Zhang X., Han L., Li J. et al. · Journal of Materials Science and Technology · 2022 · 156-164
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
Conductive Sn-DHTPA is proposed as a high-energy/high-power LIB electrode material due to its high reversible capacity, high-rate cycling and fast Li-ion diffusion.
Caveat: Performance was measured in half-cells with Super-P/PVDF composite electrodes; full-cell or practical loading validation is not reported.
p008 / article p.163 · Conclusion · Linked to 7 structured results
Micropores/mesopores and relatively low surface area are claimed to shorten Li-ion diffusion length, accommodate volume change and limit side reactions.
Caveat: Pore-to-performance linkage is interpretive; no isolated control with different porosity is shown.
p004 / article p.159 · Results and Discussion · Figure 1e,f · Linked to 4 structured results
The lithium storage capacity is attributed to redox-active sites from both the aromatic DHTPA linker and Sn metal centres, with in-situ generated Sn nanoparticles participating during cycling.
Caveat: Evidence is based on ex-situ measurements at selected states; operando confirmation was not reported.
p001 / article p.156 · Abstract · Linked to 5 structured results
The high conductivity of Sn-DHTPA is attributed to mixed Sn4+/Sn2+ valence charge transfer, conjugated DHTPA, strong Sn-DHTPA ionic bond interactions and through-bond Sn/DHTPA orbital overlap.
Caveat: Mechanistic explanation is inferred by authors from spectroscopy and conductivity; no direct mobility or band-structure measurement is reported.
p004 / article p.159 · Results and Discussion · Linked to 6 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| Sn-DHTPA | H4O8Sn6Mixed Sn2+/Sn4+ tin species coordinated by hydroxyl and carboxyl oxygen atoms · DHTPA, 2,5-dihydroxyterephthalic acid | unknown · PristineCrystalline Sn-based coordination polymer; tetragonal P-421c from Le Bail refinement; authors describe an organic-inorganic hybrid crystalline material with Sn ions coordinated to DHTPA. | p003 / article p.158 · Results and Discussion · Table 1 |
| Sn-DHTPA/Super-P/PVDF electrode on Cu foil | Sn-DHTPA with Super-P carbon and PVDF binderSn2+/Sn4+ centres in Sn-DHTPA · DHTPA in Sn-DHTPA; PVDF binder is non-framework component | unknown · CompositeComposite electrode made by coating a 7:2:1 Sn-DHTPA/Super-P/PVDF slurry on Cu foil for CR2032 half-cell testing. | p002 / article p.157 · Experimental - Electrochemical measurements |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| Sn-DHTPA composite LIB electroderesearch_0663__mat__mat_sn_dhtpa_electrode | Electrode · Composite Sample · Composite | Slurry of Sn-DHTPA, Super-P and PVDF in N-methylpyrrolidone coated onto Cu foil, dried at 120 C under vacuum for 12 h, then assembled into CR2032 half-cells.Cu foil | p002 / article p.157 · Experimental - Electrochemical measurements |
| as-prepared Sn-DHTPA powderresearch_0663__mat__mat_sn_dhtpa | Powder · Target Sample · Pristine Framework | Yellow precipitate collected, washed and dried at 120 C for 12 h in a vacuum drying oven. | p002 / article p.157 · Experimental - Preparation of Sn-DHTPA |
| pressed Sn-DHTPA powder for four-point proberesearch_0663__mat__mat_sn_dhtpa | Pellet · Target Sample · Pristine Framework | Powder pressed in a stainless-steel die for 0.5 h at 10 MPa before room-temperature four-point-probe measurement. | p002 / article p.157 · Experimental - Material characterizations |