Other — From insulator to semiconductor: effect of host-guest interactions on charge transport in M-MOF-74 metal-organic frameworks

4 measurement groups · 8 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

H4TCNQ@Cu-MOF-74 pellet · Pellet

Elemental analysis by Galbraith Laboratories; used to compare H4TCNQ loading with TCNQ loading.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Experimental nitrogen content for H4TCNQ@Cu-MOF-74	Exp C 30.3%, N 2.36%, H 2.72%; calc C 4.50%, N 10.5%, H 1.51%.	—	—	SI Table Exact Reported	S-7 · Elemental Analysis · Table S1
H4TCNQ loading in Cu-MOF-74	2 H4TCNQ molecules per Cu-MOF-74 cell.	—	—	Text Rounded Reported	2701 · Results and discussion

H4TCNQ@Mn-MOF-74 pellet · Pellet

Elemental analysis by Galbraith Laboratories; used to compare H4TCNQ loading with TCNQ loading.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Experimental nitrogen content for H4TCNQ@Mn-MOF-74	Exp C 34.9%, N 4.52%, H 2.76%; calc C 4.66%, N 10.9%, H 1.55%.	—	—	SI Table Exact Reported	S-7 · Elemental Analysis · Table S1
H4TCNQ loading in Mn-MOF-74	4 H4TCNQ molecules per Mn-MOF-74 cell.	—	—	Text Rounded Reported	2701 · Results and discussion

TCNQ@Cu-MOF-74 pellet · Pellet

Elemental analysis by Galbraith Laboratories; used to estimate guest loading.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Experimental nitrogen content for TCNQ@Cu-MOF-74	Exp C 30.4%, N 2.36%, H 2.72%; calc C 45.4%, N 10.6%, H 7.60%.	—	—	SI Table Exact Reported	S-7 · Elemental Analysis · Table S1
TCNQ loading in Cu-MOF-74	2 TCNQ molecules per Cu-MOF-74 cell; 1 TCNQ per 6 copper ions.	0.1667 TCNQ per Cu ion	—	Text Rounded Reported	2700 · Results and discussion · Table S1

TCNQ@Mn-MOF-74 pellet · Pellet

Elemental analysis by Galbraith Laboratories; used to estimate guest loading.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Experimental nitrogen content for TCNQ@Mn-MOF-74	Exp C 35.0%, N 4.53%, H 2.77%; calc C 46.91%, N 11.0%, H 7.80%.	—	—	SI Table Exact Reported	S-7 · Elemental Analysis · Table S1
TCNQ loading in Mn-MOF-74	4 TCNQ molecules per Mn-MOF-74 cell; 2 TCNQ per 6 manganese ions.	0.3333 TCNQ per Mn ion	—	Text Rounded Reported	2700 · Results and discussion · Table S1