Porosity — The Advent of Electrically Conducting Double-Helical Metal-Organic Frameworks Featuring Butterfly-Shaped Electron-Rich π-Extended Tetrathiafulvalene Ligands

2 measurement groups · 4 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

CO2 sorption isotherm with BET surface-area and pore-volume analysis

Gas sorption and porosity

1, activated pristine dhMOF · Powder

Porosity of activated pristine dhMOF; CO2 sorption isotherms are in missing Figure S1; SI: Quantachrome Autosorb iQ Gas Sorption Analyzer after EtOH solvent exchange and high-vacuum activation

Atmosphere: CO2
Context: pristine framework porosity
Measurement source: S-2 · General Materials and Methods · Figure S1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Pore volume of pristine 1Marked as a best value within this paper	5.1 x 10-2 cm3/g	—	—	Text Exact Reported	3 · Synthesis and Structural Characterization · Figure S1 referenced
BET surface area of pristine 1Marked as a best value within this paper	66 m2/g	—	—	Text Exact Reported	3 · Synthesis and Structural Characterization · Figure S1 referenced

CO2 sorption isotherm with BET surface-area and pore-volume analysis

Gas sorption and porosity

1a, iodine-treated washed evacuated dhMOF · Powder

Porosity of iodine-treated partially oxidised 1a; CO2 sorption isotherms are in missing Figure S1; SI: Quantachrome Autosorb iQ Gas Sorption Analyzer after EtOH solvent exchange and high-vacuum activation

Atmosphere: CO2
Context: iodine-treated partially oxidised framework
Measurement source: S-2 · General Materials and Methods · Figure S1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Pore volume of iodine-treated 1aMarked as a best value within this paper	2.4 x 10-2 cm3/g	—	—	Text Exact Reported	3 · Synthesis and Structural Characterization · Figure S1 referenced
BET surface area of iodine-treated 1aMarked as a best value within this paper	1.7 m2/g	—	—	Text Exact Reported	3 · Synthesis and Structural Characterization · Figure S1 referenced