Tien Dat N., Ngoc Tien N., Ngan N.T.T. et al. · Analyst · 2023 · 1777-1785
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
Cu-BTC/GCE gives improved paracetamol sensing versus bare GCE, with higher sensitivity, lower LOD and smaller pseudo-redox peak separation.
Caveat: Application is in PBS and one traditional medicine sample; long-term stability is not reported.
p007-p008 / 1783-1784 · 3.5; Conclusions · Fig. 7; Table 2 · Linked to 6 structured results
The authors state that future work should introduce electron donor or acceptor centres to ligands to improve MOF conductivity.
Caveat: This is a forward-looking caveat, not a demonstrated result.
p005 / 1781 · 3.3 Electrochemical behavior · Linked to 1 structured result
The authors attribute improved conductivity/electron transfer partly to the two-dimensional structure of the Cu-BTC film enabling in-plane pi-delocalisation and out-of-plane pi-conjugation.
Caveat: The structure-property explanation is interpretive; direct conductivity and crystallographic data for this film are not reported.
p006 / 1782 · 3.4 Oxidation of paracetamol · Linked to 2 structured results
Microporous Cu-BTC film is proposed to improve adsorption of paracetamol and contribute to sensing performance.
Caveat: Pore size and active surface area were not directly measured in this work.
p006 / 1782 · 3.4 Oxidation of paracetamol · Linked to 3 structured results
Et3N probase increases local pH near the electrode and accelerates deprotonation, facilitating growth of homogeneous Cu-BTC film on GCE.
Caveat: Adhesion failure on FTO is noted but the detailed reason is not resolved.
p002-p003 / 1778-1779 · 3.1 Electrodeposition · Scheme 1 · Linked to 2 structured results
Electrodeposited Cu-BTC film markedly improves interfacial electron transfer compared with bare GCE, as shown by lower RCT, smaller redox-probe peak separation, higher currents and higher Ks.
Caveat: Evidence is electrochemical interfacial transport; no direct bulk electronic conductivity measurement is reported.
p005 / 1781 · 3.3 Electrochemical behavior · Fig. 5; Table 1 · Linked to 5 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| bare glassy carbon electrode | C | unknown · Model SystemCommercial glassy carbon electrode control, diameter 3 mm. | p002 / 1778 · Experimental |
| Cu-BTCBrowse family: HKUST-1 / Cu₃(BTC)₂ | Cu3(BTC)2 / Cu3(TMA)2(H2O)3 framework assignmentdimeric copper(II) carboxylate units; copper ion centres · benzene-1,3,5-tricarboxylate (BTC, trimesate) | 2D · PristineTwo-dimensional Cu-BTC film; octahedral Cu-BTC crystals observed by SEM; coordination confirmed by Raman/FTIR. | p001 / 1777 · Abstract and Introduction |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| Bare GCEresearch_0407__mat__mat_bare_gce | Electrode · Pristine Control · Model | Polished with 0.3 um Al powder, rinsed with distilled water and dried.glassy carbon electrode · not applicable | p002 / 1778 · Experimental |
| Cu-BTC/GCE, 15 min filmresearch_0407__mat__mat_cu_btc | Electrode · Target Sample · Pristine Framework | Electrodeposition time increased to 15 min for synthesis-time comparison.glassy carbon electrode · not reported; larger amount expected than 5 min film | p005 · SI Fig. 8S · Fig. 8S |
| Cu-BTC/GCE, optimised 5 min filmresearch_0407__mat__mat_cu_btc | Electrode · Target Sample · Pristine Framework | Electrodeposited in DMF by chronoamperometry at -1.1 V vs Ag/AgCl for 5 min; deposition charge -7.46 mC.glassy carbon electrode (GCE), d = 3 mm · not reported | p003 / 1779 · 3.1 Electrodeposition of Cu-BTC onto a GCE · Fig. 3S and Fig. 4S referenced |
| Cu-BTC/GCE, 60 min morphology sampleresearch_0407__mat__mat_cu_btc | Electrode · Target Sample · Pristine Framework | Long reaction time of 60 min for SEM visualisation of crystals.short glassy carbon electrode · not reported | p003 / 1779 · 3.2 Morphology and structure studies · Fig. 2 |