visual Estimate Approximate	SI p16 · Fig. S15b visual read · Fig. S15b
Li-LFP full-cell capacity with Li@NOCA@CF after 200 cyclesMarked as a best value within this paper	~100 mAh g-1	—	—	Visual Estimate Approximate	SI p16 · Fig. S15b visual read · Fig. S15b

Li||LiMn2O4 (LMO) full-cell cycling

Li@NOCA@CF · Electrode

Li@NOCA@CF or Li@CF anode; LiMn2O4 (LMO) cathode; carbonate electrolyte; 100 mA g-1; 3.0-4.3 V.

Atmosphere: carbonate electrolyte
Geometry: full cell
Context: Target Li@NOCA@CF versus Li@CF control
Measurement source: SI p17 · Fig. S16 caption · Fig. S16

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Li-LMO full-cell Li@CF capacity after failure	near 0 mAh g-1 after ~130 cycles	—	—	Visual Estimate Approximate	SI p17 · Fig. S16b visual read · Fig. S16b
Li-LMO full-cell capacity with Li@NOCA@CF after 250 cyclesMarked as a best value within this paper	~95 mAh g-1	—	—	Visual Estimate Approximate	SI p17 · Fig. S16b visual read · Fig. S16b

Li||LiNi0.5Mn1.5O4 full-cell cycling

Li@NOCA@CF · Electrode

Li@NOCA@CF or Li@CF anode; LNMO cathode; carbonate electrolyte; 100 mA g-1; 3.5-5 V.

Atmosphere: carbonate electrolyte
Geometry: full cell
Context: Target Li@NOCA@CF versus Li@CF control
Measurement source: 5 · 2.5. Electrochemical measurement · Fig. 7f-g

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Li-LNMO full-cell capacity retention with Li@NOCA@CFMarked as a best value within this paper	~92.77% capacity retention over 500 cycles	—	~	Text Approximate	11 · 3.4. Electrochemical performance in carbonate-based electrolyte · Fig. 7g

Li||LiNi0.8Co0.1Mn0.1O2 full-cell cycling

Li@NOCA@CF · Electrode

Li@NOCA@CF or Li@CF anode; NCM cathode; carbonate electrolyte; 100 mA g-1; 3.0-4.25 V.

Atmosphere: carbonate electrolyte
Geometry: full cell
Context: Target Li@NOCA@CF versus Li@CF control
Measurement source: 5 · 2.5. Electrochemical measurement · Fig. 7h-i

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Li-NCM full-cell capacity retention with Li@NOCA@CFMarked as a best value within this paper	~96.34% capacity retention after 200 cycles	—	~	Text Approximate	11 · 3.4. Electrochemical performance in carbonate-based electrolyte · Fig. 7i

Galvanostatic charge/discharge cycling of NOCA@CF as LIB anode

Galvanostatic cycling

NOCA@CF · Electrode

NOCA@CF anode tested at 500 mA g-1.

Geometry: NOCA@CF self-standing anode
Context: MOF-derived carbon electrode tested directly as LIB anode.
Measurement source: rendered SI text · Fig. S18 caption and SI narrative · Fig. S18

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
NOCA@CF LIB anode capacity after 200 cycles at 500 mA g-1Marked as a best value within this paper	1066 mAh g-1 even after 200 cycles	—	—	Text Exact Reported	rendered SI text · Supplementary narrative · Fig. S18
Initial Coulombic efficiency of NOCA@CF LIB anode	75.7 % ICE	—	—	Text Exact Reported	rendered SI text · Supplementary narrative · Fig. S18
Initial reversible capacity of NOCA@CF LIB anode at 500 mA g-1	1004 mAh g-1	—	—	Text Exact Reported	rendered SI text · Supplementary narrative · Fig. S18
NOCA@CF LIB anode capacity retention after 200 cycles at 500 mA g-1	95.1 %	—	—	Text Exact Reported	rendered SI text · Supplementary narrative · Fig. S18

Cyclic voltammetry of NOCA@CF as binder-free LIB anode

Voltammetry

NOCA@CF · Electrode

First five continuous CV profiles of NOCA@CF anode for lithium-ion batteries.

Geometry: NOCA@CF self-standing anode
Context: MOF-derived carbon electrode tested directly as LIB anode.
Measurement source: rendered SI text · Fig. S17 caption and SI narrative · Fig. S17

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
NOCA@CF LIB CV anodic/cathodic peak window	between 1.5 V and 0.01 V	—	—	Text Range	rendered SI text · Supplementary narrative · Fig. S17

Long-term cycling of NOCA@CF as LIB anode

NOCA@CF · Electrode

NOCA@CF anode cycled at 10 A g-1 for about 3000 cycles.

Geometry: NOCA@CF self-standing anode
Context: MOF-derived carbon electrode tested directly as LIB anode.
Measurement source: rendered SI text · Fig. S20 caption and SI narrative · Fig. S20

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
NOCA@CF LIB long-term capacity around 3000 cycles at 10 A g-1Marked as a best value within this paper	423 mAh g-1 around 3000 cycles	—	—	Text Rounded Reported	rendered SI text · Supplementary narrative · Fig. S20
NOCA@CF LIB Coulombic efficiency after first five cycles	CE approximately approaches 100 % after first five cycles	—	—	Text Approximate	rendered SI text · Supplementary narrative · Fig. S20
NOCA@CF LIB capacity decay per cycle at 10 A g-1	0.0317 % capacity decay per cycle	—	—	Text Exact Reported	rendered SI text · Supplementary narrative · Fig. S20
NOCA@CF LIB capacity retention around 3000 cycles at 10 A g-1	95.27 % of sixth reversible capacity	—	—	Text Exact Reported	rendered SI text · Supplementary narrative · Fig. S20

Rate capability of NOCA@CF as LIB anode

NOCA@CF · Electrode

Current density increased from 0.5 to 50 A g-1, then returned to 0.5 A g-1.

Geometry: NOCA@CF self-standing anode
Context: MOF-derived carbon electrode tested directly as LIB anode.
Measurement source: rendered SI text · Fig. S19 caption and SI narrative · Fig. S19

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
NOCA@CF LIB rate capacity at 0.5 A g-1	1130 mAh g-1	—	—	Text Exact Reported	rendered SI text · Supplementary narrative · Fig. S19
NOCA@CF LIB rate capacity at 10 A g-1	593 mAh g-1	—	—	Text Exact Reported	rendered SI text · Supplementary narrative · Fig. S19
NOCA@CF LIB rate capacity at 1 A g-1	956 mAh g-1	—	—	Text Exact Reported	rendered SI text · Supplementary narrative · Fig. S19
NOCA@CF LIB rate capacity at 20 A g-1	573 mAh g-1	—	—	Text Exact Reported	rendered SI text · Supplementary narrative · Fig. S19
NOCA@CF LIB rate capacity at 2 A g-1	805 mAh g-1	—	—	Text Exact Reported	rendered SI text · Supplementary narrative · Fig. S19
NOCA@CF LIB rate capacity at 30 A g-1	526 mAh g-1	—	—	Text Exact Reported	rendered SI text · Supplementary narrative · Fig. S19
NOCA@CF LIB rate capacity at 3 A g-1	737 mAh g-1	—	—	Text Exact Reported	rendered SI text · Supplementary narrative · Fig. S19
NOCA@CF LIB rate capacity at 40 A g-1	464 mAh g-1	—	—	Text Exact Reported	rendered SI text · Supplementary narrative · Fig. S19
NOCA@CF LIB rate capacity at 4 A g-1	723 mAh g-1	—	—	Text Exact Reported	rendered SI text · Supplementary narrative · Fig. S19
NOCA@CF LIB rate capacity at 50 A g-1	428 mAh g-1	—	—	Text Exact Reported	rendered SI text · Supplementary narrative · Fig. S19
NOCA@CF LIB rate capacity at 5 A g-1	718 mAh g-1	—	—	Text Exact Reported	rendered SI text · Supplementary narrative · Fig. S19
NOCA@CF LIB rate capacity at 6 A g-1	707 mAh g-1	—	—	Text Exact Reported	rendered SI text · Supplementary narrative · Fig. S19
NOCA@CF LIB rate capacity at 7 A g-1	686 mAh g-1	—	—	Text Exact Reported	rendered SI text · Supplementary narrative · Fig. S19
NOCA@CF LIB rate capacity at 8 A g-1	664 mAh g-1	—	—	Text Exact Reported	rendered SI text · Supplementary narrative · Fig. S19
NOCA@CF LIB rate capacity at 9 A g-1	629 mAh g-1	—	—	Text Exact Reported	rendered SI text · Supplementary narrative · Fig. S19
NOCA@CF LIB capacity when current returned to 0.5 A g-1	1012 mAh g-1	—	—	Text Exact Reported	rendered SI text · Supplementary narrative · Fig. S19

Zn plating/stripping Coulombic efficiency in 2032 coin half-cells

NOCA@CF · Electrode

NOCA@CF or Cu working electrode, Zn foil counter/reference, 2 M ZnSO4 electrolyte, 1 mAh cm-2 Zn deposited; cutoff 0.1 V.

Atmosphere: aqueous 2 M ZnSO4 electrolyte
Geometry: 2032 coin half-cell
Context: Target NOCA@CF versus Cu/CF control
Measurement source: 5 · 2.5. Electrochemical measurement · Fig. 4a-b

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Zn Coulombic efficiency on CF at 1 mA cm-2	80.7% after 250 cycles	—	—	Text Exact Reported	9 · 3.2. Electrochemical performance of NOCA@CF for Zn metal anode · Fig. 4a
Average Zn Coulombic efficiency on NOCA@CF at 1 mA cm-2Marked as a best value within this paper	95.7% up to 350 cycles	—	around	Text Rounded Reported	9 · 3.2. Electrochemical performance of NOCA@CF for Zn metal anode · Fig. 4a
Average Zn Coulombic efficiency on NOCA@CF at 2 mA cm-2	95.3% over 350 cycles	—	around	Text Rounded Reported	9 · 3.2. Electrochemical performance of NOCA@CF for Zn metal anode · Fig. 4b

Electrochemical impedance spectroscopy of Zn||LiMn2O4 cells

Impedance spectroscopy

Zn@NOCA@CF · Electrode

EIS tests of Zn||LiMn2O4 cells based on Zn@CF and Zn@NOCA@CF anodes after 120 cycles.

Atmosphere: aqueous ZnSO4/MnSO4 electrolyte
Geometry: full cell
Context: Zn@NOCA@CF versus Zn@CF control
Measurement source: SI p10 · Fig. S9 caption · Fig. S9

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Estimated EIS semicircle diameter for Zn@CF cell after 120 cycles	~550 ohm	—	—	Visual Estimate Approximate	SI p10 · Fig. S9 visual read · Fig. S9
Estimated EIS semicircle diameter for Zn@NOCA@CF cell after 120 cyclesMarked as a best value within this paper	~250 ohm	—	—	Visual Estimate Approximate	SI p10 · Fig. S9 visual read · Fig. S9

Zn||LiMn2O4 full-cell cycling and rate testing

Zn@NOCA@CF · Electrode

Zn@NOCA@CF or Zn@CF anode, LiMn2O4 cathode, 2 M ZnSO4 + 0.4 M MnSO4, 1.4-2.1 V.

Atmosphere: aqueous ZnSO4/MnSO4 electrolyte
Geometry: full cell
Context: Target Zn@NOCA@CF versus Zn@CF control
Measurement source: 5 · 2.5. Electrochemical measurement · Fig. 4h-i

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Zn\|\|LiMn2O4 reversible capacity with Zn@CF after 120 cycles	49.8 mAh g-1 after 120 cycles at 100 mA g-1	—	—	Text Exact Reported	10 · 3.2. Electrochemical performance of NOCA@CF for Zn metal anode · Fig. 4h
Zn\|\|LiMn2O4 reversible capacity with Zn@NOCA@CF after 120 cyclesMarked as a best value within this paper	74.9 mAh g-1 after 120 cycles at 100 mA g-1	—	—	Text Exact Reported	10 · 3.2. Electrochemical performance of NOCA@CF for Zn metal anode · Fig. 4h
Zn\|\|LiMn2O4 capacity after rate test returned to 100 mA g-1 with Zn@NOCA@CF	82.4 mAh g-1	—	—	Text Exact Reported	10 · 3.2. Electrochemical performance of NOCA@CF for Zn metal anode · Fig. 4i

Zn||Zn symmetric-cell cycling

Zn@NOCA@CF · Electrode

Zn@NOCA@CF or Zn@CF anodes cycled in 2 M ZnSO4 at 1 or 2 mA cm-2.

Atmosphere: aqueous 2 M ZnSO4 electrolyte
Geometry: symmetric cell
Context: Target Zn@NOCA@CF versus Zn@CF control
Measurement source: 5 · 2.5. Electrochemical measurement · Fig. 4e-g

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Zn\|\|Zn symmetric cycling instability with Zn@CF at 1 mA cm-2	fluctuations after 110 h	—	after only	Text Rounded Reported	10 · 3.2. Electrochemical performance of NOCA@CF for Zn metal anode · Fig. 4f
Zn\|\|Zn symmetric cycling life with Zn@NOCA@CF at 1 mA cm-2Marked as a best value within this paper	stable for 240 h	—	up to	Text Rounded Reported	10 · 3.2. Electrochemical performance of NOCA@CF for Zn metal anode · Fig. 4f
Zn\|\|Zn symmetric cycling life with Zn@NOCA@CF at 2 mA cm-2	stable up to 210 h	—	up to	Text Rounded Reported	10 · 3.2. Electrochemical performance of NOCA@CF for Zn metal anode · Fig. 4g

Zn||Zn symmetric-cell comparison table entry

Zn@NOCA@CF · Electrode

This-work rows in Table S1 for Zn@NOCA@CF in 2 M ZnSO4.

Atmosphere: 2 M ZnSO4
Geometry: symmetric cell
Context: This-work comparison-table values
Measurement source: SI p22 · Table S1 · Table S1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Zn@NOCA@CF cycle life in Zn\|\|Zn at 1 mA cm-2 / 0.5 mAh cm-2	240 h	—	—	SI Table Rounded Reported	SI p22 · Table S1 · Table S1
Zn@NOCA@CF cycle life in Zn\|\|Zn at 2 mA cm-2 / 1 mAh cm-2	210 h	—	—	SI Table Rounded Reported	SI p22 · Table S1 · Table S1
Zn@NOCA@CF overpotential in Zn\|\|Zn at 1 mA cm-2 / 0.5 mAh cm-2	45 mV	—	—	SI Table Rounded Reported	SI p22 · Table S1 · Table S1
Zn@NOCA@CF overpotential in Zn\|\|Zn at 2 mA cm-2 / 1 mAh cm-2	64 mV	—	—	SI Table Rounded Reported	SI p22 · Table S1 · Table S1