Electrochemistry Application — The Advent of Electrically Conducting Double-Helical Metal-Organic Frameworks Featuring Butterfly-Shaped Electron-Rich π-Extended Tetrathiafulvalene Ligands

3 measurement groups · 8 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Cyclic voltammetry

Voltammetry

1 drop-cast thin film on glassy carbon · Thin Film

Pristine dhMOF 1 thin film drop-cast on glassy carbon, vs Ag/AgCl, 0.1 M Bu4NPF6 in MeCN; SI: Princeton Applied Research VersaStat 3-450, glassy carbon working electrode, Ag/AgCl reference, Pt-mesh counter, 0.1 M Bu4NPF6 in MeCN or DMF

Geometry: drop-cast thin film on glassy carbon electrode
Context: pristine framework redox
Measurement source: S-2 · General Materials and Methods · Figure 3; Figure S2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Pristine 1 first anodic peak potential	0.50 V vs Ag/AgCl	—	—	Text Exact Reported	3 · Electrochemical Behavior · Figure 3b,c
Pristine 1 second anodic peak potential	0.66 V vs Ag/AgCl	—	—	Text Exact Reported	3 · Electrochemical Behavior · Figure 3b,c

Cyclic voltammetry

Voltammetry

1a iodine-treated thin film for CV · Thin Film

Iodine-treated 1a vs Ag/AgCl, 0.1 M Bu4NPF6 in MeCN; SI: Princeton Applied Research VersaStat 3-450, glassy carbon working electrode, Ag/AgCl reference, Pt-mesh counter, 0.1 M Bu4NPF6 in MeCN or DMF

Geometry: film/electrode CV; exact construction blocked by missing SI
Context: iodine-treated partially oxidised framework redox
Measurement source: S-2 · General Materials and Methods · Figure 3; Figure S2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Iodine-treated 1a first anodic peak potential	0.53 V vs Ag/AgCl	—	—	Text Exact Reported	3 · Electrochemical Behavior · Figure 3b,d
Iodine-treated 1a second anodic peak potential	0.74 V vs Ag/AgCl	—	—	Text Exact Reported	3 · Electrochemical Behavior · Figure 3b,d
CV cycling stability of 1 and 1a	Multiple CV cycles displayed good agreement among repetitive cycles	—	—	Text Qualitative	S-5 · Supporting figures · Figure S2

Cyclic voltammetry

Voltammetry

Free ExTTFTB ligand · Model

Free ExTTFTB ligand vs Ag/AgCl in 0.1 M Bu4NPF6/DMF; SI: Princeton Applied Research VersaStat 3-450, glassy carbon working electrode, Ag/AgCl reference, Pt-mesh counter, 0.1 M Bu4NPF6 in MeCN or DMF

Geometry: solution CV
Context: free ligand model
Measurement source: S-2 · General Materials and Methods · Figure 3; Figure S2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Free ExTTFTB anodic peak potential	0.66 V vs Ag/AgCl	—	—	Text Exact Reported	3 · Electrochemical Behavior · Figure 3a
Free ExTTFTB cathodic peak potential	0.34 V vs Ag/AgCl	—	—	Text Exact Reported	3 · Electrochemical Behavior · Figure 3a
Free ExTTFTB oxidation midpoint	Eox = 0.50 V vs Ag/AgCl	—	—	Text Exact Reported	3 · Electrochemical Behavior · Figure 3a