Porosity — High-resolution structure of Zn3(HOTP)2 (HOTP = hexaoxidotriphenylene), a three-dimensional conductive MOF

Measurement evidence

Porosity

High-resolution structure of Zn3(HOTP)2 (HOTP = hexaoxidotriphenylene), a three-dimensional conductive MOF · Zhang K.J., Chen T., Oppenheim J.J. et al. · Chemical Science · 2025 · 12416-12420

1 measurement group · 4 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

N2 adsorption/desorption isotherm; BET surface area; BJH pore size distribution; Zeo++ pore diameter from crystal structure

Activated Zn3(HOTP)2 for N2 sorption · Powder

Micromeritics ASAP 2020 Plus; activated at 90 deg C under high dynamic vacuum for 24 h; N2 at 77 K in liquid nitrogen bath.

Temperature
77
Atmosphere
N2
Context
activated pristine Zn3(HOTP)2
Measurement source
p002 · Methods; N2 adsorption isotherms · Figure S2
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
BET surface areaMarked as a best value within this paper249.9 m2 g^-1Text
Exact Reported
p002 / journal page 12417 · Results and discussion · Fig. S2
Minor mesopore contributionnear ~6 nmCaption
Approximate
p006 · 4. N2 adsorption isotherm · Figure S2
BJH pore size distribution main peak~1.1 nmCaption
Approximate
p006 · 4. N2 adsorption isotherm · Figure S2
Calculated pore size from crystal structure14 ACaption
Rounded Reported
p006 · 4. N2 adsorption isotherm · Figure S2