Diffraction Structure — Metal-organic framework nanosheets for enhanced performance of organic photovoltaic cells

Measurement evidence

Diffraction Structure

Metal-organic framework nanosheets for enhanced performance of organic photovoltaic cells · Sasitharan K., Bossanyi D.G., Vaenas N. et al. · Journal of Materials Chemistry A · 2020 · 6067-6075

2 measurement groups · 3 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

GI-WAXS

P3HT-Zn2(ZnTCPP) 1:0.5 blend film · Thin Film

Xeuss 2.0, MetalJet liquid gallium X-ray source, 9.24 keV, 400 um beam, Pilatus3R 1M detector, near critical angle under vacuum.

Temperature
room temperature
Atmosphere
vacuum
Geometry
about 150 nm thin films
Context
P3HT-Zn2(ZnTCPP) and ternary active layers compared with pristine P3HT
Measurement source
31-32 · 10. GI-WAXS · Fig. S23-S24; Table S4
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Zn2(ZnTCPP) nanosheet reflection peakq = 0.55 Angstrom-1Text
Exact Reported
5 · Fig. 5d
P3HT crystallite size13.59 nmText
Exact Reported
5 · Table S4

Powder X-ray diffraction (PXRD/XRPD)

bulk Zn2(ZnTCPP)(DMF) MOF · Powder

Cu Kalpha source, lambda=1.5418 Angstrom, 40 kV and 40 mA; bulk MOF compared with exfoliated MONs and literature patterns.

Temperature
room temperature
Atmosphere
ambient
Geometry
rotating flat plate sample holder
Context
pristine parent MOF and exfoliated MON comparison
Measurement source
2,4 · 1. General experimental procedures; 3. Structural characterisations · Fig. S1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
XRPD phase matchmatches previously reported Zn2(ZnTCPP) and analogous structuresQualitative
Qualitative
4 · Fig. S1