cMOF Evidence Base
Electrical Transport — A new semiconducting coordination polymer consisting of copper(I)-iodide and 3-pyridinecarboxaldehyde

Measurement evidence

Electrical Transport

A new semiconducting coordination polymer consisting of copper(I)-iodide and 3-pyridinecarboxaldehyde · Himoto K., Horii T., Syoji T. et al. · Inorganic Chemistry Communications · 2018 · 34-37

2 measurement groups · 250 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Impedance, electric modulus, dielectric spectroscopy, and equivalent-circuit fitting

Impedance spectroscopy

Pressed powder pellet of 1 for impedance measurements · Pellet

Pressed powder pellet between 13 mm brass electrodes; measurements over 300-360 K; SI method states 100 Hz to 3 MHz; main-text fitting used 200 Hz to 1 MHz with ZView and an R1/R2 plus CPE1/CPE2 equivalent circuit.

Temperature
300-360
Geometry
Pellet diameter 13 mm; thickness 0.332 mm; brass electrodes.
Context
pristine_framework
Measurement source
main p.2-p.3 / article pp.35-36 · Impedance measurements · Figs. 4 and 5; Tables S1-S4
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Average CPE1-alpha used in reduced-parameter SI fitCPE1-alpha = 0.941——SI Table
Exact Reported		SI p.S8 · Table S3 caption · Table S3
Average CPE2-alpha used in reduced-parameter SI fitCPE2-alpha = 0.899——SI Table
Exact Reported		SI p.S8 · Table S3 caption · Table S3
Activation energy from relaxation timeEa = 0.41 eV——Text
Exact Reported		main p.3 / article p.36 · Electric modulus/relaxation discussion · Fig. 5b
SI bulk activation energy from Table S2 conductivity valuesEa = 0.448 eV——Caption
Exact Reported		SI p.S8 · Supporting figures · Fig. S6
SI bulk activation energy from Table S4 conductivity valuesEa = 0.438 eV——Caption
Exact Reported		SI p.S10 · Supporting figures · Figure S7
Activation energy from sigma_dc Arrhenius fitMarked as a best value within this paperEa = 0.36 eV——Text
Exact Reported		main p.3 / article p.36 · Impedance results · Fig. 5c
Main-text equivalent-circuit fitting frequency range200 Hz to 1 MHz——Text
Exact Reported		main p.3 / article p.36 · Electric modulus/relaxation discussion · Fig. 4
SI impedance measurement frequency range100 Hz to 3 MHz——Text
Exact Reported		1.4. Physical Measurements
Impedance pellet diameter13 mm——Text
Exact Reported		main p.2 / article p.35 · Impedance measurements · Fig. 4
Impedance pellet thickness0.332 mm——Text
Exact Reported		main p.2 / article p.35 · Impedance measurements · Fig. 4
Nyquist plot shapeSemicircular arcs were obtained from 300 to 360 K——Text
Qualitative		main p.2 / article p.35 · Impedance measurements · Fig. 4
Bulk conductivity at 300 K from impedance fitMarked as a best value within this papersigma300K = 4.57 x 10^-8 S/cm——Text
Exact Reported		main p.3 / article p.36 · Impedance results · Fig. 5c
Table S1 CPE1-A at 300 KCPE1-A = 1.20E-10 at 300 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 CPE1-A at 305 KCPE1-A = 1.23E-10 at 305 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 CPE1-A at 310 KCPE1-A = 1.27E-10 at 310 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 CPE1-A at 315 KCPE1-A = 1.30E-10 at 315 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 CPE1-A at 320 KCPE1-A = 1.32E-10 at 320 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 CPE1-A at 325 KCPE1-A = 1.41E-10 at 325 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 CPE1-A at 330 KCPE1-A = 1.47E-10 at 330 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 CPE1-A at 335 KCPE1-A = 1.58E-10 at 335 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 CPE1-A at 340 KCPE1-A = 1.73E-10 at 340 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 CPE1-A at 345 KCPE1-A = 1.91E-10 at 345 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 CPE1-A at 350 KCPE1-A = 2.08E-10 at 350 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 CPE1-A at 355 KCPE1-A = 2.30E-10 at 355 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 CPE1-A at 360 KCPE1-A = 2.60E-10 at 360 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 CPE1-alpha at 300 KCPE1-alpha = 0.947 at 300 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 CPE1-alpha at 305 KCPE1-alpha = 0.950 at 305 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 CPE1-alpha at 310 KCPE1-alpha = 0.950 at 310 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 CPE1-alpha at 315 KCPE1-alpha = 0.953 at 315 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 CPE1-alpha at 320 KCPE1-alpha = 0.955 at 320 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 CPE1-alpha at 325 KCPE1-alpha = 0.951 at 325 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 CPE1-alpha at 330 KCPE1-alpha = 0.950 at 330 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 CPE1-alpha at 335 KCPE1-alpha = 0.946 at 335 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 CPE1-alpha at 340 KCPE1-alpha = 0.940 at 340 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 CPE1-alpha at 345 KCPE1-alpha = 0.932 at 345 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 CPE1-alpha at 350 KCPE1-alpha = 0.927 at 350 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 CPE1-alpha at 355 KCPE1-alpha = 0.920 at 355 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 CPE1-alpha at 360 KCPE1-alpha = 0.911 at 360 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 CPE2-A at 300 KCPE2-A = 1.24E-10 at 300 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 CPE2-A at 305 KCPE2-A = 1.32E-10 at 305 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 CPE2-A at 310 KCPE2-A = 1.39E-10 at 310 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 CPE2-A at 315 KCPE2-A = 1.47E-10 at 315 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 CPE2-A at 320 KCPE2-A = 1.56E-10 at 320 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 CPE2-A at 325 KCPE2-A = 1.58E-10 at 325 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 CPE2-A at 330 KCPE2-A = 1.65E-10 at 330 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 CPE2-A at 335 KCPE2-A = 1.70E-10 at 335 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 CPE2-A at 340 KCPE2-A = 1.73E-10 at 340 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 CPE2-A at 345 KCPE2-A = 1.75E-10 at 345 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 CPE2-A at 350 KCPE2-A = 1.80E-10 at 350 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 CPE2-A at 355 KCPE2-A = 1.82E-10 at 355 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 CPE2-A at 360 KCPE2-A = 1.82E-10 at 360 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 CPE2-alpha at 300 KCPE2-alpha = 0.917 at 300 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 CPE2-alpha at 305 KCPE2-alpha = 0.911 at 305 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 CPE2-alpha at 310 KCPE2-alpha = 0.907 at 310 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 CPE2-alpha at 315 KCPE2-alpha = 0.902 at 315 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 CPE2-alpha at 320 KCPE2-alpha = 0.897 at 320 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 CPE2-alpha at 325 KCPE2-alpha = 0.897 at 325 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 CPE2-alpha at 330 KCPE2-alpha = 0.895 at 330 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 CPE2-alpha at 335 KCPE2-alpha = 0.893 at 335 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 CPE2-alpha at 340 KCPE2-alpha = 0.893 at 340 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 CPE2-alpha at 345 KCPE2-alpha = 0.894 at 345 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 CPE2-alpha at 350 KCPE2-alpha = 0.893 at 350 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 CPE2-alpha at 355 KCPE2-alpha = 0.894 at 355 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 CPE2-alpha at 360 KCPE2-alpha = 0.896 at 360 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 R1 at 300 KR1 = 547330 ohm at 300 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 R1 at 305 KR1 = 423790 ohm at 305 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 R1 at 310 KR1 = 331650 ohm at 310 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 R1 at 315 KR1 = 258210 ohm at 315 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 R1 at 320 KR1 = 200360 ohm at 320 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 R1 at 325 KR1 = 158160 ohm at 325 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 R1 at 330 KR1 = 121370 ohm at 330 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 R1 at 335 KR1 = 93921 ohm at 335 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 R1 at 340 KR1 = 73092 ohm at 340 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 R1 at 345 KR1 = 58355 ohm at 345 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 R1 at 350 KR1 = 46106 ohm at 350 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 R1 at 355 KR1 = 38436 ohm at 355 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 R1 at 360 KR1 = 33032 ohm at 360 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 R2 at 300 KR2 = 2.55E+08 ohm at 300 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 R2 at 305 KR2 = 2.84E+08 ohm at 305 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 R2 at 310 KR2 = 2.82E+08 ohm at 310 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 R2 at 315 KR2 = 3.28E+08 ohm at 315 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 R2 at 320 KR2 = 4.51E+08 ohm at 320 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 R2 at 325 KR2 = 3.29E+08 ohm at 325 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 R2 at 330 KR2 = 3.00E+08 ohm at 330 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 R2 at 335 KR2 = 3.07E+08 ohm at 335 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 R2 at 340 KR2 = 2.52E+08 ohm at 340 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 R2 at 345 KR2 = 2.25E+08 ohm at 345 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 R2 at 350 KR2 = 1.96E+08 ohm at 350 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 R2 at 355 KR2 = 1.72E+08 ohm at 355 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S1 R2 at 360 KR2 = 1.30E+08 ohm at 360 K——SI Table
Exact Reported		SI p.S6 · Table S1 · Table S1
Table S2 bulk dielectric constant epsilon1 at 300 Kepsilon1' = 33.8 at 300 K——SI Table
Exact Reported		SI p.S7 · Table S2 · Table S2
Table S2 bulk dielectric constant epsilon1 at 305 Kepsilon1' = 34.7 at 305 K——SI Table
Exact Reported		SI p.S7 · Table S2 · Table S2
Table S2 bulk dielectric constant epsilon1 at 310 Kepsilon1' = 35.8 at 310 K——SI Table
Exact Reported		SI p.S7 · Table S2 · Table S2
Table S2 bulk dielectric constant epsilon1 at 315 Kepsilon1' = 36.7 at 315 K——SI Table
Exact Reported		SI p.S7 · Table S2 · Table S2
Table S2 bulk dielectric constant epsilon1 at 320 Kepsilon1' = 37.2 at 320 K——SI Table
Exact Reported		SI p.S7 · Table S2 · Table S2
Table S2 bulk dielectric constant epsilon1 at 325 Kepsilon1' = 39.8 at 325 K——SI Table
Exact Reported		SI p.S7 · Table S2 · Table S2
Table S2 bulk dielectric constant epsilon1 at 330 Kepsilon1' = 41.4 at 330 K——SI Table
Exact Reported		SI p.S7 · Table S2 · Table S2
Table S2 bulk dielectric constant epsilon1 at 335 Kepsilon1' = 44.5 at 335 K——SI Table
Exact Reported		SI p.S7 · Table S2 · Table S2
Table S2 bulk dielectric constant epsilon1 at 340 Kepsilon1' = 48.8 at 340 K——SI Table
Exact Reported		SI p.S7 · Table S2 · Table S2
Table S2 bulk dielectric constant epsilon1 at 345 Kepsilon1' = 53.8 at 345 K——SI Table
Exact Reported		SI p.S7 · Table S2 · Table S2
Table S2 bulk dielectric constant epsilon1 at 350 Kepsilon1' = 58.6 at 350 K——SI Table
Exact Reported		SI p.S7 · Table S2 · Table S2
Table S2 bulk dielectric constant epsilon1 at 355 Kepsilon1' = 64.8 at 355 K——SI Table
Exact Reported		SI p.S7 · Table S2 · Table S2
Table S2 bulk dielectric constant epsilon1 at 360 Kepsilon1' = 73.3 at 360 K——SI Table
Exact Reported		SI p.S7 · Table S2 · Table S2
Table S2 interface dielectric constant epsilon2 at 300 Kepsilon2' = 35.0 at 300 K——SI Table
Exact Reported		SI p.S7 · Table S2 · Table S2
Table S2 interface dielectric constant epsilon2 at 305 Kepsilon2' = 37.2 at 305 K——SI Table
Exact Reported		SI p.S7 · Table S2 · Table S2
Table S2 interface dielectric constant epsilon2 at 310 Kepsilon2' = 39.2 at 310 K——SI Table
Exact Reported		SI p.S7 · Table S2 · Table S2
Table S2 interface dielectric constant epsilon2 at 315 Kepsilon2' = 41.4 at 315 K——SI Table
Exact Reported		SI p.S7 · Table S2 · Table S2
Table S2 interface dielectric constant epsilon2 at 320 Kepsilon2' = 44.0 at 320 K——SI Table
Exact Reported		SI p.S7 · Table S2 · Table S2
Table S2 interface dielectric constant epsilon2 at 325 Kepsilon2' = 44.5 at 325 K——SI Table
Exact Reported		SI p.S7 · Table S2 · Table S2
Table S2 interface dielectric constant epsilon2 at 330 Kepsilon2' = 46.5 at 330 K——SI Table
Exact Reported		SI p.S7 · Table S2 · Table S2
Table S2 interface dielectric constant epsilon2 at 335 Kepsilon2' = 47.9 at 335 K——SI Table
Exact Reported		SI p.S7 · Table S2 · Table S2
Table S2 interface dielectric constant epsilon2 at 340 Kepsilon2' = 48.8 at 340 K——SI Table
Exact Reported		SI p.S7 · Table S2 · Table S2
Table S2 interface dielectric constant epsilon2 at 345 Kepsilon2' = 49.3 at 345 K——SI Table
Exact Reported		SI p.S7 · Table S2 · Table S2
Table S2 interface dielectric constant epsilon2 at 350 Kepsilon2' = 50.7 at 350 K——SI Table
Exact Reported		SI p.S7 · Table S2 · Table S2
Table S2 interface dielectric constant epsilon2 at 355 Kepsilon2' = 51.3 at 355 K——SI Table
Exact Reported		SI p.S7 · Table S2 · Table S2
Table S2 interface dielectric constant epsilon2 at 360 Kepsilon2' = 51.3 at 360 K——SI Table
Exact Reported		SI p.S7 · Table S2 · Table S2
Table S2 bulk conductivity sigma1 at 300 KMarked as a best value within this papersigma1 = 4.56E-08 S/cm at 300 K——SI Table
Exact Reported		SI p.S7 · Table S2 · Table S2
Table S2 bulk conductivity sigma1 at 305 Ksigma1 = 5.89E-08 S/cm at 305 K——SI Table
Exact Reported		SI p.S7 · Table S2 · Table S2
Table S2 bulk conductivity sigma1 at 310 Ksigma1 = 7.53E-08 S/cm at 310 K——SI Table
Exact Reported		SI p.S7 · Table S2 · Table S2
Table S2 bulk conductivity sigma1 at 315 Ksigma1 = 9.67E-08 S/cm at 315 K——SI Table
Exact Reported		SI p.S7 · Table S2 · Table S2
Table S2 bulk conductivity sigma1 at 320 Ksigma1 = 1.25E-07 S/cm at 320 K——SI Table
Exact Reported		SI p.S7 · Table S2 · Table S2
Table S2 bulk conductivity sigma1 at 325 Ksigma1 = 1.58E-07 S/cm at 325 K——SI Table
Exact Reported		SI p.S7 · Table S2 · Table S2
Table S2 bulk conductivity sigma1 at 330 Ksigma1 = 2.06E-07 S/cm at 330 K——SI Table
Exact Reported		SI p.S7 · Table S2 · Table S2
Table S2 bulk conductivity sigma1 at 335 Ksigma1 = 2.66E-07 S/cm at 335 K——SI Table
Exact Reported		SI p.S7 · Table S2 · Table S2
Table S2 bulk conductivity sigma1 at 340 Ksigma1 = 3.42E-07 S/cm at 340 K——SI Table
Exact Reported		SI p.S7 · Table S2 · Table S2
Table S2 bulk conductivity sigma1 at 345 Ksigma1 = 4.28E-07 S/cm at 345 K——SI Table
Exact Reported		SI p.S7 · Table S2 · Table S2
Table S2 bulk conductivity sigma1 at 350 Ksigma1 = 5.41E-07 S/cm at 350 K——SI Table
Exact Reported		SI p.S7 · Table S2 · Table S2
Table S2 bulk conductivity sigma1 at 355 Ksigma1 = 6.49E-07 S/cm at 355 K——SI Table
Exact Reported		SI p.S7 · Table S2 · Table S2
Table S2 bulk conductivity sigma1 at 360 Ksigma1 = 7.56E-07 S/cm at 360 K——SI Table
Exact Reported		SI p.S7 · Table S2 · Table S2
Table S2 interface conductivity sigma2 at 300 Ksigma2 = 9.79E-11 S/cm at 300 K——SI Table
Exact Reported		SI p.S7 · Table S2 · Table S2
Table S2 interface conductivity sigma2 at 305 Ksigma2 = 8.79E-11 S/cm at 305 K——SI Table
Exact Reported		SI p.S7 · Table S2 · Table S2
Table S2 interface conductivity sigma2 at 310 Ksigma2 = 8.85E-11 S/cm at 310 K——SI Table
Exact Reported		SI p.S7 · Table S2 · Table S2
Table S2 interface conductivity sigma2 at 315 Ksigma2 = 7.61E-11 S/cm at 315 K——SI Table
Exact Reported		SI p.S7 · Table S2 · Table S2
Table S2 interface conductivity sigma2 at 320 Ksigma2 = 5.53E-11 S/cm at 320 K——SI Table
Exact Reported		SI p.S7 · Table S2 · Table S2
Table S2 interface conductivity sigma2 at 325 Ksigma2 = 7.59E-11 S/cm at 325 K——SI Table
Exact Reported		SI p.S7 · Table S2 · Table S2
Table S2 interface conductivity sigma2 at 330 Ksigma2 = 8.32E-11 S/cm at 330 K——SI Table
Exact Reported		SI p.S7 · Table S2 · Table S2
Table S2 interface conductivity sigma2 at 335 Ksigma2 = 8.13E-11 S/cm at 335 K——SI Table
Exact Reported		SI p.S7 · Table S2 · Table S2
Table S2 interface conductivity sigma2 at 340 Ksigma2 = 9.90E-11 S/cm at 340 K——SI Table
Exact Reported		SI p.S7 · Table S2 · Table S2
Table S2 interface conductivity sigma2 at 345 Ksigma2 = 1.11E-10 S/cm at 345 K——SI Table
Exact Reported		SI p.S7 · Table S2 · Table S2
Table S2 interface conductivity sigma2 at 350 Ksigma2 = 1.27E-10 S/cm at 350 K——SI Table
Exact Reported		SI p.S7 · Table S2 · Table S2
Table S2 interface conductivity sigma2 at 355 Ksigma2 = 1.45E-10 S/cm at 355 K——SI Table
Exact Reported		SI p.S7 · Table S2 · Table S2
Table S2 interface conductivity sigma2 at 360 Ksigma2 = 1.92E-10 S/cm at 360 K——SI Table
Exact Reported		SI p.S7 · Table S2 · Table S2
Table S3 constrained-fit CPE1-A at 300 KCPE1-A = 1.51E-10 at 300 K——SI Table
Exact Reported		SI p.S8-S9 · Table S3 · Table S3
Table S3 constrained-fit CPE1-A at 305 KCPE1-A = 1.53E-10 at 305 K——SI Table
Exact Reported		SI p.S8-S9 · Table S3 · Table S3
Table S3 constrained-fit CPE1-A at 310 KCPE1-A = 1.54E-10 at 310 K——SI Table
Exact Reported		SI p.S8-S9 · Table S3 · Table S3
Table S3 constrained-fit CPE1-A at 315 KCPE1-A = 1.55E-10 at 315 K——SI Table
Exact Reported		SI p.S8-S9 · Table S3 · Table S3
Table S3 constrained-fit CPE1-A at 320 KCPE1-A = 1.56E-10 at 320 K——SI Table
Exact Reported		SI p.S8-S9 · Table S3 · Table S3
Table S3 constrained-fit CPE1-A at 325 KCPE1-A = 1.59E-10 at 325 K——SI Table
Exact Reported		SI p.S8-S9 · Table S3 · Table S3
Table S3 constrained-fit CPE1-A at 330 KCPE1-A = 1.60E-10 at 330 K——SI Table
Exact Reported		SI p.S8-S9 · Table S3 · Table S3
Table S3 constrained-fit CPE1-A at 335 KCPE1-A = 1.60E-10 at 335 K——SI Table
Exact Reported		SI p.S8-S9 · Table S3 · Table S3
Table S3 constrained-fit CPE1-A at 340 KCPE1-A = 1.61E-10 at 340 K——SI Table
Exact Reported		SI p.S8-S9 · Table S3 · Table S3
Table S3 constrained-fit CPE1-A at 345 KCPE1-A = 1.61E-10 at 345 K——SI Table
Exact Reported		SI p.S8-S9 · Table S3 · Table S3
Table S3 constrained-fit CPE1-A at 350 KCPE1-A = 1.61E-10 at 350 K——SI Table
Exact Reported		SI p.S8-S9 · Table S3 · Table S3
Table S3 constrained-fit CPE1-A at 355 KCPE1-A = 1.61E-10 at 355 K——SI Table
Exact Reported		SI p.S8-S9 · Table S3 · Table S3
Table S3 constrained-fit CPE1-A at 360 KCPE1-A = 1.63E-10 at 360 K——SI Table
Exact Reported		SI p.S8-S9 · Table S3 · Table S3
Table S3 constrained-fit CPE2-A at 300 KCPE2-A = 1.43E-10 at 300 K——SI Table
Exact Reported		SI p.S8-S9 · Table S3 · Table S3
Table S3 constrained-fit CPE2-A at 305 KCPE2-A = 1.46E-10 at 305 K——SI Table
Exact Reported		SI p.S8-S9 · Table S3 · Table S3
Table S3 constrained-fit CPE2-A at 310 KCPE2-A = 1.48E-10 at 310 K——SI Table
Exact Reported		SI p.S8-S9 · Table S3 · Table S3
Table S3 constrained-fit CPE2-A at 315 KCPE2-A = 1.51E-10 at 315 K——SI Table
Exact Reported		SI p.S8-S9 · Table S3 · Table S3
Table S3 constrained-fit CPE2-A at 320 KCPE2-A = 1.54E-10 at 320 K——SI Table
Exact Reported		SI p.S8-S9 · Table S3 · Table S3
Table S3 constrained-fit CPE2-A at 325 KCPE2-A = 1.56E-10 at 325 K——SI Table
Exact Reported		SI p.S8-S9 · Table S3 · Table S3
Table S3 constrained-fit CPE2-A at 330 KCPE2-A = 1.59E-10 at 330 K——SI Table
Exact Reported		SI p.S8-S9 · Table S3 · Table S3
Table S3 constrained-fit CPE2-A at 335 KCPE2-A = 1.62E-10 at 335 K——SI Table
Exact Reported		SI p.S8-S9 · Table S3 · Table S3
Table S3 constrained-fit CPE2-A at 340 KCPE2-A = 1.65E-10 at 340 K——SI Table
Exact Reported		SI p.S8-S9 · Table S3 · Table S3
Table S3 constrained-fit CPE2-A at 345 KCPE2-A = 1.68E-10 at 345 K——SI Table
Exact Reported		SI p.S8-S9 · Table S3 · Table S3
Table S3 constrained-fit CPE2-A at 350 KCPE2-A = 1.71E-10 at 350 K——SI Table
Exact Reported		SI p.S8-S9 · Table S3 · Table S3
Table S3 constrained-fit CPE2-A at 355 KCPE2-A = 1.73E-10 at 355 K——SI Table
Exact Reported		SI p.S8-S9 · Table S3 · Table S3
Table S3 constrained-fit CPE2-A at 360 KCPE2-A = 1.76E-10 at 360 K——SI Table
Exact Reported		SI p.S8-S9 · Table S3 · Table S3
Table S3 constrained-fit R1 at 300 KR1 = 511230 ohm at 300 K——SI Table
Exact Reported		SI p.S8-S9 · Table S3 · Table S3
Table S3 constrained-fit R1 at 305 KR1 = 406700 ohm at 305 K——SI Table
Exact Reported		SI p.S8-S9 · Table S3 · Table S3
Table S3 constrained-fit R1 at 310 KR1 = 325130 ohm at 310 K——SI Table
Exact Reported		SI p.S8-S9 · Table S3 · Table S3
Table S3 constrained-fit R1 at 315 KR1 = 263050 ohm at 315 K——SI Table
Exact Reported		SI p.S8-S9 · Table S3 · Table S3
Table S3 constrained-fit R1 at 320 KR1 = 213340 ohm at 320 K——SI Table
Exact Reported		SI p.S8-S9 · Table S3 · Table S3
Table S3 constrained-fit R1 at 325 KR1 = 166920 ohm at 325 K——SI Table
Exact Reported		SI p.S8-S9 · Table S3 · Table S3
Table S3 constrained-fit R1 at 330 KR1 = 130880 ohm at 330 K——SI Table
Exact Reported		SI p.S8-S9 · Table S3 · Table S3
Table S3 constrained-fit R1 at 335 KR1 = 102100 ohm at 335 K——SI Table
Exact Reported		SI p.S8-S9 · Table S3 · Table S3
Table S3 constrained-fit R1 at 340 KR1 = 78192 ohm at 340 K——SI Table
Exact Reported		SI p.S8-S9 · Table S3 · Table S3
Table S3 constrained-fit R1 at 345 KR1 = 60933 ohm at 345 K——SI Table
Exact Reported		SI p.S8-S9 · Table S3 · Table S3
Table S3 constrained-fit R1 at 350 KR1 = 48076 ohm at 350 K——SI Table
Exact Reported		SI p.S8-S9 · Table S3 · Table S3
Table S3 constrained-fit R1 at 355 KR1 = 39301 ohm at 355 K——SI Table
Exact Reported		SI p.S8-S9 · Table S3 · Table S3
Table S3 constrained-fit R1 at 360 KR1 = 32352 ohm at 360 K——SI Table
Exact Reported		SI p.S8-S9 · Table S3 · Table S3
Table S3 constrained-fit R2 at 300 KR2 = 5.38E+08 ohm at 300 K——SI Table
Exact Reported		SI p.S8-S9 · Table S3 · Table S3
Table S3 constrained-fit R2 at 305 KR2 = 5.01E+08 ohm at 305 K——SI Table
Exact Reported		SI p.S8-S9 · Table S3 · Table S3
Table S3 constrained-fit R2 at 310 KR2 = 3.99E+08 ohm at 310 K——SI Table
Exact Reported		SI p.S8-S9 · Table S3 · Table S3
Table S3 constrained-fit R2 at 315 KR2 = 3.91E+08 ohm at 315 K——SI Table
Exact Reported		SI p.S8-S9 · Table S3 · Table S3
Table S3 constrained-fit R2 at 320 KR2 = 4.36E+08 ohm at 320 K——SI Table
Exact Reported		SI p.S8-S9 · Table S3 · Table S3
Table S3 constrained-fit R2 at 325 KR2 = 3.09E+08 ohm at 325 K——SI Table
Exact Reported		SI p.S8-S9 · Table S3 · Table S3
Table S3 constrained-fit R2 at 330 KR2 = 2.56E+08 ohm at 330 K——SI Table
Exact Reported		SI p.S8-S9 · Table S3 · Table S3
Table S3 constrained-fit R2 at 335 KR2 = 2.44E+08 ohm at 335 K——SI Table
Exact Reported		SI p.S8-S9 · Table S3 · Table S3
Table S3 constrained-fit R2 at 340 KR2 = 2.06E+08 ohm at 340 K——SI Table
Exact Reported		SI p.S8-S9 · Table S3 · Table S3
Table S3 constrained-fit R2 at 345 KR2 = 1.88E+08 ohm at 345 K——SI Table
Exact Reported		SI p.S8-S9 · Table S3 · Table S3
Table S3 constrained-fit R2 at 350 KR2 = 1.63E+08 ohm at 350 K——SI Table
Exact Reported		SI p.S8-S9 · Table S3 · Table S3
Table S3 constrained-fit R2 at 355 KR2 = 1.46E+08 ohm at 355 K——SI Table
Exact Reported		SI p.S8-S9 · Table S3 · Table S3
Table S3 constrained-fit R2 at 360 KR2 = 1.18E+08 ohm at 360 K——SI Table
Exact Reported		SI p.S8-S9 · Table S3 · Table S3
Table S4 constrained-fit bulk dielectric constant epsilon1 at 300 Kepsilon1' = 42.6 at 300 K——SI Table
Exact Reported		SI p.S9 · Table S4 · Table S4
Table S4 constrained-fit bulk dielectric constant epsilon1 at 305 Kepsilon1' = 43.1 at 305 K——SI Table
Exact Reported		SI p.S9 · Table S4 · Table S4
Table S4 constrained-fit bulk dielectric constant epsilon1 at 310 Kepsilon1' = 43.4 at 310 K——SI Table
Exact Reported		SI p.S9 · Table S4 · Table S4
Table S4 constrained-fit bulk dielectric constant epsilon1 at 315 Kepsilon1' = 43.7 at 315 K——SI Table
Exact Reported		SI p.S9 · Table S4 · Table S4
Table S4 constrained-fit bulk dielectric constant epsilon1 at 320 Kepsilon1' = 44.0 at 320 K——SI Table
Exact Reported		SI p.S9 · Table S4 · Table S4
Table S4 constrained-fit bulk dielectric constant epsilon1 at 325 Kepsilon1' = 44.8 at 325 K——SI Table
Exact Reported		SI p.S9 · Table S4 · Table S4
Table S4 constrained-fit bulk dielectric constant epsilon1 at 330 Kepsilon1' = 45.1 at 330 K——SI Table
Exact Reported		SI p.S9 · Table S4 · Table S4
Table S4 constrained-fit bulk dielectric constant epsilon1 at 335 Kepsilon1' = 45.1 at 335 K——SI Table
Exact Reported		SI p.S9 · Table S4 · Table S4
Table S4 constrained-fit bulk dielectric constant epsilon1 at 340 Kepsilon1' = 45.4 at 340 K——SI Table
Exact Reported		SI p.S9 · Table S4 · Table S4
Table S4 constrained-fit bulk dielectric constant epsilon1 at 345 Kepsilon1' = 45.4 at 345 K——SI Table
Exact Reported		SI p.S9 · Table S4 · Table S4
Table S4 constrained-fit bulk dielectric constant epsilon1 at 350 Kepsilon1' = 45.4 at 350 K——SI Table
Exact Reported		SI p.S9 · Table S4 · Table S4
Table S4 constrained-fit bulk dielectric constant epsilon1 at 355 Kepsilon1' = 45.4 at 355 K——SI Table
Exact Reported		SI p.S9 · Table S4 · Table S4
Table S4 constrained-fit bulk dielectric constant epsilon1 at 360 Kepsilon1' = 46.0 at 360 K——SI Table
Exact Reported		SI p.S9 · Table S4 · Table S4
Table S4 constrained-fit interface dielectric constant epsilon2 at 300 Kepsilon2' = 40.3 at 300 K——SI Table
Exact Reported		SI p.S9 · Table S4 · Table S4
Table S4 constrained-fit interface dielectric constant epsilon2 at 305 Kepsilon2' = 41.2 at 305 K——SI Table
Exact Reported		SI p.S9 · Table S4 · Table S4
Table S4 constrained-fit interface dielectric constant epsilon2 at 310 Kepsilon2' = 41.7 at 310 K——SI Table
Exact Reported		SI p.S9 · Table S4 · Table S4
Table S4 constrained-fit interface dielectric constant epsilon2 at 315 Kepsilon2' = 42.6 at 315 K——SI Table
Exact Reported		SI p.S9 · Table S4 · Table S4
Table S4 constrained-fit interface dielectric constant epsilon2 at 320 Kepsilon2' = 43.4 at 320 K——SI Table
Exact Reported		SI p.S9 · Table S4 · Table S4
Table S4 constrained-fit interface dielectric constant epsilon2 at 325 Kepsilon2' = 44.0 at 325 K——SI Table
Exact Reported		SI p.S9 · Table S4 · Table S4
Table S4 constrained-fit interface dielectric constant epsilon2 at 330 Kepsilon2' = 44.8 at 330 K——SI Table
Exact Reported		SI p.S9 · Table S4 · Table S4
Table S4 constrained-fit interface dielectric constant epsilon2 at 335 Kepsilon2' = 45.7 at 335 K——SI Table
Exact Reported		SI p.S9 · Table S4 · Table S4
Table S4 constrained-fit interface dielectric constant epsilon2 at 340 Kepsilon2' = 46.5 at 340 K——SI Table
Exact Reported		SI p.S9 · Table S4 · Table S4
Table S4 constrained-fit interface dielectric constant epsilon2 at 345 Kepsilon2' = 47.4 at 345 K——SI Table
Exact Reported		SI p.S9 · Table S4 · Table S4
Table S4 constrained-fit interface dielectric constant epsilon2 at 350 Kepsilon2' = 48.2 at 350 K——SI Table
Exact Reported		SI p.S9 · Table S4 · Table S4
Table S4 constrained-fit interface dielectric constant epsilon2 at 355 Kepsilon2' = 48.8 at 355 K——SI Table
Exact Reported		SI p.S9 · Table S4 · Table S4
Table S4 constrained-fit interface dielectric constant epsilon2 at 360 Kepsilon2' = 49.6 at 360 K——SI Table
Exact Reported		SI p.S9 · Table S4 · Table S4
Table S4 constrained-fit bulk conductivity sigma1 at 300 KMarked as a best value within this papersigma1 = 4.88E-08 S/cm at 300 K——SI Table
Exact Reported		SI p.S9 · Table S4 · Table S4
Table S4 constrained-fit bulk conductivity sigma1 at 305 Ksigma1 = 6.14E-08 S/cm at 305 K——SI Table
Exact Reported		SI p.S9 · Table S4 · Table S4
Table S4 constrained-fit bulk conductivity sigma1 at 310 Ksigma1 = 7.68E-08 S/cm at 310 K——SI Table
Exact Reported		SI p.S9 · Table S4 · Table S4
Table S4 constrained-fit bulk conductivity sigma1 at 315 Ksigma1 = 9.49E-08 S/cm at 315 K——SI Table
Exact Reported		SI p.S9 · Table S4 · Table S4
Table S4 constrained-fit bulk conductivity sigma1 at 320 Ksigma1 = 1.17E-07 S/cm at 320 K——SI Table
Exact Reported		SI p.S9 · Table S4 · Table S4
Table S4 constrained-fit bulk conductivity sigma1 at 325 Ksigma1 = 1.50E-07 S/cm at 325 K——SI Table
Exact Reported		SI p.S9 · Table S4 · Table S4
Table S4 constrained-fit bulk conductivity sigma1 at 330 Ksigma1 = 1.91E-07 S/cm at 330 K——SI Table
Exact Reported		SI p.S9 · Table S4 · Table S4
Table S4 constrained-fit bulk conductivity sigma1 at 335 Ksigma1 = 2.44E-07 S/cm at 335 K——SI Table
Exact Reported		SI p.S9 · Table S4 · Table S4
Table S4 constrained-fit bulk conductivity sigma1 at 340 Ksigma1 = 3.19E-07 S/cm at 340 K——SI Table
Exact Reported		SI p.S9 · Table S4 · Table S4
Table S4 constrained-fit bulk conductivity sigma1 at 345 Ksigma1 = 4.10E-07 S/cm at 345 K——SI Table
Exact Reported		SI p.S9 · Table S4 · Table S4
Table S4 constrained-fit bulk conductivity sigma1 at 350 Ksigma1 = 5.19E-07 S/cm at 350 K——SI Table
Exact Reported		SI p.S9 · Table S4 · Table S4
Table S4 constrained-fit bulk conductivity sigma1 at 355 Ksigma1 = 6.35E-07 S/cm at 355 K——SI Table
Exact Reported		SI p.S9 · Table S4 · Table S4
Table S4 constrained-fit bulk conductivity sigma1 at 360 Ksigma1 = 7.72E-07 S/cm at 360 K——SI Table
Exact Reported		SI p.S9 · Table S4 · Table S4
Table S4 constrained-fit interface conductivity sigma2 at 300 Ksigma2 = 4.64E-11 S/cm at 300 K——SI Table
Exact Reported		SI p.S9 · Table S4 · Table S4
Table S4 constrained-fit interface conductivity sigma2 at 305 Ksigma2 = 4.98E-11 S/cm at 305 K——SI Table
Exact Reported		SI p.S9 · Table S4 · Table S4
Table S4 constrained-fit interface conductivity sigma2 at 310 Ksigma2 = 6.25E-11 S/cm at 310 K——SI Table
Exact Reported		SI p.S9 · Table S4 · Table S4
Table S4 constrained-fit interface conductivity sigma2 at 315 Ksigma2 = 6.38E-11 S/cm at 315 K——SI Table
Exact Reported		SI p.S9 · Table S4 · Table S4
Table S4 constrained-fit interface conductivity sigma2 at 320 Ksigma2 = 5.72E-11 S/cm at 320 K——SI Table
Exact Reported		SI p.S9 · Table S4 · Table S4
Table S4 constrained-fit interface conductivity sigma2 at 325 Ksigma2 = 8.07E-11 S/cm at 325 K——SI Table
Exact Reported		SI p.S9 · Table S4 · Table S4
Table S4 constrained-fit interface conductivity sigma2 at 330 Ksigma2 = 9.75E-11 S/cm at 330 K——SI Table
Exact Reported		SI p.S9 · Table S4 · Table S4
Table S4 constrained-fit interface conductivity sigma2 at 335 Ksigma2 = 1.02E-10 S/cm at 335 K——SI Table
Exact Reported		SI p.S9 · Table S4 · Table S4
Table S4 constrained-fit interface conductivity sigma2 at 340 Ksigma2 = 1.21E-10 S/cm at 340 K——SI Table
Exact Reported		SI p.S9 · Table S4 · Table S4
Table S4 constrained-fit interface conductivity sigma2 at 345 Ksigma2 = 1.33E-10 S/cm at 345 K——SI Table
Exact Reported		SI p.S9 · Table S4 · Table S4
Table S4 constrained-fit interface conductivity sigma2 at 350 Ksigma2 = 1.53E-10 S/cm at 350 K——SI Table
Exact Reported		SI p.S9 · Table S4 · Table S4
Table S4 constrained-fit interface conductivity sigma2 at 355 Ksigma2 = 1.71E-10 S/cm at 355 K——SI Table
Exact Reported		SI p.S9 · Table S4 · Table S4
Table S4 constrained-fit interface conductivity sigma2 at 360 Ksigma2 = 2.12E-10 S/cm at 360 K——SI Table
Exact Reported		SI p.S9 · Table S4 · Table S4

Single-crystal DC current-voltage measurement

Electrical conductivity

Yellow needle-shaped single crystals of 1 · Single Crystal

6517A electrometer; gold electrodes pasted on both sides of one single crystal; low-voltage ohmic region fitted.

Geometry
Cross-sectional area A = 2.95 x 10^-4 cm2; electrode distance l = 1.70 x 10^2 um; dimensions estimated by laser microscope.
Context
pristine_framework
Measurement source
main p.2 / article p.35 · Single crystal DC conductivity · Fig. 3
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Single-crystal cross-sectional areaA = 2.95 x 10^-4 cm2——Text
Exact Reported		main p.2 / article p.35 · Single crystal DC conductivity · Fig. 3 inset
Single-crystal DC conductivityMarked as a best value within this paper1.83 x 10^-8 S/cm——Text
Exact Reported		main p.2 / article p.35 · Single crystal DC conductivity · Fig. 3
Single-crystal electrode distancel = 1.70 x 10^2 um——Text
Exact Reported		main p.2 / article p.35 · Single crystal DC conductivity · Fig. 3 inset
Low-voltage I-V behaviourCurrent increased proportionally with applied voltage in low-voltage region——Text
Qualitative		main p.2 / article p.35 · Single crystal DC conductivity · Fig. 3