Measurement evidence
Enhancing the Photocatalytic Degradation Efficiency of Dyes of Copper-Based Metal-Organic Frameworks through a Dimension-Induced Structural Strategy · Jia R.-Q., Chen Y.-J., Zuo L.-Y. et al. · Inorganic Chemistry · 2023 · 442-453
Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.
Complex 1 reddish-brown acicular crystals · Single Crystal
PXRD patterns compared with simulated patterns for complexes 1-3
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| PXRD crystallinity of complexes 1-3 | complexes 1-3 exhibit good crystallinity | — | — | Text Qualitative | p.445 · Crystal Structure Characterization · Figure S5 |
Complex 1 reddish-brown acicular crystals · Single Crystal
293 K; absorption correction with SADABS; solved/refined with SHELXS/SHELXL
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Complex 1 N1-Cu1-Cl1 angle | 164.31(10) | — | — | SI Table Exact Reported | SI p.5-6 · Table S2 · Table S2 |
| Complex 1 Cu1-Cl1 bond length | 2.1228(12) | — | — | SI Table Exact Reported | SI p.5-6 · Table S2 · Table S2 |
| Complex 1 Cu1-N1 bond length | 1.911(3) | — | — | SI Table Exact Reported | SI p.5-6 · Table S2 · Table S2 |
| Complex 1 unit cell a | 11.5922 | — | — | SI Table Exact Reported | SI p.5 · Table S1 · Table S1 |
| Complex 1 absorption coefficient | 2.262 | — | — | SI Table Exact Reported | SI p.5 · Table S1 · Table S1 |
| Complex 1 alpha | 90 | — | — | SI Table Exact Reported | SI p.5 · Table S1 · Table S1 |
| Complex 1 unit cell b | 5.5991 | — | — | SI Table Exact Reported | SI p.5 · Table S1 · Table S1 |
| Complex 1 beta | 95.288 | — | — | SI Table Exact Reported | SI p.5 · Table S1 · Table S1 |
| Complex 1 unit cell c | 16.7004 | — | — | SI Table Exact Reported | SI p.5 · Table S1 · Table S1 |
| Complex 1 crystal system | Monoclinic | — | — | SI Table Exact Reported | SI p.5 · Table S1 · Table S1 |
| Complex 1 calculated density | 1.902 | — | — | SI Table Exact Reported | SI p.5 · Table S1 · Table S1 |
| Complex 1 assigned dimensionality | 1D | — | — | Text Exact Reported | p.443 · Introduction |
| Complex 1 formula | C12H6N2O2CuCl | — | — | SI Table Exact Reported | SI p.5 · Table S1 · Table S1 |
| Complex 1 formula weight | 309.18 | — | — | SI Table Exact Reported | SI p.5 · Table S1 · Table S1 |
| Complex 1 gamma | 90 | — | — | SI Table Exact Reported | SI p.5 · Table S1 · Table S1 |
| Complex 1 GOF on F2 | 0.951 | — | — | SI Table Exact Reported | SI p.5 · Table S1 · Table S1 |
| Complex 1 R1 I>2sigma(I) | 0.0433 | — | — | SI Table Exact Reported | SI p.5 · Table S1 · Table S1 |
| Complex 1 Rint | 0.0569 | — | — | SI Table Exact Reported | SI p.5 · Table S1 · Table S1 |
| Complex 1 space group | P21/c | — | — | SI Table Exact Reported | SI p.5 · Table S1 · Table S1 |
| Complex 1 unit cell volume | 1079.45 | — | — | SI Table Exact Reported | SI p.5 · Table S1 · Table S1 |
| Complex 1 wR2 I>2sigma(I) | 0.0721 | — | — | SI Table Exact Reported | SI p.5 · Table S1 · Table S1 |
| Complex 1 Z | 4 | — | — | SI Table Exact Reported | SI p.5 · Table S1 · Table S1 |
Complex 2 green block crystals · Single Crystal
293 K; absorption correction with SADABS; solved/refined with SHELXS/SHELXL
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Complex 2 N5-Cu1-O7 angle | 174.55(8) | — | — | SI Table Exact Reported | SI p.5-6 · Table S2 · Table S2 |
| Complex 2 Cu1-N5 bond length | 2.021(2) | — | — | SI Table Exact Reported | SI p.5-6 · Table S2 · Table S2 |
| Complex 2 Cu1-O3 bond length | 1.9845(17) | — | — | SI Table Exact Reported | SI p.5-6 · Table S2 · Table S2 |
| Complex 2 unit cell a | 10.2296 | — | — | SI Table Exact Reported | SI p.5 · Table S1 · Table S1 |
| Complex 2 absorption coefficient | 0.696 | — | — | SI Table Exact Reported | SI p.5 · Table S1 · Table S1 |
| Complex 2 alpha | 100.162 | — | — | SI Table Exact Reported | SI p.5 · Table S1 · Table S1 |
| Complex 2 unit cell b | 12.6836 | — | — | SI Table Exact Reported | SI p.5 · Table S1 · Table S1 |
| Complex 2 beta | 93.91 | — | — | SI Table Exact Reported | SI p.5 · Table S1 · Table S1 |
| Complex 2 unit cell c | 14.4315 | — | — | SI Table Exact Reported | SI p.5 · Table S1 · Table S1 |
| Complex 2 crystal system | triclinic | — | — | SI Table Exact Reported | SI p.5 · Table S1 · Table S1 |
| Complex 2 calculated density | 1.617 | — | — | SI Table Exact Reported | SI p.5 · Table S1 · Table S1 |
| Complex 2 assigned dimensionality | 2D | — | — | Text Exact Reported | p.443 · Introduction |
| Complex 2 formula | C43H22CuN6O11 | — | — | SI Table Exact Reported | SI p.5 · Table S1 · Table S1 |
| Complex 2 formula weight | 862.2 | — | — | SI Table Exact Reported | SI p.5 · Table S1 · Table S1 |
| Complex 2 gamma | 104.622 | — | — | SI Table Exact Reported | SI p.5 · Table S1 · Table S1 |
| Complex 2 GOF on F2 | 1.016 | — | — | SI Table Exact Reported | SI p.5 · Table S1 · Table S1 |
| Complex 2 R1 I>2sigma(I) | 0.0455 | — | — | SI Table Exact Reported | SI p.5 · Table S1 · Table S1 |
| Complex 2 Rint | 0.0357 | — | — | SI Table Exact Reported | SI p.5 · Table S1 · Table S1 |
| Complex 2 space group | P-1 | — | — | SI Table Exact Reported | SI p.5 · Table S1 · Table S1 |
| Complex 2 unit cell volume | 1770.86 | — | — | SI Table Exact Reported | SI p.5 · Table S1 · Table S1 |
| Complex 2 wR2 I>2sigma(I) | 0.1141 | — | — | SI Table Exact Reported | SI p.5 · Table S1 · Table S1 |
| Complex 2 Z | 2 | — | — | SI Table Exact Reported | SI p.5 · Table S1 · Table S1 |
Complex 3 red block crystals · Single Crystal
293 K; absorption correction with SADABS; solved/refined with SHELXS/SHELXL
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Complex 3 Cl1-Cu2-Cl1#4 angle | 180.0 | — | — | SI Table Exact Reported | SI p.5-6 · Table S2 · Table S2 |
| Complex 3 Cu1-N1 bond length | 2.054(2) | — | — | SI Table Exact Reported | SI p.5-6 · Table S2 · Table S2 |
| Complex 3 Cu2-Cl1 bond length | 2.0969(16) | — | — | SI Table Exact Reported | SI p.5-6 · Table S2 · Table S2 |
| Complex 3 unit cell a | 12.1776 | — | — | SI Table Exact Reported | SI p.5 · Table S1 · Table S1 |
| Complex 3 absorption coefficient | 1.163 | — | — | SI Table Exact Reported | SI p.5 · Table S1 · Table S1 |
| Complex 3 alpha | 90 | — | — | SI Table Exact Reported | SI p.5 · Table S1 · Table S1 |
| Complex 3 unit cell b | 12.1776 | — | — | SI Table Exact Reported | SI p.5 · Table S1 · Table S1 |
| Complex 3 beta | 90 | — | — | SI Table Exact Reported | SI p.5 · Table S1 · Table S1 |
| Complex 3 unit cell c | 14.7629 | — | — | SI Table Exact Reported | SI p.5 · Table S1 · Table S1 |
| Complex 3 crystal system | tetragonal | — | — | SI Table Exact Reported | SI p.5 · Table S1 · Table S1 |
| Complex 3 calculated density | 1.603 | — | — | SI Table Exact Reported | SI p.5 · Table S1 · Table S1 |
| Complex 3 assigned dimensionality | 3D | — | — | Text Exact Reported | p.443 · Introduction |
| Complex 3 formula | C48H26Cl2Cu2N8O9 | — | — | SI Table Exact Reported | SI p.5 · Table S1 · Table S1 |
| Complex 3 formula weight | 1056.75 | — | — | SI Table Exact Reported | SI p.5 · Table S1 · Table S1 |
| Complex 3 gamma | 90 | — | — | SI Table Exact Reported | SI p.5 · Table S1 · Table S1 |
| Complex 3 GOF on F2 | 1.038 | — | — | SI Table Exact Reported | SI p.5 · Table S1 · Table S1 |
| Complex 3 R1 I>2sigma(I) | 0.0435 | — | — | SI Table Exact Reported | SI p.5 · Table S1 · Table S1 |
| Complex 3 Rint | 0.0313 | — | — | SI Table Exact Reported | SI p.5 · Table S1 · Table S1 |
| Complex 3 space group | P4/n | — | — | SI Table Exact Reported | SI p.5 · Table S1 · Table S1 |
| Complex 3 unit cell volume | 2189.25 | — | — | SI Table Exact Reported | SI p.5 · Table S1 · Table S1 |
| Complex 3 wR2 I>2sigma(I) | 0.1127 | — | — | SI Table Exact Reported | SI p.5 · Table S1 · Table S1 |
| Complex 3 Z | 2 | — | — | SI Table Exact Reported | SI p.5 · Table S1 · Table S1 |