Measurement evidence
A novel Sn-based coordination polymer with high-efficiency and ultrafast lithium storage · Zhang X., Han L., Li J. et al. · Journal of Materials Science and Technology · 2022 · 156-164
Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.
Sn-DHTPA composite LIB electrode · Electrode
Li metal counter electrode; 1 M LiPF6 in EC/DEC/DMC 1:1:1 with 5 wt% FEC; glass-fibre separator; argon-filled glovebox
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| active-material mass loading | about 1.0-1.3 mg cm-2 | — | about | Text Range | p002 / article p.157 · Experimental - Electrochemical measurements |
Sn-DHTPA composite LIB electrode · Electrode
Initial five cycles at 0.2 mV s^-1 unless otherwise noted; voltage window 0.01-3 V vs Li+/Li
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| upper bound for weak hydroxyl extraction anodic feature | 3.0 V | — | — | Text Approximate | p007 / article p.162 · Results and Discussion · Figure 3a; Figure 6 |
| lower bound for weak hydroxyl extraction anodic feature | 2.6 V | — | — | Text Approximate | p007 / article p.162 · Results and Discussion · Figure 3a; Figure 6 |
| initial anodic peak for LixSn decomposition | about 0.55 V | — | — | Text Approximate | p007 / article p.162 · Results and Discussion · Figure 3a; Figure 6 |
| initial anodic peak for aromatic ring/carboxylate delithiation | about 1.07 V | — | — | Text Approximate | p007 / article p.162 · Results and Discussion · Figure 3a; Figure 6 |
| initial-cycle cathodic peak assigned to SEI formation | about 0.71 V | — | about | Text Approximate | p004 / article p.159 · Results and Discussion · Figure 3a |
| subsequent-cycle organic oxidation peak | 1.21 V | — | — | Text Exact Reported | p007 / article p.162 · Results and Discussion · Figure 3a; Figure 6 |
| subsequent-cycle Sn alloying peak | 0.22 V | — | — | Text Exact Reported | p007 / article p.162 · Results and Discussion · Figure 3a; Figure 6 |
| subsequent-cycle organic lithiation peak | 0.70 V | — | — | Text Exact Reported | p007 / article p.162 · Results and Discussion · Figure 3a; Figure 6 |
Sn-DHTPA composite LIB electrode · Electrode
CV scan rates 0.2-2.0 mV s^-1; b-value analysis by log(i) versus log(v)
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| capacitive contribution at 0.2 mV s-1 | 25% | — | — | Text Exact Reported | p007 / article p.162 · Results and Discussion · Figure 7b |
| capacitive contribution at 0.4 mV s^-1 | 32% | — | — | Text Exact Reported | p007 / article p.162 · Results and Discussion · Figure 7b |
| capacitive contribution at 0.6 mV s^-1 | 37% | — | — | Text Exact Reported | p007 / article p.162 · Results and Discussion · Figure 7b |
| capacitive contribution at 0.8 mV s^-1 | 40% | — | — | Text Exact Reported | p007 / article p.162 · Results and Discussion · Figure 7b |
| capacitive contribution at 1.0 mV s^-1 | 43% | — | — | Text Exact Reported | p007 / article p.162 · Results and Discussion · Figure 7b |
| capacitive contribution at 1.5 mV s^-1 | 48% | — | — | Text Exact Reported | p007 / article p.162 · Results and Discussion · Figure 7b |
| capacitive contribution at 2.0 mV s-1Marked as a best value within this paper | 52% | — | — | Text Exact Reported | p007 / article p.162 · Results and Discussion · Figure 7b |
| b value for reduction peak 1 | 0.74 | — | — | Text Exact Reported | p007 / article p.162 · Results and Discussion · Figure S6 |
| b value for oxidation peak 2 | 0.71 | — | — | Text Exact Reported | p007 / article p.162 · Results and Discussion · Figure S6 |
| b value for oxidation peak 3 | 0.51 | — | — | Text Exact Reported | p007 / article p.162 · Results and Discussion · Figure S6 |
Sn-DHTPA composite LIB electrode · Electrode
0.1 Hz-100 kHz with 5 mV amplitude; fresh electrode and electrodes cycled 50 and 100 cycles at 0.1 A g^-1
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| charge-transfer resistance after 100 cyclesMarked as a best value within this paper | 9.54 Ohm | — | — | Text Exact Reported | p008 / article p.163 · Results and Discussion · Figure 7c |
| charge-transfer resistance after 50 cycles | 62.4 Ohm | — | — | Text Exact Reported | p008 / article p.163 · Results and Discussion · Figure 7c |
| Warburg factor after 100 cyclesMarked as a best value within this paper | 8.6 Ohm s^-1/2 | — | — | Text Exact Reported | p008 / article p.163 · Results and Discussion · Figure 7d |
| Warburg factor after 50 cycles | 49.7 Ohm s^-1/2 | — | — | Text Exact Reported | p008 / article p.163 · Results and Discussion · Figure 7d |
| Warburg factor fresh electrode | 161.8 Ohm s^-1/2 | — | — | Text Exact Reported | p008 / article p.163 · Results and Discussion · Figure 7d |
Sn-DHTPA composite LIB electrode · Electrode
0.01-3 V vs Li+/Li; 100 mA g^-1 unless otherwise noted
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| reversible capacity after 100 cycles at 100 mA g-1Marked as a best value within this paper | 1142.6 mA h g-1 at 100 mA g-1 after 100 cycles | — | — | Text Exact Reported | p004 / article p.159 · Results and Discussion · Figure 3c |
| initial discharge capacity | 1513 mA h g-1 | — | — | Text Exact Reported | p004 / article p.159 · Results and Discussion · Figure 3b |
| initial reversible capacity | 850 mA h g-1 | — | — | Text Exact Reported | p004 / article p.159 · Results and Discussion · Figure 3b |
| SI Table S2 specific capacity at 100 mA g^-1 after 200 cyclesMarked as a best value within this paper | 1176.3 mA h g^-1 at 100 mA g^-1, cycle number 200 | — | — | SI Table Exact Reported | SI rendered p008 · Supporting Information · Table S2 |
Sn-DHTPA composite LIB electrode · Electrode
Ultra-high current density 20 A g^-1 for 1000 cycles; Figure S4 also reports 5 and 10 A g^-1 for 1000 cycles
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| long-cycle capacity at 10 A g-1 after 1000 cycles | 375.1 mA h g-1 after 1000 cycles | — | — | Text Exact Reported | p004-p005 / article pp.159-160 · Results and Discussion · Figure S4 |
| long-cycle capacity at 20 A g-1 after 1000 cyclesMarked as a best value within this paper | 205.5 mA h g-1 after 1000 cycles | — | — | Text Exact Reported | p004 / article p.159 · Results and Discussion · Figure 3f |
| long-cycle capacity at 5 A g-1 after 1000 cycles | 483.3 mA h g-1 after 1000 cycles | — | — | Text Exact Reported | p004-p005 / article pp.159-160 · Results and Discussion · Figure S4 |
Sn-DHTPA composite LIB electrode · Electrode
Current densities from 0.1 to 20 A g^-1, then return to 0.1 A g^-1
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| rate capacity at 0.1 A g-1 | 783 mA h g-1 | — | — | Text Rounded Reported | p004 / article p.159 · Results and Discussion · Figure 3d |
| rate capacity at 0.2 A g^-1 | 778 mA h g^-1 | — | — | Text Rounded Reported | p004-p005 / article pp.159-160 · Results and Discussion · Figure 3d |
| rate capacity at 0.4 A g^-1 | 772 mA h g^-1 | — | — | Text Rounded Reported | p004-p005 / article pp.159-160 · Results and Discussion · Figure 3d |
| rate capacity at 0.8 A g^-1 | 766 mA h g^-1 | — | — | Text Rounded Reported | p004-p005 / article pp.159-160 · Results and Discussion · Figure 3d |
| rate capacity at 10 A g^-1 | 461 mA h g^-1 | — | — | Text Rounded Reported | p004-p005 / article pp.159-160 · Results and Discussion · Figure 3d |
| rate capacity at 15 A g^-1 | 371 mA h g^-1 | — | — | Text Rounded Reported | p004-p005 / article pp.159-160 · Results and Discussion · Figure 3d |
| rate capacity at 1 A g^-1 | 713 mA h g^-1 | — | — | Text Rounded Reported | p004-p005 / article pp.159-160 · Results and Discussion · Figure 3d |
| rate capacity at 20 A g-1Marked as a best value within this paper | 287.7 mA h g^-1 at 20 A g^-1; main text rate series rounds to 286 mA h g^-1 | — | main text rounded to 286 | SI Table Exact Reported | SI rendered p008 · Supporting Information · Table S2 |
| rate capacity at 2 A g^-1 | 606 mA h g^-1 | — | — | Text Rounded Reported | p004-p005 / article pp.159-160 · Results and Discussion · Figure 3d |
| rate capacity at 5 A g^-1 | 572 mA h g^-1 | — | — | Text Rounded Reported | p004-p005 / article pp.159-160 · Results and Discussion · Figure 3d |
| capacity recovery when current returns to 0.1 A g-1 | 1065 mA h g-1 | — | — | Text Exact Reported | p004 / article p.159 · Results and Discussion · Figure 3d |
| SI Table S2 specific capacity at 20 A g^-1Marked as a best value within this paper | 287.7 mA h g^-1 at 20*1000 mA g^-1 | — | — | SI Table Exact Reported | SI rendered p008 · Supporting Information · Table S2 |