Electrical Transport — Porous, conductive metal-triazolates and their structural elucidation by the charge-flipping method

3 measurement groups · 5 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Four-point probe DC conductivity after iodine-vapour exposure

Electrical conductivity

MET-3 pellet exposed to iodine vapour · Pellet

Same pressed MET-3 pellet/device type after 40 min exposure to I2 vapour; PXRD checked after exposure.

Temperature: 295
Atmosphere: vacuum measurement after I2 vapour exposure
Geometry: pressed pellet four-probe geometry
Context: iodine-doped MET-3 pellet; framework retained by PXRD
Measurement source: p.5, article p.10599 · Electrical conductivity · Figure 6b

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
conductivity after I2 exposureMarked as a best value within this paper	1.0 x 10^-3 S cm^-1 after 40 min I2 exposure	—	—	Text Exact Reported	p.5, article p.10599 · Electrical conductivity · Figure 6b
iodine exposure conductivity enhancement	ca. 13-fold relative to pristine pellet	—	—	Calculated From Reported Approximate	p.5, article p.10599 · Electrical conductivity · Figure 6a-b

Four-point probe DC conductivity/resistivity measurement

Electrical conductivity

MET-3 freshly prepared pressed pellet · Pellet

Pressed bulk pellet; 500 micrometre gold electrodes thermally deposited by shadow mask; 1.6 mm electrode spacing; Lake Shore TTP4 station under vacuum.

Temperature: 295
Atmosphere: vacuum
Geometry: pressed pellet, 1 cm diameter, 0.5 mm thick; four-probe geometry
Context: pristine MET-3 framework pellet
Measurement source: p.5, article p.10599 · Electrical conductivity · Figure 6a

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
undoped pellet conductivity stability	conductivity does not degrade after eight weeks in air	—	—	Text Exact Reported	p.5, article p.10599 · Electrical conductivity
room-temperature conductivityMarked as a best value within this paper	0.77 x 10^-4 S cm^-1	—	—	Text Exact Reported	p.5, article p.10599 · Electrical conductivity · Figure 6a

Temperature-dependent four-point probe I-V curves

Electrical conductivity

MET-3 freshly prepared pressed pellet · Pellet

Four-probe measurements at 295, 305, 315 and 325 K on MET-3 pellet under vacuum.

Temperature: 295, 305, 315, 325
Atmosphere: vacuum
Geometry: pressed pellet four-probe geometry
Context: pristine MET-3 framework pellet
Measurement source: p.5, article p.10599 · Electrical conductivity · Figure 6d

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
temperature dependence of current/conductivity	conductivity/current increases with temperature from 295 to 325 K	—	—	Caption Qualitative	p.5, article p.10599 · Electrical conductivity · Figure 6d