Partial recipeSource: Main
Route 1: Solvothermal
1678-1679 · 2.2 / 3.1 · Figure 1
Metal precursorsCopper(I) iodide (AR, >=99%), 5 mmol
Linker precursorsTCNQ in acetonitrile; amount not reported in the methods passage
SolventsAcetonitrile, 100 mL TCNQ/acetonitrile solution
Atmosphereair/not specified
Temperature60 deg C in Figure 1/results discussion; methods passage only says stirred for 5 min
Time0.083 h by methods stirring time; discussion/Figure 1 imply 10 min
Oxidant / reductantCu(I) acts as in situ reductant for TCNQ
Work-upSeparated by filtration several times, washed with ethanol, dried at 65 deg C overnight.
ActivationNo activation reported beyond drying at 65 deg C overnight.
Scalability contextAuthors state high yield/no pyrolysis generally, but no numerical yield or batch scale beyond reagent amounts is given.
Show 4 structured reagent records
| Role | Reagent | Amount / concentration | Source |
|---|---|---|---|
| Metal Source | Copper(I) iodide | 5 mmol | 1678-1679 · 2.2 / 3.1 · Figure 1 |
| Linker | TCNQ | not reported for Cu route | 1678-1679 · 2.2 / 3.1 · Figure 1 |
| Solvent | Acetonitrile | 100 mL | 1678-1679 · 2.2 / 3.1 · Figure 1 |
| Other | Ethanol wash | Not specified | 1678-1679 · 2.2 / 3.1 · Figure 1 |