Electrochemistry Application — Nanoporous gold induced vertically standing 2D NiCo bimetal-organic framework nanosheets for non-enzymatic glucose biosensing

6 measurement groups · 14 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

vertical NiCo(1:1)-MOFNs array on nanoporous gold, 4 h growth · Electrode

0.1 M NaOH without and with 4 mM glucose; scan rate 50 mV s^-1

Atmosphere: N2-saturated electrolyte per electrochemical measurements
Geometry: three-electrode; working electrode 2D NiCo-MOFNs, SCE reference, Pt plate counter
Context: target sample
Measurement source: 654 · 3.2 Synergistic effect · Fig. 2b

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Co2+/Co3+ oxidation potential	about 0.25 V	—	—	Text Approximate	654 · 3.2 Synergistic effect · Equations 1-5
glucose catalytic peak potentialMarked as a best value within this paper	0.50 V vs. SCE	—	—	Text Rounded Reported	654 · 3.2 Synergistic effect · Fig. 2b

NiCo-MOFNs on nanoporous gold, 2 h growth · Electrode

0.1 M NaOH; scan-rate-dependent CV; potential window -0.1 to 0.02 V vs. SCE; scan rates 10-200 mV s^-1 in SI

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
double-layer capacitance label	0.1860 mF cm^-2	—	—	Figure Axis Rounded Reported	654 · 3.1 Preparation · Fig. 2a

vertical NiCo(1:1)-MOFNs array on nanoporous gold, 4 h growth · Electrode

0.1 M NaOH; scan-rate-dependent CV; potential window -0.1 to 0.02 V vs. SCE; scan rates 10-200 mV s^-1 in SI

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
double-layer capacitance labelMarked as a best value within this paper	0.6638 mF cm^-2	—	—	Figure Axis Rounded Reported	654 · 3.1 Preparation · Fig. 2a
ECSA ratio versus 2 h sampleMarked as a best value within this paper	3.6 times of the 2 h NiCo-MOFNs	—	—	Text Rounded Reported	654 · 3.1 Preparation · Fig. 2a
ECSA ratio versus 6 h sampleMarked as a best value within this paper	2.0 times of the 6 h NiCo-MOFNs	—	—	Text Rounded Reported	654 · 3.1 Preparation · Fig. 2a

NiCo-MOFNs on nanoporous gold, 6 h growth · Electrode

0.1 M NaOH; scan-rate-dependent CV; potential window -0.1 to 0.02 V vs. SCE; scan rates 10-200 mV s^-1 in SI

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
double-layer capacitance label	0.3311 mF cm^-2	—	—	Figure Axis Rounded Reported	654 · 3.1 Preparation · Fig. 2a

vertical NiCo(1:1)-MOFNs array on nanoporous gold, 4 h growth · Electrode

Glucose oxidation current calculated by subtracting 0.1 M NaOH oxidation current from glucose solution oxidation current

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
best Ni/Co ratioMarked as a best value within this paper	Ni/Co ratio of 1:1 show the best electrochemical performance	—	—	Text Qualitative	655 · 3.2 Synergistic effect · Fig. 2d, Fig. S7
glucose oxidation current at 0% Co	approximately 0.13 mA	—	—	Visual Estimate Uncertain	654 · Fig. 2 caption · Fig. 2d
glucose oxidation current at about 25% Co	approximately 0.44 mA	—	—	Visual Estimate Uncertain	654 · Fig. 2 caption · Fig. 2d
glucose oxidation current at about 50% Co (Ni:Co 1:1)Marked as a best value within this paper	approximately 0.56 mA	—	—	Visual Estimate Uncertain	654 · Fig. 2 caption · Fig. 2d
glucose oxidation current at about 75% Co	approximately 0.08 mA	—	—	Visual Estimate Uncertain	654 · Fig. 2 caption · Fig. 2d

vertical NiCo(1:1)-MOFNs array on nanoporous gold, 4 h growth · Electrode

0.1 M NaOH; scan rates 20-100 mV s^-1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
peak-current scan-rate dependence	oxidation and reduction peak currents increase linearly with scan rates	—	—	Text Qualitative	655 · 3.2 Synergistic effect · Fig. 2c
kinetic regime	surface-controlled electrochemical process	—	—	Text Qualitative	655 · 3.2 Synergistic effect · Fig. 2c