Electrical Transport — Sensing interface based on electrodeposited Cu-BTC microporous film for electrochemical detection of the painkiller paracetamol

4 measurement groups · 14 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Cu-BTC/GCE, optimised 5 min film · Electrode

CVs recorded in 100 mM KCl over -600 mV to +600 mV vs Ag/AgCl.

Geometry: Cu-BTC/GCE electrode
Context: pristine Cu-BTC film
Measurement source: p004-p005 / 1780-1781 · 3.3 Electrochemical behavior of Cu-BTC grown on a GCE · Fig. 5

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Cu(I)/Cu(0) transition potentials	Cu(I) + e- <-> Cu(0): -380 mV / -40 mV	—	—	Text Exact Reported	p004 / 1780 · 3.3 · Fig. 5
Cu(II)/Cu(I) transition potentials	Cu(II) + e- <-> Cu(I): 111 mV / 150 mV	—	—	Text Exact Reported	p004 / 1780 · 3.3 · Fig. 5

Bare GCE · Electrode

100 mM KCl containing 5 mM K3[Fe(CN)6]/K4[Fe(CN)6], frequencies 10^-1 to 10^5 Hz.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
constant phase element CPE	1.123 x 10^-6 uMho	—	—	Table Exact Reported	p005 / 1781 · 3.3 · Table 1
charge transfer resistance RCT	2172.5 +/- 30.5 ohm	—	+/- 30.5 ohm	Table Exact Reported	p005 / 1781 · 3.3 · Table 1
solution resistance Rs	11.8 +/- 0.5 ohm	—	+/- 0.5 ohm	Table Exact Reported	p005 / 1781 · 3.3 · Table 1
Warburg element W1	47.461 x 10^-5 uMho	—	—	Table Exact Reported	p005 / 1781 · 3.3 · Table 1

Cu-BTC/GCE, optimised 5 min film · Electrode

100 mM KCl containing 5 mM K3[Fe(CN)6]/K4[Fe(CN)6], frequencies 10^-1 to 10^5 Hz.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
constant phase element CPE	1.131 x 10^-5 uMho	—	—	Table Exact Reported	p005 / 1781 · 3.3 · Table 1
charge transfer resistance RCTMarked as a best value within this paper	86.0 +/- 8.6 ohm	—	+/- 8.6 ohm	Table Exact Reported	p005 / 1781 · 3.3 · Table 1
solution resistance Rs	14.2 +/- 0.5 ohm	—	+/- 0.5 ohm	Table Exact Reported	p005 / 1781 · 3.3 · Table 1
Warburg element W1	42.048 x 10^-5 uMho	—	—	Table Exact Reported	p005 / 1781 · 3.3 · Table 1
charge-transfer resistance decrease factorMarked as a best value within this paper	twenty-five times	—	—	Text Rounded Reported	p008 / 1784 · Conclusions

Cu-BTC/GCE, optimised 5 min film · Electrode

100 mM KCl containing 5 mM K3[Fe(CN)6]/K4[Fe(CN)6], scan rate 50 mV s-1; Laviron scan-rate series 10-200 mV s-1 for Ks.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
ferri/ferrocyanide anodic and cathodic current increaseMarked as a best value within this paper	increased by 40%	—	—	Text Rounded Reported	p004 / 1780 · 3.3 · Fig. 5
ferri/ferrocyanide peak separation decreaseMarked as a best value within this paper	decreased by 80 mV	—	—	Text Rounded Reported	p004 / 1780 · 3.3 · Fig. 5
standard electron transfer rate constant improvementMarked as a best value within this paper	improved by 3.55 times	—	—	Text Exact Reported	p004 / 1780 · 3.3 · Fig. 5