Other — Plasma-catalytic removal of toluene over bimetallic M/Mn-BTC catalysts in dielectric barrier discharge reactor

Measurement evidence

Other

Plasma-catalytic removal of toluene over bimetallic M/Mn-BTC catalysts in dielectric barrier discharge reactor · Zang X., Sun H., Wang W. et al. · Separation and Purification Technology · 2024 · 125667

15 measurement groups · 49 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

O3 and NOx monitoring

Ce/Mn-BTC · Powder

O3 measured with ozone analyser; NOx monitored with flue gas analyser across SED values

Context
application comparison
Measurement source
p003,p007-p008 · 2.3; 3.2
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
NOx concentration at SED 565.39 J/L109.6 mg/m3Text
Rounded Reported
p007 · 3.2 · Fig. 7
O3 concentration at SED 343.59 J/L485.29 mg/m3Text
Exact Reported
p007 · 3.2 · Fig. 7

O3 and NOx monitoring

Co/Mn-BTC / Co/Mn-BTC-1 · Powder

O3 measured with ozone analyser; NOx monitored with flue gas analyser across SED values

Context
application comparison
Measurement source
p003,p007-p008 · 2.3; 3.2
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
NOx concentration at SED 565.39 J/L103.0 mg/m3Text
Rounded Reported
p007 · 3.2 · Fig. 7
O3 concentration at SED 343.59 J/LMarked as a best value within this paper183.99 mg/m3Text
Exact Reported
p007 · 3.2 · Fig. 7

O3 and NOx monitoring

Cu/Mn-BTC · Powder

O3 measured with ozone analyser; NOx monitored with flue gas analyser across SED values

Context
application comparison
Measurement source
p003,p007-p008 · 2.3; 3.2
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
NOx concentration at SED 565.39 J/LMarked as a best value within this paper79.2 mg/m3Text
Rounded Reported
p007 · 3.2 · Fig. 7
O3 concentration at SED 343.59 J/L406.29 mg/m3Text
Exact Reported
p007 · 3.2 · Fig. 7

O3 and NOx monitoring

DBD-alone · Model

O3 measured with ozone analyser; NOx monitored with flue gas analyser across SED values

Context
application comparison
Measurement source
p003,p007-p008 · 2.3; 3.2
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
NOx concentration at SED 565.39 J/L138.4 mg/m3Text
Rounded Reported
p007 · 3.2 · Fig. 7
O3 concentration at SED 343.59 J/L538.64 mg/m3Text
Exact Reported
p007 · 3.2 · Fig. 7

O3 and NOx monitoring

Fe/Mn-BTC · Powder

O3 measured with ozone analyser; NOx monitored with flue gas analyser across SED values

Context
application comparison
Measurement source
p003,p007-p008 · 2.3; 3.2
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
NOx concentration at SED 565.39 J/L111.4 mg/m3Text
Rounded Reported
p007 · 3.2 · Fig. 7
O3 concentration at SED 343.59 J/L468.57 mg/m3Text
Exact Reported
p007 · 3.2 · Fig. 7

GC-MS of exhaust byproducts

Co/Mn-BTC / Co/Mn-BTC-1 · Powder

Exhaust gas absorbed in n-hexane for 20 min; fixed SED 689.01 J/L with Co/Mn-BTC catalyst

Measurement source
p011-p012 · 3.4.3. GC-MS analysis for organic byproducts in exhaust gas
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
DBD + Co/Mn-BTC organic byproducts detectedToluene; 3-Hexanone; Cyclopentanol, 1-methyl-; 3-Hexanol; Heptane, 2,4-dimethyl-; Benzene, 1,4-dimethyl-; Benzaldehyde; Nonanal; Phenol, 2-nitro-; Benzoic acid; Benzaldehyde, 2,5-dimethyl-; Nonadecane, 2-methyl-; n-Hexadecanoic acidTable
Qualitative
p012 · 3.4.3 · Table 6
DBD-alone organic byproducts detected3-Pentanol, 3-methyl-; Toluene; 3-Hexanone; Cyclopentanol, 1-methyl-; 3-Hexanol; Heptane, 2,4-dimethyl-; Benzene, 1,4-dimethyl-; Benzaldehyde; Benzyl alcohol; Phenol, 2-nitro-; Benzoic acid; Benzaldehyde, 2,5-dimethyl-; Dodecane, 2,6,11-trimethyl-; Heptacosance; n-Hexadecanoic acid; Octadecanoic acidTable
Qualitative
p012 · 3.4.3 · Table 6

DBD-catalytic toluene abatement for Co/Mn ratio series

Co/Mn-BTC-0.33 · Powder

500 ppm toluene, 4 vol% O2, SED 267.24-808.99 J/L; Co/Mn ratio varied

Context
ratio optimisation
Measurement source
p008-p010 · 3.3. Effect of Co/Mn ratios on performance
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
NOx concentration at SED 689.01 J/L115.2 mg/m3Text
Exact Reported
p009-p010 · 3.3 · Fig. 10
O3 concentration at SED 689.01 J/LMarked as a best value within this paper7.71 mg/m3Text
Exact Reported
p010 · 3.3 · Fig. 10

DBD-catalytic toluene abatement for Co/Mn ratio series

Co/Mn-BTC-0.5 · Powder

500 ppm toluene, 4 vol% O2, SED 267.24-808.99 J/L; Co/Mn ratio varied

Context
ratio optimisation
Measurement source
p008-p010 · 3.3. Effect of Co/Mn ratios on performance
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
NOx concentration at SED 689.01 J/L132.9 mg/m3Text
Exact Reported
p009-p010 · 3.3 · Fig. 10
O3 concentration at SED 689.01 J/L10.35 mg/m3Text
Exact Reported
p010 · 3.3 · Fig. 10

DBD-catalytic toluene abatement for Co/Mn ratio series

Co/Mn-BTC / Co/Mn-BTC-1 · Powder

500 ppm toluene, 4 vol% O2, SED 267.24-808.99 J/L; Co/Mn ratio varied

Context
ratio optimisation
Measurement source
p008-p010 · 3.3. Effect of Co/Mn ratios on performance
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Co/Mn-BTC-1 degradation efficiency at SED 808.99 J/LMarked as a best value within this paper96.2%Text
Rounded Reported
p009 · 3.3 · Fig. 9
Co/Mn-BTC-1 maximum energy efficiencyMarked as a best value within this paper18.85 g/kWh at SED 267.24 J/LText
Exact Reported
p009 · 3.3 · Fig. 9
Co/Mn-BTC-1 mineralization degree at SED 808.99 J/LMarked as a best value within this paper93.9%Text
Rounded Reported
p009 · 3.3 · Fig. 9
NOx concentration at SED 689.01 J/L140.5 mg/m3Text
Exact Reported
p009-p010 · 3.3 · Fig. 10
O3 concentration at SED 689.01 J/L15.41 mg/m3Text
Exact Reported
p010 · 3.3 · Fig. 10
Co/Mn ratio performance orderMarked as a best value within this paperCo/Mn-BTC-1 > Co/Mn-BTC-0.5 > Co/Mn-BTC-2 > Co/Mn-BTC-0.33Text
Qualitative
p008-p009 · 3.3 · Fig. 9

DBD-catalytic toluene abatement for Co/Mn ratio series

Co/Mn-BTC-2 · Powder

500 ppm toluene, 4 vol% O2, SED 267.24-808.99 J/L; Co/Mn ratio varied

Context
ratio optimisation
Measurement source
p008-p010 · 3.3. Effect of Co/Mn ratios on performance
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
NOx concentration at SED 689.01 J/LMarked as a best value within this paper110.0 mg/m3Text
Exact Reported
p009-p010 · 3.3 · Fig. 10
O3 concentration at SED 689.01 J/L13.16 mg/m3Text
Exact Reported
p010 · 3.3 · Fig. 10

DBD-catalytic toluene abatement

Ce/Mn-BTC · Powder

500 ppm toluene, 1 L/min gas flow, 4 vol% O2, SED 267.24-808.99 J/L; 0.3 g catalyst plus 1.5 g quartz sand for catalyst tests

Context
application comparison
Measurement source
p002-p005 · 2.3; 3.2
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Energy efficiency at SED 267.24 J/L14.2 g/kWhText
Rounded Reported
p005 · 3.2 · Fig. 5
Toluene degradation efficiency at SED 267.24 J/L54.4%Text
Rounded Reported
p005 · 3.2 · Fig. 5
Toluene degradation efficiency at SED 808.99 J/L95.2%Text
Rounded Reported
p005 · 3.2 · Fig. 5

DBD-catalytic toluene abatement

Co/Mn-BTC / Co/Mn-BTC-1 · Powder

500 ppm toluene, 1 L/min gas flow, 4 vol% O2, SED 267.24-808.99 J/L; 0.3 g catalyst plus 1.5 g quartz sand for catalyst tests

Context
application comparison
Measurement source
p002-p005 · 2.3; 3.2
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
CO2 concentration at SED 343.59 J/L with Co/Mn-BTC1825.17 mg/m3Text
Exact Reported
p006 · 3.2 · Fig. 6
CO concentration at SED 343.59 J/L with Co/Mn-BTC1226.28 mg/m3Text
Exact Reported
p006 · 3.2 · Fig. 6
CO2 selectivity at SED 689.01 J/L with Co/Mn-BTCMarked as a best value within this paper52.6%Text
Rounded Reported
p006 · 3.2 · Fig. 6
Energy efficiency at SED 267.24 J/LMarked as a best value within this paper18.8 g/kWhText
Rounded Reported
p005 · 3.2 · Fig. 5
Mineralization degree at SED 343.59 J/L with Co/Mn-BTC66.4%Text
Rounded Reported
p007 · 3.2 · Fig. 6
Mineralization degree at SED 808.99 J/L with Co/Mn-BTCMarked as a best value within this paper94.1%Text
Rounded Reported
p007 · 3.2 · Fig. 6
Co/Mn-BTC energy efficiency rangeMarked as a best value within this paper8.32-18.85Table
Range
p007 · 3.2 · Table 4
Toluene degradation efficiency at SED 267.24 J/L72.0%Text
Rounded Reported
p005 · 3.2 · Fig. 5
Toluene degradation efficiency at SED 808.99 J/LMarked as a best value within this paper96.2%Text
Rounded Reported
p005 · 3.2 · Fig. 5

DBD-catalytic toluene abatement

Cu/Mn-BTC · Powder

500 ppm toluene, 1 L/min gas flow, 4 vol% O2, SED 267.24-808.99 J/L; 0.3 g catalyst plus 1.5 g quartz sand for catalyst tests

Context
application comparison
Measurement source
p002-p005 · 2.3; 3.2
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Energy efficiency at SED 267.24 J/L17.74 g/kWhText
Rounded Reported
p005 · 3.2 · Fig. 5
Toluene degradation efficiency at SED 267.24 J/L67.9%Text
Rounded Reported
p005 · 3.2 · Fig. 5
Toluene degradation efficiency at SED 808.99 J/L95.5%Text
Rounded Reported
p005 · 3.2 · Fig. 5

DBD-catalytic toluene abatement

DBD-alone · Model

500 ppm toluene, 1 L/min gas flow, 4 vol% O2, SED 267.24-808.99 J/L; 0.3 g catalyst plus 1.5 g quartz sand for catalyst tests

Context
application comparison
Measurement source
p002-p005 · 2.3; 3.2
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
CO2 concentration at SED 343.59 J/L for DBD alone885.03 mg/m3Text
Exact Reported
p006 · 3.2 · Fig. 6
CO concentration at SED 343.59 J/L for DBD alone707.31 mg/m3Text
Exact Reported
p006 · 3.2 · Fig. 6
CO2 selectivity at SED 689.01 J/L for DBD alone46.1%Text
Rounded Reported
p006 · 3.2 · Fig. 6
Energy efficiency at SED 267.24 J/L11.77 g/kWhText
Rounded Reported
p005 · 3.2 · Fig. 5
Mineralization degree at SED 343.59 J/L for DBD alone50.6%Text
Rounded Reported
p007 · 3.2 · Fig. 6
Toluene degradation efficiency at SED 267.24 J/L45.0%Text
Rounded Reported
p005 · 3.2 · Fig. 5
Toluene degradation efficiency at SED 808.99 J/L88.9%Text
Rounded Reported
p005 · 3.2 · Fig. 5

DBD-catalytic toluene abatement

Fe/Mn-BTC · Powder

500 ppm toluene, 1 L/min gas flow, 4 vol% O2, SED 267.24-808.99 J/L; 0.3 g catalyst plus 1.5 g quartz sand for catalyst tests

Context
application comparison
Measurement source
p002-p005 · 2.3; 3.2
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Energy efficiency at SED 267.24 J/L13.06 g/kWhText
Rounded Reported
p005 · 3.2 · Fig. 5
Toluene degradation efficiency at SED 267.24 J/L50.0%Text
Rounded Reported
p005 · 3.2 · Fig. 5
Toluene degradation efficiency at SED 808.99 J/L93.5%Text
Rounded Reported
p005 · 3.2 · Fig. 5