Diffraction Structure — Oriented growth of semiconducting TCNQ@Cu3(BTC)2MOF on Cu(OH)2: crystallographic orientation and pattern formation toward semiconducting thin-film devices

Measurement evidence

Diffraction Structure

Oriented growth of semiconducting TCNQ@Cu3(BTC)2MOF on Cu(OH)2: crystallographic orientation and pattern formation toward semiconducting thin-film devices · Okada K., Mori K., Fukatsu A. et al. · Journal of Materials Chemistry A · 2021 · 19613-19618

1 measurement group · 8 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Out-of-plane XRD, in-plane XRD, azimuthal phi scan, and in-plane RSM

X-ray diffraction and scattering

Three-dimensionally oriented Cu3(BTC)2 thin film · Thin Film

CuKalpha radiation; out-of-plane and in-plane geometries with incident angle parallel/perpendicular to nanobelt longitudinal direction; phi scan and RSM for orientation relationship.

Context: pristine oriented framework film
Measurement source: 19614-19615 · 2.1 Oriented growth of Cu3(BTC)2 on Cu(OH)2 · Figure 1c,d; Figures S2-S4

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Cu-paddlewheel Cu-Cu distance in Cu3(BTC)2	approximately 2.63 A	2.63e-10 m	—	Text Approximate	19615 · 2.1 Oriented growth of Cu3(BTC)2 on Cu(OH)2 · Figures S6-S7
Cu-Cu distance along Cu(OH)2 a-axis	2.95 A	2.95e-10 m	—	Text Exact Reported	19615 · 2.1 Oriented growth of Cu3(BTC)2 on Cu(OH)2 · Figures S6-S7
Lattice mismatch for [111bar](112)Cu3(BTC)2//[001](010)Cu(OH)2	5.34%	0.0534 fraction	—	Text Exact Reported	19615 · 2.1 Oriented growth of Cu3(BTC)2 on Cu(OH)2 · Figures S6-S7
Lattice mismatch for [001](110)Cu3(BTC)2//[001](010)Cu(OH)2	5.34%	0.0534 fraction	—	Text Exact Reported	19615 · 2.1 Oriented growth of Cu3(BTC)2 on Cu(OH)2 · Figures S6-S7
Cu3(BTC)2 222 phi scan angular maxima	phi approximately 0, 55, 125, 180, 235, 305 and 360 degrees	—	—	Text Approximate	19615 · 2.1 Oriented growth of Cu3(BTC)2 on Cu(OH)2 · Figure 1d
Phi scan 200/220 reflection maxima	intense signals at phi = 90 and 270 degrees for Cu(OH)2 200 and Cu3(BTC)2 220 reflections	—	—	Text Rounded Reported	19614 · 2.1 Oriented growth of Cu3(BTC)2 on Cu(OH)2 · Figure 1d
Cu3(BTC)2 220 reflection position	2theta = 9.5 degrees	—	—	Text Rounded Reported	19614 · 2.1 Oriented growth of Cu3(BTC)2 on Cu(OH)2 · Figure 1c
Out-of-plane Cu3(BTC)2 222 reflection position	2theta = 11.7 degrees	—	—	Text Rounded Reported	19614 · 2.1 Oriented growth of Cu3(BTC)2 on Cu(OH)2 · Figure 1c