cMOF Evidence Base

Synthesis evidence

Plasma-catalytic removal of toluene over bimetallic M/Mn-BTC catalysts in dielectric barrier discharge reactor

Zang X., Sun H., Wang W. et al. · Separation and Purification Technology · 2024 · 125667

7 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Partial recipeSource: Main

Route 1: Solvothermal

p002 · 2.1. Synthesis of M/Mn-BTC

Metal precursorsCe(NO3)2.6H2O; Mn(NO3)2 (same molar basis as Co/Mn-BTC route)
Linker precursorshomophthalic acid (1.681 g assumed from similar process)
Solvents60 mL DMF/ethanol = 5:1 v/v (similar process)
Atmospherenot reported
Temperature120
Time24
Oxidant / reductantnone reported
Work-upsimilar process to Co/Mn-BTC: cool, centrifuge, wash with ethanol and water
Activationdried under vacuum at 80 C for 12 h by similar process
Scalability context100 mL Teflon-coated stainless-steel autoclave by analogy with Co/Mn-BTC route
Show 4 structured reagent records
RoleReagentAmount / concentrationSource
Metal SourceCe(NO3)2.6H2Osame molar amount as Co(NO3)2.6H2O in Co/Mn-BTC route; exact mass not reportedp002 · 2.1. Synthesis of M/Mn-BTC
Metal SourceMn(NO3)21.432 g by similar processp002 · 2.1. Synthesis of M/Mn-BTC
Linkerhomophthalic acid1.681 g by similar processp002 · 2.1. Synthesis of M/Mn-BTC
SolventDMF/ethanol = 5:1 (v/v)60 mL by similar processp002 · 2.1. Synthesis of M/Mn-BTC
Partial recipeSource: Main

Route 2: Solvothermal

p002 · 2.1. Synthesis of M/Mn-BTC

Metal precursorsCo(NO3)2.6H2O adjusted to Co/Mn molar ratio 1:3; Mn(NO3)2
Linker precursorshomophthalic acid
SolventsDMF/ethanol = 5:1 v/v
Atmospherenot reported
Temperature120
Time24
Oxidant / reductantnone reported
Work-upsame process as Co/Mn-BTC route
Activationdried under vacuum at 80 C for 12 h by same process
Scalability context100 mL Teflon-coated stainless-steel autoclave by analogy with Co/Mn-BTC route
Show 4 structured reagent records
RoleReagentAmount / concentrationSource
Metal SourceCo(NO3)2.6H2Oadjusted for Co/Mn 1:3; exact mass not reportedp002 · 2.1. Synthesis of M/Mn-BTC
Metal SourceMn(NO3)2not separately reported for ratio variantp002 · 2.1. Synthesis of M/Mn-BTC
Linkerhomophthalic acidnot separately reported for ratio variantp002 · 2.1. Synthesis of M/Mn-BTC
SolventDMF/ethanol = 5:1 (v/v)not separately reported for ratio variantp002 · 2.1. Synthesis of M/Mn-BTC
Partial recipeSource: Main

Route 3: Solvothermal

p002 · 2.1. Synthesis of M/Mn-BTC

Metal precursorsCo(NO3)2.6H2O adjusted to Co/Mn molar ratio 1:2; Mn(NO3)2
Linker precursorshomophthalic acid
SolventsDMF/ethanol = 5:1 v/v
Atmospherenot reported
Temperature120
Time24
Oxidant / reductantnone reported
Work-upsame process as Co/Mn-BTC route
Activationdried under vacuum at 80 C for 12 h by same process
Scalability context100 mL Teflon-coated stainless-steel autoclave by analogy with Co/Mn-BTC route
Show 4 structured reagent records
RoleReagentAmount / concentrationSource
Metal SourceCo(NO3)2.6H2Oadjusted for Co/Mn 1:2; exact mass not reportedp002 · 2.1. Synthesis of M/Mn-BTC
Metal SourceMn(NO3)2not separately reported for ratio variantp002 · 2.1. Synthesis of M/Mn-BTC
Linkerhomophthalic acidnot separately reported for ratio variantp002 · 2.1. Synthesis of M/Mn-BTC
SolventDMF/ethanol = 5:1 (v/v)not separately reported for ratio variantp002 · 2.1. Synthesis of M/Mn-BTC
Partial recipeSource: Main

Route 4: Solvothermal

p002 · 2.1. Synthesis of M/Mn-BTC

Metal precursorsCo(NO3)2.6H2O (2.328 g); Mn(NO3)2 (1.432 g)
Linker precursorshomophthalic acid (1.681 g)
Solvents60 mL DMF/ethanol = 5:1 v/v
Atmospherenot reported
Temperature120
Time24
Oxidant / reductantnone reported
Work-upcool to room temperature; centrifuge at 8000 rpm; collect precipitated crystals; wash at least three times with ethanol and water
Activationdried under vacuum at 80 C for 12 h
Scalability context100 mL Teflon-coated stainless-steel autoclave; batch solvothermal synthesis
Show 4 structured reagent records
RoleReagentAmount / concentrationSource
Metal SourceCo(NO3)2.6H2O2.328 g for Co/Mn-BTC 1:1 routep002 · 2.1. Synthesis of M/Mn-BTC
Metal SourceMn(NO3)21.432 gp002 · 2.1. Synthesis of M/Mn-BTC
Linkerhomophthalic acid1.681 gp002 · 2.1. Synthesis of M/Mn-BTC
SolventDMF/ethanol = 5:1 (v/v)60 mLp002 · 2.1. Synthesis of M/Mn-BTC
Partial recipeSource: Main

Route 5: Solvothermal

p002 · 2.1. Synthesis of M/Mn-BTC

Metal precursorsCo(NO3)2.6H2O adjusted to Co/Mn molar ratio 2:1; Mn(NO3)2
Linker precursorshomophthalic acid
SolventsDMF/ethanol = 5:1 v/v
Atmospherenot reported
Temperature120
Time24
Oxidant / reductantnone reported
Work-upsame process as Co/Mn-BTC route
Activationdried under vacuum at 80 C for 12 h by same process
Scalability context100 mL Teflon-coated stainless-steel autoclave by analogy with Co/Mn-BTC route
Show 4 structured reagent records
RoleReagentAmount / concentrationSource
Metal SourceCo(NO3)2.6H2Oadjusted for Co/Mn 2:1; exact mass not reportedp002 · 2.1. Synthesis of M/Mn-BTC
Metal SourceMn(NO3)2not separately reported for ratio variantp002 · 2.1. Synthesis of M/Mn-BTC
Linkerhomophthalic acidnot separately reported for ratio variantp002 · 2.1. Synthesis of M/Mn-BTC
SolventDMF/ethanol = 5:1 (v/v)not separately reported for ratio variantp002 · 2.1. Synthesis of M/Mn-BTC
Partial recipeSource: Main

Route 6: Solvothermal

p002 · 2.1. Synthesis of M/Mn-BTC

Metal precursorsCu(NO3)2.3H2O; Mn(NO3)2 (same molar basis as Co/Mn-BTC route)
Linker precursorshomophthalic acid (1.681 g assumed from similar process)
Solvents60 mL DMF/ethanol = 5:1 v/v (similar process)
Atmospherenot reported
Temperature120
Time24
Oxidant / reductantnone reported
Work-upsimilar process to Co/Mn-BTC: cool, centrifuge, wash with ethanol and water
Activationdried under vacuum at 80 C for 12 h by similar process
Scalability context100 mL Teflon-coated stainless-steel autoclave by analogy with Co/Mn-BTC route
Show 4 structured reagent records
RoleReagentAmount / concentrationSource
Metal SourceCu(NO3)2.3H2Osame molar amount as Co(NO3)2.6H2O in Co/Mn-BTC route; exact mass not reportedp002 · 2.1. Synthesis of M/Mn-BTC
Metal SourceMn(NO3)21.432 g by similar processp002 · 2.1. Synthesis of M/Mn-BTC
Linkerhomophthalic acid1.681 g by similar processp002 · 2.1. Synthesis of M/Mn-BTC
SolventDMF/ethanol = 5:1 (v/v)60 mL by similar processp002 · 2.1. Synthesis of M/Mn-BTC
Partial recipeSource: Main

Route 7: Solvothermal

p002 · 2.1. Synthesis of M/Mn-BTC

Metal precursorsFe(NO3)3.9H2O; Mn(NO3)2 (same molar basis as Co/Mn-BTC route)
Linker precursorshomophthalic acid (1.681 g assumed from similar process)
Solvents60 mL DMF/ethanol = 5:1 v/v (similar process)
Atmospherenot reported
Temperature120
Time24
Oxidant / reductantnone reported
Work-upsimilar process to Co/Mn-BTC: cool, centrifuge, wash with ethanol and water
Activationdried under vacuum at 80 C for 12 h by similar process
Scalability context100 mL Teflon-coated stainless-steel autoclave by analogy with Co/Mn-BTC route
Show 4 structured reagent records
RoleReagentAmount / concentrationSource
Metal SourceFe(NO3)3.9H2Osame molar amount as Co(NO3)2.6H2O in Co/Mn-BTC route; exact mass not reportedp002 · 2.1. Synthesis of M/Mn-BTC
Metal SourceMn(NO3)21.432 g by similar processp002 · 2.1. Synthesis of M/Mn-BTC
Linkerhomophthalic acid1.681 g by similar processp002 · 2.1. Synthesis of M/Mn-BTC
SolventDMF/ethanol = 5:1 (v/v)60 mL by similar processp002 · 2.1. Synthesis of M/Mn-BTC