FT-IR spectroscopy, Bruker Vertex with liquid nitrogen cooled detector
as-synthesized missing-linker aNi-HAB solid · Powder
FTIR comparison of aNi-HAB and cNi-HAB; oxidized HAB FTIR also used for ligand assignment.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| FTIR peak 1022 cm-1 | 1022 cm-1; assigned to in-plane bending of unsubstituted C-H in benzene | — | — | Text Rounded Reported | 431 · Synthesis of conductive 2D MOF · Figure S3c |
| FTIR peak 1132 cm-1 | 1132 cm-1; assigned to quinoid ring | — | — | Caption Rounded Reported | 8 · Figure S3 caption · Figure S3c |
| FTIR peak 1350 cm-1 | 1350 cm-1; assigned to C-N stretching | — | — | Text Rounded Reported | 431 · Synthesis of conductive 2D MOF · Figure S3c |
| FTIR peak 1606 cm-1 | 1606 cm-1; assigned to aromatic ring | — | — | Text Rounded Reported | 431 · Synthesis of conductive 2D MOF · Figure S3c |
| FTIR peak 3220 cm-1 | 3220 cm-1; assigned to associative N-H peak affected by water molecules | — | — | Caption Rounded Reported | 8 · Figure S3 caption · Figure S3c |
| FTIR peak 645 cm-1 | 645 cm-1; assigned to aromatic ring | — | — | Text Rounded Reported | 431 · Synthesis of conductive 2D MOF · Figure S3c |
| FTIR peak 860 cm-1 | 860 cm-1; assigned to in-plane bending of unsubstituted C-H in benzene | — | — | Text Rounded Reported | 431 · Synthesis of conductive 2D MOF · Figure S3c |