Spectroscopy — Air-Stability and Carrier Type in Conductive M3(Hexaaminobenzene)2,(M = Co, Ni, Cu)

Measurement evidence

Spectroscopy

Air-Stability and Carrier Type in Conductive M3(Hexaaminobenzene)2,(M = Co, Ni, Cu) · Hinckley A.C., Park J., Gomes J. et al. · Journal of the American Chemical Society · 2020 · 11123-11130

1 measurement group · 7 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Photoemission spectroscopy in air (PESA)

Co-HAB pressed-powder pellet · Pellet

MOF pellets; HOMO estimated by PESA and LUMO inferred with optical bandgap

Atmosphere: air
Geometry: pressed pellet
Context: representative M-HAB pristine MOF pellets
Measurement source: 11126 · Experimental determination of electronic structure · Figure 3B

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
All M-HAB LUMO levels relative to water oxidation stability criterion	HOMO and LUMO levels of all M-HABs lie below -4.02 eV	—	—	Text Rounded Reported	11126 · Experimental determination of electronic structure · Figure 3B
Co-HAB HOMO level versus vacuum	approximately -4.95 eV	—	—	Figure Axis Approximate	11126 · Experimental determination of electronic structure · Figure 3B
Co-HAB previously reported optical bandgap	0.87 eV	—	—	Text Exact Reported	11124 · Results and Discussion
Cu-HAB HOMO level versus vacuum	approximately -5.30 eV	—	—	Figure Axis Approximate	11126 · Experimental determination of electronic structure · Figure 3B
Cu-HAB previously reported optical bandgap	0.74 eV	—	—	Text Exact Reported	11124 · Results and Discussion
Ni-HAB HOMO level versus vacuum	approximately -4.95 eV	—	—	Figure Axis Approximate	11126 · Experimental determination of electronic structure · Figure 3B
Ni-HAB previously reported optical bandgap	0.57 eV	—	—	Text Exact Reported	11124 · Results and Discussion