Other — The Advent of Electrically Conducting Double-Helical Metal-Organic Frameworks Featuring Butterfly-Shaped Electron-Rich π-Extended Tetrathiafulvalene Ligands

4 measurement groups · 10 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

1a, iodine-treated washed evacuated dhMOF · Powder

Elemental composition of 1a used to estimate ExTTFTB radical cation and iodide stoichiometry

Context: iodine-treated partially oxidised framework
Measurement source: 4 · Elemental Analysis of Pristine and Iodine-Treated dhMOFs · Figure 1c

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Elemental carbon content of 1a	C 52.78%	—	—	Text Exact Reported	4 · Elemental Analysis
Empirical formula of 1a	Zn3C100H78O26S8I	—	—	Text Exact Reported	4 · Elemental Analysis
ExTTFTB to iodide ratio in 1a	ExTTFTB:I- = 2:1	—	—	Text Exact Reported	4 · Elemental Analysis · Figure 1c
Elemental hydrogen content of 1a	H 3.59%	—	—	Text Exact Reported	4 · Elemental Analysis
Elemental iodine content of 1a	I 5.91%	—	—	Text Exact Reported	4 · Elemental Analysis
Elemental sulphur content of 1a	S 10.84%	—	—	Text Exact Reported	4 · Elemental Analysis

1, activated pristine dhMOF · Powder

Thermal analysis of pristine 1; SI: conducted under N2 atmosphere using an SDT Q600 instrument

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Thermal plateau upper temperature for 1	steady until 350 deg C	—	—	Text Rounded Reported	3 · Synthesis and Structural Characterization · Figure 2b
Initial TGA weight loss for 1	10% before 200 deg C	—	—	Text Rounded Reported	3 · Synthesis and Structural Characterization · Figure 2b

1a, iodine-treated washed evacuated dhMOF · Powder

Thermal analysis of iodine-treated, washed 1a; SI: conducted under N2 atmosphere using an SDT Q600 instrument

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Initial TGA weight loss for 1a	10% between 50 and 100 deg C	—	—	Text Rounded Reported	3 · Synthesis and Structural Characterization · Figure 2b

1b, iodine-treated air-exposed unwashed dhMOF · Powder

Thermal analysis of iodine-treated air-exposed unwashed 1b; SI: conducted under N2 atmosphere using an SDT Q600 instrument

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Residual-iodine-associated TGA weight loss for 1b	17% between 50 and 150 deg C	—	—	Text Rounded Reported	3 · Synthesis and Structural Characterization · Figure 2b