Synthesis · Facile one-pot synthesis of Co coordination polymer spheres doped macroporous carbon and its application for electrocatalytic oxidation of glucose

7 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Complete recipeSource: Main

Route 1: Solvothermal

137 · 2.2

Metal precursorsCo(NO3)2.6H2O, 0.14 g

Linker precursorsisophthalic acid (H2IPA), 0.08 g

Solvents60 mL mixed DMF/acetone 1/1

Atmospherenot specified

Temperature160

Time4 reaction after 6 h stirring

Work-upcollected by centrifugation, washed with fresh DMF three times, dried at 60 deg C

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	Co(NO3)2.6H2O	0.14 g	137 · 2.2
Linker	isophthalic acid (H2IPA)	0.08 g	137 · 2.2
Solvent	N,N-dimethylformamide	part of 60 mL DMF:acetone 1/1	137 · 2.2
Solvent	acetone	part of 60 mL DMF:acetone 1/1	137 · 2.2

Complete recipeSource: Both

Route 2: Solvothermal

137 · 2.3

Metal precursorsCo(NO3)2.6H2O, 0.14 g

Linker precursorsisophthalic acid (H2IPA), 0.08 g

Solvents60 mL mixed DMF/acetone 1/1 by analogy to Co CPSs route

AdditivesMPC, 5 mg

Atmospherenot specified

Temperature160

Time4 reaction after 6 h stirring

Work-upassumed same as Co CPSs route: centrifugation, DMF washing, drying at 60 deg C

Show 3 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	Co(NO3)2.6H2O	0.14 g	137 · 2.3
Linker	H2IPA	0.08 g	137 · 2.3
Additive	MPC	5 mg	137 · 2.3

Complete recipeSource: Both

Route 3: Solvothermal

137 · 2.3

Metal precursorsCo(NO3)2.6H2O, 0.14 g

Linker precursorsisophthalic acid (H2IPA), 0.08 g

Solvents60 mL mixed DMF/acetone 1/1 by analogy to Co CPSs route

AdditivesMPC, 10 mg

Atmospherenot specified

Temperature160

Time4 reaction after 6 h stirring

Work-upassumed same as Co CPSs route: centrifugation, DMF washing, drying at 60 deg C

Show 3 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	Co(NO3)2.6H2O	0.14 g	137 · 2.3
Linker	H2IPA	0.08 g	137 · 2.3
Additive	MPC	10 mg	137 · 2.3

Complete recipeSource: Both

Route 4: Solvothermal

137 · 2.3

Metal precursorsCo(NO3)2.6H2O, 0.14 g

Linker precursorsisophthalic acid (H2IPA), 0.08 g

Solvents60 mL mixed DMF/acetone 1/1 by analogy to Co CPSs route

AdditivesMPC, 20 mg

Atmospherenot specified

Temperature160

Time4 reaction after 6 h stirring

Work-upassumed same as Co CPSs route: centrifugation, DMF washing, drying at 60 deg C

Show 3 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	Co(NO3)2.6H2O	0.14 g	137 · 2.3
Linker	H2IPA	0.08 g	137 · 2.3
Additive	MPC	20 mg	137 · 2.3

Complete recipeSource: Both

Route 5: Solvothermal

137 · 2.3

Metal precursorsCo(NO3)2.6H2O, 0.14 g

Linker precursorsisophthalic acid (H2IPA), 0.08 g

Solvents60 mL mixed DMF/acetone 1/1 by analogy to Co CPSs route

AdditivesMPC, 40 mg

Atmospherenot specified

Temperature160

Time4 reaction after 6 h stirring

Work-upassumed same as Co CPSs route: centrifugation, DMF washing, drying at 60 deg C

Show 3 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	Co(NO3)2.6H2O	0.14 g	137 · 2.3
Linker	H2IPA	0.08 g	137 · 2.3
Additive	MPC	40 mg	137 · 2.3

Complete recipeSource: SI

Route 6: Drop Cast

2-3 · Preparation of the modified electrodes

SolventsDMF, 1 mL

Additives2 mg electrocatalyst

Atmosphereambient drying implied

Temperature25

Substrate orientationglassy carbon electrode working electrode

Work-upGCE polished with 0.05 mm alumina slurry, ultrasonicated in ethanol and double distilled water; 5 uL suspension applied and dried

Show 3 structured reagent records

Role	Reagent	Amount / concentration	Source
Other	electrocatalysts	2 mg · 2 mg mL^-1 in DMF	2-3 · Preparation of the modified electrodes
Solvent	DMF	1 mL	2-3 · Preparation of the modified electrodes
Other	suspension	5 uL	2-3 · Preparation of the modified electrodes

Complete recipeSource: SI

Route 7: Other

2 · Synthesis of MPC

Solventswater; aqueous 98% H2SO4; 10% aqueous HF

AdditivesSiO2 template; 98% H2SO4

AtmosphereN2 during carbonisation

Temperature100; 160; 900

Time3 h vacuum impregnation; 6 h at 100 deg C; 6 h at 160 deg C; 3 h at 900 deg C; overnight HF etch

Work-upSiO2 template etched away by overnight dissolution in 10% aqueous HF

Activationcarbonised at 900 deg C in N2 for 3 h

Show 5 structured reagent records

Role	Reagent	Amount / concentration	Source
Other	SiO2 template	2.0 g	2 · Synthesis of MPC
Other	sucrose	2.0 g	2 · Synthesis of MPC
Solvent	aqueous solution	10 mL	2 · Synthesis of MPC
Acid	H2SO4	0.15 mL · 98%	2 · Synthesis of MPC
Acid	aqueous HF	overnight dissolution · 10%	2 · Synthesis of MPC