Electrical Transport — Air-Stability and Carrier Type in Conductive M3(Hexaaminobenzene)2,(M = Co, Ni, Cu)

3 measurement groups · 14 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Co-HAB pressed-powder pellet · Pellet

Pressed pellet measured from 25 to 125 degC under nitrogen-filled glovebox and ambient conditions

Temperature: 298-398
Atmosphere: nitrogen and ambient air
Geometry: Four gold nanowires around pellet circumference; current and voltage measured across opposite electrode pairs
Context: pristine MOF pellet
Measurement source: S3 · Electrical conductivity measurement · Scheme 1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Restoration of inert electrical conductivity after ambient exposure	fully restored after baking for 1 h at 120 degC	—	—	Text Qualitative	11124 · Results and Discussion
Co-HAB hopping activation energy, ambient	EA,Ambient = 52 meV	—	—	Figure Axis Rounded Reported	11125 · Results and Discussion · Figure 2B
Co-HAB hopping activation energy, nitrogen	EA,Nitrogen = 53 meV	—	—	Figure Axis Rounded Reported	11125 · Results and Discussion · Figure 2B
Co-HAB ambient conductivity retention versus inert	3.5%	0.035 fraction	—	Text Rounded Reported	11124 · Results and Discussion
Co-HAB electrical conductivity near 35 degC, ambient	approximately 0.11 S cm-1	—	—	Figure Axis Approximate	11124 · Results and Discussion · Figure 1B
Co-HAB electrical conductivity near 35 degC, nitrogenMarked as a best value within this paper	approximately 3 S cm-1	—	—	Figure Axis Approximate	11124 · Results and Discussion · Figure 1B

Cu-HAB pressed-powder pellet · Pellet

Pressed pellet measured from 25 to 125 degC under nitrogen-filled glovebox and ambient conditions

Temperature: 298-398
Atmosphere: nitrogen and ambient air
Geometry: Four gold nanowires around pellet circumference; current and voltage measured across opposite electrode pairs
Context: pristine MOF pellet
Measurement source: 11124 · Results and Discussion · Figure 1B

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Cu-HAB hopping activation energy, ambient	EA,Ambient = 291 meV	—	—	Figure Axis Rounded Reported	11126 · Results and Discussion · Figure 2B
Cu-HAB hopping activation energy, nitrogen	EA,Nitrogen = 305 meV	—	—	Figure Axis Rounded Reported	11125 · Results and Discussion · Figure 2B
Cu-HAB electrical conductivity near 35 degC, ambient	approximately 6e-4 S cm-1	—	—	Figure Axis Approximate	11124 · Results and Discussion · Figure 1B
Cu-HAB electrical conductivity near 35 degC, nitrogen	approximately 8e-4 S cm-1	—	—	Figure Axis Approximate	11124 · Results and Discussion · Figure 1B

Ni-HAB pressed-powder pellet · Pellet

Pressed pellet measured from 25 to 125 degC under nitrogen-filled glovebox and ambient conditions

Temperature: 298-398
Atmosphere: nitrogen and ambient air
Geometry: Four gold nanowires around pellet circumference; current and voltage measured across opposite electrode pairs
Context: pristine MOF pellet
Measurement source: 11124 · Results and Discussion · Figure 1B

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Ni-HAB hopping activation energy, ambient	EA,Ambient = 57 meV	—	—	Figure Axis Rounded Reported	11126 · Results and Discussion · Figure 2B
Ni-HAB hopping activation energy, nitrogen	EA,Nitrogen = 75 meV	—	—	Figure Axis Rounded Reported	11125 · Results and Discussion · Figure 2B
Ni-HAB electrical conductivity near 35 degC, ambient	approximately 1.1 S cm-1	—	—	Figure Axis Approximate	11124 · Results and Discussion · Figure 1B
Ni-HAB electrical conductivity near 35 degC, nitrogenMarked as a best value within this paper	approximately 1.0 S cm-1	—	—	Figure Axis Approximate	11124 · Results and Discussion · Figure 1B