cMOF Evidence Base

Synthesis evidence

Fabrication of a halopyridine appended Co(II) based 1D coordination polymer for efficient charge transportation

Naaz S., Das P., Khan S. et al. · Polyhedron · 2021 · 115159

2 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Partial recipeSource: Main

Route 1: Other

p002 · 2.6 Electrical measurements

Solventsacetonitrile
Atmospherevacuum drying; aluminium deposition at base pressure 10^-6 Torr
Temperatureroom temperature not explicitly stated
Time0.75 h ultrasonication
Substrate orientationpre-cleaned ITO-coated glass substrate
Work-upSpin-coated homogeneous acetonitrile solution on ITO, dried in a vacuum chamber, vacuum-coated with Al through a shadow mask.
Activationvacuum drying before Al deposition
Show 4 structured reagent records
RoleReagentAmount / concentrationSource
Othercompound 1not reported · not reportedp002 · 2.6 Electrical measurements
Solventacetonitrilenot reportedp002 · 2.6 Electrical measurements
OtherITO coated glass substrateone substrate; area not reportedp002 · 2.6 Electrical measurements
Otheraluminium metal top contactvacuum deposited; thickness not reportedp002 · 2.6 Electrical measurements
Partial recipeSource: Main

Route 2: Liquid Liquid Interface

p002 · 2.2.1 Preparation

Metal precursorsCoCl2.6H2O (0.047 g, 0.2 mmol) in H2O (2 mL)
Linker precursors3clpy (0.016 g, 0.2 mmol) in MeOH (2 mL); fumaric acid (0.023 g, 0.2 mmol) neutralised with Et3N (0.021 g, 0.2 mmol) in EtOH (2 mL)
SolventsMeOH, H2O, 1:1 v/v MeOH/H2O buffer solution, EtOH
AdditivesEt3N used to neutralise fumaric acid
Atmospherenot reported
Temperatureroom temperature inferred from layering crystallisation; not explicitly reported
Timefew days; exact time not reported
Work-upBlocked shaped pink crystals obtained; isolation/washing/drying not further specified.
Activationnone reported
Show 7 structured reagent records
RoleReagentAmount / concentrationSource
Linker3clpy0.016 g, 0.2 mmol · in MeOH (2 mL)p002 · 2.2.1 Preparation
SolventMeOH2 mL plus 1 mL in 2 mL 1:1 MeOH/H2O bufferp002 · 2.2.1 Preparation
Metal SourceCoCl2.6H2O0.047 g, 0.2 mmol · in H2O (2 mL)p002 · 2.2.1 Preparation
SolventH2O2 mL plus 1 mL in 2 mL 1:1 MeOH/H2O bufferp002 · 2.2.1 Preparation
Linkerfumaric acid0.023 g, 0.2 mmol · neutralised with Et3N in 2 mL EtOHp002 · 2.2.1 Preparation
BaseEt3N0.021 g, 0.2 mmolp002 · 2.2.1 Preparation
SolventEtOH2 mLp002 · 2.2.1 Preparation