Salman F., Zengin A., Celik Kazici H. · Ionics · 2020 · 5221-5232
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
The sensor was applicable to H2O2 detection in an industrial hair lightener sample.
Caveat: Only one industrial sample type is reported.
5230 · Analytical application · Table 3 · Linked to 3 structured results
The MIL-101(Fe)@Fe3O4/NGCE sensor showed low DPV LOD and high CA sensitivity for non-enzymatic H2O2 sensing.
Caveat: Application performance is for the composite electrode, not pristine MIL-101(Fe).
5221 · Abstract · Linked to 4 structured results
The improved H2O2 response was attributed to metal nanoparticles with high electrical conductivity and iron redox activity.
Caveat: No direct electrical conductivity measurement was reported for the powder or electrode; this is an interpretation from electrochemical response.
5224 · Electrochemical properties · Fig. 4 · Linked to 3 structured results
MIL-101(Fe) formed a shell on Fe3O4 nanoparticles and the Fe3O4 crystallinity was preserved after coating.
Caveat: No CIF or Rietveld refinement supplied in the assigned documents.
5224 · XRD analysis · Fig. 3 · Linked to 4 structured results
XPS O 1s and C 1s features were interpreted as evidence that Fe3+ ions coordinated with H3btc to form MIL-101(Fe) on Fe3O4.
Caveat: Assignment is based on fitted XPS peak positions rather than direct structural refinement.
5224 · XPS analysis · Fig. 2 · Linked to 3 structured results
The H2O2 electrochemical reaction on MIL-101(Fe)@Fe3O4/NGCE was assigned to a diffusion-controlled process.
Caveat: Based on linear dependence of peak current on square root of scan rate.
5225 · Electrochemical properties · Fig. 5 · Linked to 2 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| Fe3O4 nanoparticles | Fe3O4iron oxide nanoparticle core | 0D · Pristinespherical magnetic nanoparticles used as the core/support for MIL-101(Fe) growth | 5223 · SEM and TEM analysis · Fig. 1a,c |
| MIL-101(Fe)@Fe3O4 | MIL-101(Fe) shell on Fe3O4 coreFe3+ MIL-101 nodes plus Fe3O4 core · benzene-1,3,5-tricarboxylate (H3btc-derived) | 3D · Compositecore-shell magnetic MOF nanoparticles with MIL-101(Fe) layer on Fe3O4 | 5223 · SEM and TEM analysis · Fig. 1d |
| MIL-101(Fe)@Fe3O4/NGCE | MIL-101(Fe)@Fe3O4 plus Nafion on glassy carbon electrodeFe3+ MIL-101 nodes plus Fe3O4 core · benzene-1,3,5-tricarboxylate (H3btc-derived) | 3D · CompositeNafion glassy carbon electrode modified with MIL-101(Fe)@Fe3O4 nanocomposite | 5222 · Preparation of the MIL-101(Fe)@Fe3O4/NGCE sensor |
| Nafion glassy carbon electrode | Nafion/GCE | unknown · Model Systembare NGCE electrode control | 5224 · Electrochemical properties of MIL-101(Fe)@Fe3O4/NGCE · Fig. 4 |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| bare NGCEresearch_0465__mat__m_ngce | Electrode · Pristine Control · Unknown | polished GCE with Nafion control surfaceglassy carbon electrode | 5224 · Electrochemical properties of MIL-101(Fe)@Fe3O4/NGCE · Fig. 4 |
| Fe3O4 nanoparticlesresearch_0465__mat__m_fe3o4_np | Powder · Composite Component · Unknown | solvothermal magnetic nanoparticles, later MAA-modified for MOF growth | 5222 · Preparation of Fe3O4@MIL-101(Fe) nanoparticles |
| MIL-101(Fe)@Fe3O4/NGCE sensorresearch_0465__mat__m_mil101_fe_fe3o4_ngce | Electrode · Target Sample · Composite | MIL-101(Fe)@Fe3O4/Nafion dispersion drop-moulded on polished NGCE and dried at 70 CNafion glassy carbon electrode | 5222 · Preparation of the MIL-101(Fe)@Fe3O4/NGCE sensor |
| MIL-101(Fe)@Fe3O4 nanoparticlesresearch_0465__mat__m_mil101_fe_fe3o4 | Powder · Target Sample · Composite | layer-by-layer FeCl3/H3btc growth on MAA@Fe3O4, dried under vacuum at 200 CFe3O4 nanoparticle core · MOF shell approximately 25 nm | 5223 · SEM and TEM analysis · Fig. 1d |