Partial recipeSource: Both
Route 1: Other
1.2. Synthesis of [CuI(3-Py-CHO)]n (1)
Metal precursorsCuI (0.95 g, 5.0 mmol)
Linker precursors3-pyridinecarboxaldehyde / 3-Py-CHO (0.47 mL, 5.0 mmol)
SolventsAcetonitrile (100 mL) for CuI solution; CH2Cl2 (100 mL) for 3-Py-CHO solution
Atmospherenot reported
Temperatureroom temperature
Timeseveral hours
Work-upCuI solution was added to linker solution; reaction mixture was filtered; yellow needle-shaped crystals formed after standing; isolated yield 0.73 g, 49%.
Activationnone reported
Scalability contextBatch solution crystallisation on 5.0 mmol reagent scale; no scale-up or film/device synthesis reported.
Show 4 structured reagent records
| Role | Reagent | Amount / concentration | Source |
|---|---|---|---|
| Metal Source | CuI | 0.95 g, 5.0 mmol | 1.2. Synthesis of [CuI(3-Py-CHO)]n (1) |
| Linker | 3-Py-CHO (3-pyridinecarboxaldehyde) | 0.47 mL, 5.0 mmol | 1.2. Synthesis of [CuI(3-Py-CHO)]n (1) |
| Solvent | acetonitrile | 100 mL | 1.2. Synthesis of [CuI(3-Py-CHO)]n (1) |
| Solvent | CH2Cl2 | 100 mL | 1.2. Synthesis of [CuI(3-Py-CHO)]n (1) |