Feng R., Fang J., Xu J. et al. · Microchemical Journal · 2025 · 115749
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
The label-free ZnCoMOFs-based ECL immunosensor detects AFB1 over 0.001-100 ng/mL with a 0.31 pg/mL detection limit.
Caveat: SI LOD calculation says CEA in one sentence, apparently a template carry-over typo; main text and Table S1 identify AFB1.
6 · 3.6 · Fig. 6B · Linked to 6 structured results
Standard-addition tests in commercial corn samples gave recoveries from 96.2% to 97.7% with RSD values below 5%.
Caveat: Main text does not give detailed corn pre-treatment chemistry.
7 · 3.7 · Table 1 · Linked to 3 structured results
Au nanoparticles improve the modified electrode conductivity and provide surface active sites for biomolecule immobilisation.
Caveat: Conductivity improvement is supported by CV/EIS trends; no independently fitted conductivity is reported.
5 · 3.4 · Fig. 4 · Linked to 6 structured results
XRD and EDS evidence support assigning the product as a bimetallic Zn/Co organic framework with HHTP-derived C and O.
Caveat: No CIF or extended formula/topology is reported in supplied documents; assignment rests on XRD and EDS evidence.
4 · 3.1 · Fig. 1 · Linked to 4 structured results
The authors attribute higher ECL performance of ZnCoMOFs to improved conductivity/electron transfer and cobalt-assisted co-reaction acceleration.
Caveat: No independently fitted conductivity value is reported; impedance and ECL evidence are qualitative or figure-estimated.
5 · 3.3 · Fig. 3 and Fig. S3 · Linked to 5 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| Au nanoparticles | Augold nanoparticles · none | 0D · Pristineuniform spherical nanoparticles used as a conductive functionalisation layer | 4 · 3.1. Morphological and structural characteristics · Fig. 1I |
| HHTP | Not specifiednone · 2,3,6,7,10,11-triphenylenehexol | 0D · Unknownluminescent organic precursor/control ligand | 1 · Abstract |
| AFB1/BSA/Ab/Au NPs/ZnCoMOFs/GCE ECL biosensor | Not specifiedZnCoMOFs plus Au nanoparticles on glassy carbon electrode · HHTP in ZnCoMOFs; antibody/BSA biomolecular layers | unknown · Compositelayer-by-layer composite electrode biosensor based on ZnCoMOFs | 2 · 2.2. Construction of label-free ECL biosensor · Scheme 1 |
| ZnCoMOFs | Not specifiedzinc and cobalt nodes · 2,3,6,7,10,11-triphenylenehexol (HHTP) | unknown · Pristinebimetallic HHTP-based conductive metal-organic framework; XRD peaks assigned to (100), (200), and (001) planes | 1 · Abstract |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| Ab/Au NPs/ZnCoMOFs/GCEresearch_0396__mat__mat_znco_ecl_biosensor | Electrode · Composite Sample · Composite | 6 uL capture antibody Ab1, 1 ug/mL, drop-cast onto Au NPs/ZnCoMOFs/GCEglassy carbon electrode | 2 · 2.2. Construction of label-free ECL biosensor · Fig. 4 |
| AFB1/BSA/Ab/Au NPs/ZnCoMOFs/GCEresearch_0396__mat__mat_znco_ecl_biosensor | Electrode · Composite Sample · Composite | 6 uL AFB1 solution drop-cast onto blocked biosensor for specific bindingglassy carbon electrode | 2 · 2.2. Construction of label-free ECL biosensor · Scheme 1 |
| Au NPsresearch_0396__mat__mat_au_nps | Unknown · Composite Component · Unknown | aqueous citrate-prepared nanoparticle dispersion, centrifuged and stored at 4 deg C in the dark | SI text p.S4 · Preparation of Au NPs |
| Au NPs/ZnCoMOFs/GCEresearch_0396__mat__mat_znco_ecl_biosensor | Electrode · Composite Sample · Composite | 6 uL Au NPs drop-cast on dried ZnCoMOFs/GCE and left for 30 min at room temperatureglassy carbon electrode | 2 · 2.2. Construction of label-free ECL biosensor · Fig. 4 |
| BSA/Ab/Au NPs/ZnCoMOFs/GCEresearch_0396__mat__mat_znco_ecl_biosensor | Electrode · Composite Sample · Composite | 3 uL 0.1% BSA drop-cast to block nonspecific adsorptionglassy carbon electrode | 2 · 2.2. Construction of label-free ECL biosensor · Fig. 4 |
| HHTP precursor controlresearch_0396__mat__mat_hhtp | Powder · Pristine Control · Unknown | commercial/precursor material used as control | 4 · 3.2. Spectral characterization of ZnCoMOFs · Fig. 2A |
| ZnCoMOFs/GCEresearch_0396__mat__mat_znco_ecl_biosensor | Electrode · Composite Sample · Composite | 8 uL ZnCoMOFs solution drop-cast on polished GCE and dried at room temperatureglassy carbon electrode | 2 · 2.2. Construction of label-free ECL biosensor · Fig. 4 |
| ZnCoMOFs black precipitate/powderresearch_0396__mat__mat_znco_mofs | Powder · Target Sample · Mixed Metal | centrifuged, washed three times, vacuum dried at 60 deg C for 24 h | 2 · 2.1. Preparation of ZnCoMOFs |