Porosity — Pd-Embedded Ti Metal–Organic Framework Nanostructures for Photocatalytic Reductive N-Formylation of Nitroarenes in Water

2 measurement groups · 12 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Pd1.5%/Ti-MOF · Powder

N2 sorption at 77 K; BET area from P/P0 = 0.05-0.3; BJH pore diameter; degassing at 200 C for 3 h.

Temperature: 77
Atmosphere: N2
Context: Pd/Ti-MOF composite compared with pristine Ti-MOF
Measurement source: p004 / SI pS4 · Table S1; Catalyst characterization methods · Table S1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Pd1.5%/Ti-MOF BET surface area	916 m2/gm	—	—	SI Table Exact Reported	p004 / SI pS4 · Table S1 · Table S1
Pd1.5%/Ti-MOF external surface area	124 m2/gm	—	—	SI Table Exact Reported	p004 / SI pS4 · Table S1 · Table S1
Pd1.5%/Ti-MOF micropore volume	0.39 cc/gm	—	—	SI Table Exact Reported	p004 / SI pS4 · Table S1 · Table S1
Microporosity assignment	Ti-MOF and Pd1.5%/Ti-MOF possess micropores	—	—	Text Qualitative	p003 / article p466 · Physicochemical Characterization · Figure 1b
Pd1.5%/Ti-MOF N2 uptake at P/P0 approximately 1	approximately 310 cm3/g from Figure 1b	—	—	Figure Axis Approximate	p003 / article p466 · Physicochemical Characterization · Figure 1b
Pd1.5%/Ti-MOF total pore volume	0.50 cc/gm	—	—	SI Table Exact Reported	p004 / SI pS4 · Table S1 · Table S1

Ti-MOF · Powder

N2 sorption at 77 K; BET area from P/P0 = 0.05-0.3; BJH pore diameter; degassing at 200 C for 3 h.

Temperature: 77
Atmosphere: N2
Context: pristine control
Measurement source: p004 / SI pS4 · Table S1; Catalyst characterization methods · Table S1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Ti-MOF BET surface areaMarked as a best value within this paper	1203 m2/gm	—	—	SI Table Exact Reported	p004 / SI pS4 · Table S1 · Table S1
Ti-MOF external surface areaMarked as a best value within this paper	131 m2/gm	—	—	SI Table Exact Reported	p004 / SI pS4 · Table S1 · Table S1
Ti-MOF micropore volumeMarked as a best value within this paper	0.55 cc/gm	—	—	SI Table Exact Reported	p004 / SI pS4 · Table S1 · Table S1
Ti-MOF N2 uptake at P/P0 approximately 1Marked as a best value within this paper	approximately 370 cm3/g from Figure 1b	—	—	Figure Axis Approximate	p003 / article p466 · Physicochemical Characterization · Figure 1b
Ti-MOF pore size from crystal-structure discussion	about 1.5 nm	—	—	Text Approximate	p005 / article p468 · Physicochemical Characterization · Figure 4 discussion
Ti-MOF total pore volumeMarked as a best value within this paper	0.65 cc/gm	—	—	SI Table Exact Reported	p004 / SI pS4 · Table S1 · Table S1