Zang X., Sun H., Wang W. et al. · Separation and Purification Technology · 2024 · 125667
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
Co/Mn-BTC was the most active of the Fe, Ce, Co and Cu bimetallic Mn-BTC catalysts for plasma-catalytic toluene removal.
Caveat: Performance is application-specific to the DBD reactor and reaction conditions.
p013 · 4. Conclusion · Linked to 4 structured results
The article does not report first-hand electrical conductivity, carrier mobility, Seebeck coefficient, thermal conductivity or electrochemical device performance for the MOFs.
Caveat: The introduction states energised MOFs can show semiconductor-like characteristics, but this paper does not measure transport properties.
p002 · 1. Introduction
Underlying data are not shared by the authors, limiting extraction of exact values from plotted curves beyond numbers reported in the text and tables.
Caveat: No network retrieval was attempted per assignment instructions.
p013 · Data availability
The authors conclude that bimetallic M/Mn-BTC MOF materials were successfully synthesised, based on XRD, FTIR, SEM/EDS and XPS evidence.
Caveat: Exact crystallographic structures and formulae are not reported; assignments rely on comparison to literature peaks.
p003 · 3.1.2. FTIR analysis · Fig. 1 · Linked to 5 structured results
A high Oads/Olatt ratio is linked to superior toluene oxidation, and the strong decrease after reaction indicates consumption or participation of adsorbed oxygen during catalysis.
Caveat: Mechanistic assignment is inferred from ex situ XPS and catalytic trends.
p012-p013 · 3.4.4; 4. Conclusion · Linked to 3 structured results
The authors attribute the synergistic activity of Co/Mn-BTC to Mn/Co redox cycling, enhanced electron transfer and oxygen mobility, forming Oads and active oxygen species from O3 decomposition.
Caveat: No direct electrical transport measurement was reported; electron transfer is mechanistic interpretation from redox-state changes and activity.
p012 · 3.4.4. Mechanism of toluene degradation · Linked to 4 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| Ce/Mn-BTC | Ce/Mn-BTC (exact stoichiometry not reported)mixed Ce/Mn nodes; Ce3+/Ce4+ and Mn redox states observed by XPS · homophthalic acid / BTC-type linker as named by authors | unknown · PristineBimetallic Mn-BTC-derived MOF with retained Mn-BTC peaks and additional Ce-BTC diffraction peaks. | p003 · 3.1.1. XRD analysis · Fig. 1 |
| Co/Mn-BTC | Co/Mn-BTC (exact stoichiometry not reported)mixed Co/Mn nodes; Co2+/Co3+ and Mn4+/Mn3+/Mn2+ redox states observed by XPS · homophthalic acid / BTC-type linker as named by authors | unknown · PristineBimetallic Mn-BTC-derived MOF; Co/Mn-BTC shows diffraction peaks similar to Mn-BTC and plate-like morphology. | p003 · 3.1.1. XRD analysis · Fig. 1 |
| Cu/Mn-BTC | Cu/Mn-BTC (exact stoichiometry not reported)mixed Cu/Mn nodes; Cu+/Cu2+ and Mn redox states observed by XPS · homophthalic acid / BTC-type linker as named by authors | unknown · PristineBimetallic Mn-BTC-derived MOF; XRD mainly exhibits Cu-BTC characteristic peaks and SEM shows octahedral particles. | p003 · 3.1.1. XRD analysis · Fig. 1 |
| DBD-alone plasma reactor system | not applicablenone · none | 0D · Model SystemCatalyst-free dielectric barrier discharge comparator. | p002 · 2.3. Toluene abatement in the DBD-catalytic reactor |
| Fe/Mn-BTC | Fe/Mn-BTC (exact stoichiometry not reported)mixed Fe/Mn nodes; Fe2+/Fe3+ and Mn redox states observed by XPS · homophthalic acid / BTC-type linker as named by authors | unknown · PristineBimetallic Mn-BTC-derived MOF with Fe-associated diffraction peaks at 2theta 10.58 and 23.63 degrees; SEM shows a layer-like morphology. | p003 · 3.1.1. XRD analysis · Fig. 1 |
| Mn-BTC | Mn-BTC (exact stoichiometry not reported)Mn sites with Mn4+, Mn3+ and Mn2+ states discussed for Mn-containing BTC frameworks · homophthalic acid, described by the authors as the BTC linker system | unknown · PristineMn-BTC reference framework; XRD and FTIR peaks used as baseline for bimetallic M/Mn-BTC catalysts. | p003 · 3.1.1. XRD analysis · Fig. 1 |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| Ce/Mn-BTCresearch_0623__mat__mat_ce_mn_btc | Powder · Target Sample · Mixed Metal | solvothermal powder catalyst; 40-60 mesh in DBD tests | p002 · 2.1. Synthesis of M/Mn-BTC |
| Co/Mn-BTC-0.33research_0623__mat__mat_co_mn_btc | Powder · Target Sample · Mixed Metal | Co/Mn molar ratio 1:3; Co amount adjusted | p002 · 2.1. Synthesis of M/Mn-BTC |
| Co/Mn-BTC-0.5research_0623__mat__mat_co_mn_btc | Powder · Target Sample · Mixed Metal | Co/Mn molar ratio 1:2; Co amount adjusted | p002 · 2.1. Synthesis of M/Mn-BTC |
| Co/Mn-BTC / Co/Mn-BTC-1research_0623__mat__mat_co_mn_btc | Powder · Target Sample · Mixed Metal | Co/Mn molar ratio 1:1; solvothermal powder catalyst; 40-60 mesh in DBD tests | p002 · 2.1. Synthesis of M/Mn-BTC |
| Co/Mn-BTC-2research_0623__mat__mat_co_mn_btc | Powder · Target Sample · Mixed Metal | Co/Mn molar ratio 2:1; Co amount adjusted | p002 · 2.1. Synthesis of M/Mn-BTC |
| Co/Mn-BTC used after DBD reactionresearch_0623__mat__mat_co_mn_btc | Powder · Target Sample · Mixed Metal | Co/Mn-BTC-1 after plasma-catalytic toluene reaction | p010 · 3.4.1. XPS analysis before and after Co/Mn-BTC reaction · Fig. 11 |
| Cu/Mn-BTCresearch_0623__mat__mat_cu_mn_btc | Powder · Target Sample · Mixed Metal | solvothermal powder catalyst; 40-60 mesh in DBD tests | p002 · 2.1. Synthesis of M/Mn-BTC |
| DBD-aloneresearch_0623__mat__mat_dbd_system | Model · Model System · Model | catalyst-free DBD treatment of toluene | p005 · 3.2. DBD-catalytic decomposition of toluene · Fig. 5 |
| Fe/Mn-BTCresearch_0623__mat__mat_fe_mn_btc | Powder · Target Sample · Mixed Metal | solvothermal powder catalyst; 40-60 mesh in DBD tests | p002 · 2.1. Synthesis of M/Mn-BTC |
| Mn-BTCresearch_0623__mat__mat_mn_btc | Powder · Pristine Control · Pristine Framework | single-metal Mn-BTC reference catalyst/control | p003 · 3.1.1. XRD analysis · Fig. 1 |