Synthesis evidence

Phosphonate Metal–Organic Frameworks: A Novel Family of Semiconductors

Siemensmeyer K., Peeples C.A., Tholen P. et al. · Advanced Materials · 2020 · 2000474

1 structured synthesis route

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Partial recipeSource: Both

Route 1: Hydrothermal

3 · Magnetization measurements

Metal precursorsCopper source not specified in the supplied main article or SI.
Linker precursors1,4-naphthalenediphosphonic acid and 4,4'-bipyridine inferred from the reported TUB75 composition; exact reagent form and amounts not supplied.
SolventsHydrothermal reaction medium; exact solvent composition not supplied.
Atmospherenot specified
Temperature>180
Work-upHand-picked crystals used for measurements; detailed workup not supplied.
Show 4 structured reagent records
RoleReagentAmount / concentrationSource
Metal Sourcecopper source not reported in supplied documentsNot specified3 · Magnetization measurements
Linker1,4-naphthalenediphosphonic acidNot specified3 · Magnetization measurements
Linker4,4'-bipyridineNot specified3 · Magnetization measurements
Solventhydrothermal reaction medium not otherwise specifiedNot specified3 · Magnetization measurements