Complete recipeSource: Both
Route 1: Solvothermal
p004 · 2. Synthetic Procedures
Metal precursorsZn(OAc)2 . 2H2O (24.6 mg, 0.112 mmol, 1.82 eq.)
Linker precursorsH6HOTP (20 mg, 0.0617 mmol, 1 eq.)
SolventsDI water (4.4 mL) and N,N-dimethylformamide (DMF, 1.28 mL)
Atmospherenot specified
Temperature85
Time8
Work-upCooled to room temperature; washed with water (5 mL, 3 times), ethanol (5 mL, 3 times), and acetone (5 mL, 3 times).
ActivationFor sorption/electron diffraction: desolvation or activation at 90 deg C under high dynamic vacuum (<10^-4 mbar) for 24 h before N2 analysis.
Scalability contextReported isolated yield: 8.92 mg, 35% yield per HOTP. Small batch vial synthesis.
Show 7 structured reagent records
| Role | Reagent | Amount / concentration | Source |
|---|---|---|---|
| Metal Source | Zn(OAc)2 . 2H2O | 24.6 mg, 0.112 mmol, 1.82 eq. | p004 · 2. Synthetic Procedures |
| Linker | H6HOTP | 20 mg, 0.0617 mmol, 1 eq. | p004 · 2. Synthetic Procedures |
| Solvent | DI water | 4.4 mL | p004 · 2. Synthetic Procedures |
| Solvent | N,N-dimethylformamide (DMF) | 1.28 mL | p004 · 2. Synthetic Procedures |
| Solvent | water wash | 5 mL, 3 times | p004 · 2. Synthetic Procedures |
| Solvent | ethanol wash | 5 mL, 3 times | p004 · 2. Synthetic Procedures |
| Solvent | acetone wash | 5 mL, 3 times | p004 · 2. Synthetic Procedures |