Siemensmeyer K., Peeples C.A., Tholen P. et al. · Advanced Materials · 2020 · 2000474
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
The authors suggest phosphonate MOFs like TUB75 could be useful for next-generation electrodes and supercapacitors under harsh operating conditions.
Caveat: No electrochemical supercapacitor measurements are reported in this paper.
5 · conclusion · Linked to 3 structured results
TUB75 contains antiferromagnetically coupled 1D copper dimer chains best described by Heisenberg chains.
Caveat: Low-temperature susceptibility includes a small paramagnetic impurity contribution.
4 · main text · Figure 4 · Linked to 4 structured results
The wide single-crystal conductivity range is interpreted as evidence for directional electrical conductivity in TUB75.
Caveat: The contact area and gold-crystal contact quality are uncertain; authors state actual conductances could be higher.
3 · main text · Linked to 2 structured results
TUB75 is a semiconductor and is reported as the first semiconducting phosphonate MOF.
Caveat: Conductivity values are approximate and orientation/contact dependent.
5 · conclusion · Linked to 4 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| TUB75 | [{Cu2(4,4'-bpy)0.5}(1,4-NDPA)]Cu-based 1D inorganic building unit; zigzag chain of corner-sharing copper dimers · 1,4-naphthalenediphosphonic acid (1,4-NDPA) and 4,4'-bipyridine (4,4'-bpy) | 1D · PristinePhosphonate MOF with 1D copper dimer chains linked by polyaromatic 1,4-NDPA; void channels present in the layer view. | 2 · main text · Figure 1 |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| TUB75 1x3x1 periodic DFT supercellresearch_0517__mat__tub75 | Model · Model System · Model | Geometry-optimised periodic 1x3x1 supercell based on the experimental crystal structure. | 2 · Density functional theory calculations · Figure S3 |
| Hand-picked TUB75 crystalsresearch_0517__mat__tub75 | Single Crystal · Target Sample · Pristine Framework | Pure hand-picked thin green needle crystals; conductivity crystals had average size 0.15 mm x 0.02 mm x 0.02 mm. | 3 · main text |