Electrical Transport — Zeolites as a Class of Semiconductors for High-Performance Electrically Transduced Sensing

Measurement evidence

Electrical Transport

Zeolites as a Class of Semiconductors for High-Performance Electrically Transduced Sensing · Wang T., Chu Y., Li X. et al. · Journal of the American Chemical Society · 2023 · 5342-5352

4 measurement groups · 7 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Electrochemical impedance spectroscopy and Arrhenius conductivity

Na-ZSM-5 (9.8) · Powder

EIS recorded 250-325 C for Na-ZSM-5 (9.8); 1 MHz to 0.1 Hz

Temperature
523-598
Geometry
impedance spectroscopy cell
Context
pristine zeolite powders
Measurement source
19 · Supplementary Figures · Figure S9
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Conduction activation energy for Na-ZSM-5 (9.8)4.0 kJ/molCaption
Rounded Reported
19 · Supplementary Figures · Figure S9

Current-voltage (I-V) under d.c. bias

Na-MTW (22) · Powder

Na-MTW (22, 30, 46) at 25-350 C

Temperature
298-623
Geometry
zeolite-based diode-like device
Context
pristine zeolite powders/films
Measurement source
41 · Supplementary Figures · Figure S31
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Na-MTW band-gap narrowing rangefrom 4.43 to 3.89 eV with decreasing framework Si/Al ratioText
Range
5347 · Semiconducting Characteristics Analyses · Figure S28

Current-voltage (I-V) under d.c. bias

Na-ZSM-5 (9.8) · Powder

Na-ZSM-5 diode device; 25-350 C depending on measurement

Temperature
298-623
Geometry
ITO anode / zeolite film / Al cathode / bottom heating element
Context
zeolite film in diode device
Measurement source
5345-5347 · Semiconducting Characteristics Analyses · Figure 2a-b; Figure S17
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Threshold voltage for Na-ZSM-5 (9.8) at 25 CVTH = 12.5 VFigure Axis
Approximate
27 · Supplementary Figures · Figure S17
Threshold voltage for Na-ZSM-5 (9.8) at 350 CMarked as a best value within this paperVTH = 8.8 VFigure Axis
Approximate
27 · Supplementary Figures · Figure S17
Electrical d.c. conductivity above approximately 600 KMarked as a best value within this paperup to 10^-7 S cm^-1 above approximately 600 KText
Approximate
5347 · Semiconducting Characteristics Analyses · Figure 2c

Photocurrent-time and dark I-V response

Na-ZSM-5 (9.8) UV photodetector film · Thin Film

280 nm UV illumination at 1 V bias; room temperature

Temperature
298
Geometry
Au / Na-ZSM-5 film / SnO2 ETL / ITO glass photodetector, effective area 0.1 cm x 0.1 cm
Context
device stack with pristine zeolite active film
Measurement source
5347 · Semiconducting Characteristics Analyses · Figure 2f-h
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
UV photodetector photocurrentabout 0.7 mAText
Approximate
5347 · Semiconducting Characteristics Analyses · Figure 2h
UV photodetector photosensitivity on/off ratioIphoto/Idark = 1.3Text
Rounded Reported
5347 · Semiconducting Characteristics Analyses · Figure 2h