Microscopy Morphology — Metal-organic framework nanosheets for enhanced performance of organic photovoltaic cells

2 measurement groups · 9 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

optimised P3HT-Zn2(ZnTCPP)-PCBM photovoltaic device · Thin Film

AFM images of annealed P3HT-Zn2(ZnTCPP)-PCBM and P3HT-PCBM active layers; spatial Fourier transform used for phase-separation length scale.

Temperature: room temperature
Atmosphere: ambient
Geometry: spin-coated active layers
Context: MON ternary active layer compared with P3HT-PCBM reference
Measurement source: 6 · 2.4 Understanding the morphology · Fig. 6; Fig. S25-S26

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
MON ternary domain size upper bound	6-10 nm	—	—	Text Range	6 · Fig. 6; Fig. S25
MON ternary domain size lower bound	6-10 nm	—	—	Text Range	6 · Fig. 6; Fig. S25
reference P3HT-PCBM domain size upper bound	10-15 nm	—	—	Text Range	6 · Fig. 6; Fig. S26
reference P3HT-PCBM domain size lower bound	10-15 nm	—	—	Text Range	6 · Fig. 6; Fig. S26

Zn2(ZnTCPP) MON suspension · Nanosheet

AFM on mica; TEM on holey C-coated Cu grid after dropcasting 10 uL suspension; JEOL-2010F at 200 kV.

Temperature: room temperature
Atmosphere: ambient for AFM; TEM vacuum
Geometry: nanosheets on mica or TEM grid
Context: pristine MON nanosheets
Measurement source: 2-3 · 2.1 Synthesis and characterisation · Fig. 1; Fig. S5-S6

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
EELS inelastic mean free path	0.10	—	—	Text Exact Reported	2 · Fig. S6c
MON lateral dimension	300 +/- 100 nm	—	+/- 100 nm	Text Exact Reported	2-3 · Fig. 1
HR-TEM lattice fringe spacing	1.66 nm	—	—	Caption Exact Reported	3 · Fig. 1c
single MON AFM height	0.77 nm	—	—	Caption Exact Reported	3 · Fig. 1e
MON thickness	1 +/- 0.3 nm	—	+/- 0.3 nm	Text Exact Reported	2-3 · Fig. 1