Thermoelectric — Air-Stability and Carrier Type in Conductive M3(Hexaaminobenzene)2,(M = Co, Ni, Cu)

4 measurement groups · 7 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Ni-HAB pressed-powder pellet · Pellet

Sealed vacuum desiccator under positive pressure flowing nitrogen with wet/dry nitrogen flow control

Temperature: 298-398
Atmosphere: N2/H2O controlled humidity, no atmospheric oxygen
Geometry: Custom Seebeck setup; resistance mode on Keysight 34972A
Context: representative M-HAB pristine MOF pellets
Measurement source: 11127 · Experimental determination of electronic structure · Figure 4

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Humidity-only effect on M-HAB Seebeck coefficients	no dependence on humidity devoid of atmospheric oxygen	—	—	Text Qualitative	11127 · Experimental determination of electronic structure · Figure 4B

Co-HAB pressed-powder pellet · Pellet

Pressed pellet measured under conditions identical to conductivity measurements

Temperature: 298-398
Atmosphere: nitrogen and ambient air
Geometry: Pellet sandwiched between two gold-coated copper blocks with thermocouples and voltage leads
Context: pristine MOF pellet
Measurement source: S4 · Seebeck coefficient measurement · Scheme 2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Co-HAB Seebeck coefficient near 300 K, ambient	approximately -4.5 microV K-1	—	—	Figure Axis Approximate	S9 · Supplemental Data · Figure S2
Co-HAB Seebeck coefficient near 300 K, nitrogen	approximately -6 microV K-1	—	—	Figure Axis Approximate	11124 · Results and Discussion · Figure 1C

Cu-HAB pressed-powder pellet · Pellet

Pressed pellet measured under nitrogen and ambient conditions

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Cu-HAB Seebeck coefficient near 300 K, ambient	approximately -335 microV K-1	—	—	Figure Axis Approximate	11124 · Results and Discussion · Figure 1C
Cu-HAB Seebeck coefficient near 300 K, nitrogen	approximately -240 microV K-1	—	—	Figure Axis Approximate	11124 · Results and Discussion · Figure 1C

Ni-HAB pressed-powder pellet · Pellet

Pressed pellet measured under nitrogen and ambient conditions

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Ni-HAB Seebeck coefficient at 300 K, ambient	+61.8 microV K-1	—	—	Text Exact Reported	11125 · Results and Discussion · Figure 1C
Ni-HAB Seebeck coefficient at 300 K, nitrogen	-65.1 microV K-1	—	—	Text Exact Reported	11125 · Results and Discussion · Figure 1C