Synthesis · Enhancing the Photocatalytic Degradation Efficiency of Dyes of Copper-Based Metal-Organic Frameworks through a Dimension-Induced Structural Strategy

3 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Complete recipeSource: Main

Route 1: Solvothermal

p.443 · Synthesis of Materials

Metal precursorsCuCl2.2H2O (17.1 mg, 0.1 mmol)

Linker precursors3-DPNDI (10.5 mg, 0.025 mmol); bpp (9.8 mg, 0.05 mmol) auxiliary ligand

SolventsMeOH/H2O (3 mL/2 mL)

Additivesbpp (1,3-di-(4-pyridyl)propane), non-coordinating auxiliary ligand

AtmosphereNot specified; sealed or closed vial conditions not explicitly stated.

Temperature140

Time72

Oxidant / reductantCuCl2.2H2O acts as copper/chloride source; no separate redox reagent reported.

Work-upUltrasound 10 min before heating; cooled to room temperature within 24 h; filtered; washed with MeOH; air-dried at ambient temperature.

ActivationNo solvent-exchange/thermal/vacuum activation reported.

Scalability context10 mL glass vial microbatch; yield 67.7%.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	CuCl2.2H2O	17.1 mg, 0.1 mmol	p.443 · Synthesis of Materials
Linker	3-DPNDI	10.5 mg, 0.025 mmol	p.443 · Synthesis of Materials
Additive	bpp	9.8 mg, 0.05 mmol	p.443 · Synthesis of Materials
Solvent	MeOH/H2O	3 mL/2 mL	p.443 · Synthesis of Materials

Complete recipeSource: Main

Route 2: Solvothermal

p.443 · Synthesis of Materials

Metal precursorsCuCl2.2H2O (8.6 mg, 0.05 mmol)

Linker precursors3-DPNDI (10.5 mg, 0.025 mmol); bpy (7.8 mg, 0.05 mmol) auxiliary ligand

SolventsMeOH/H2O (3 mL/2 mL)

Additivesbpy (2,2'-bipyridine), non-coordinating auxiliary ligand in final crystal structure

AtmosphereNot specified; sealed or closed vial conditions not explicitly stated.

Temperature140

Time72

Oxidant / reductantCuCl2.2H2O copper source; no separate redox reagent reported.

Work-upUltrasound 10 min before heating; cooled to room temperature within 24 h; filtered; washed with MeOH; air-dried at ambient temperature.

ActivationNo solvent-exchange/thermal/vacuum activation reported.

Scalability context10 mL glass vial microbatch; yield 35.3%.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	CuCl2.2H2O	8.6 mg, 0.05 mmol	p.443 · Synthesis of Materials
Linker	3-DPNDI	10.5 mg, 0.025 mmol	p.443 · Synthesis of Materials
Additive	bpy	7.8 mg, 0.05 mmol	p.443 · Synthesis of Materials
Solvent	MeOH/H2O	3 mL/2 mL	p.443 · Synthesis of Materials

Complete recipeSource: Main

Route 3: Solvothermal

p.443 · Synthesis of Materials

Metal precursorsCuCl2.2H2O (4.3 mg, 0.025 mmol)

Linker precursors3-DPNDI (10.5 mg, 0.025 mmol); bpp (9.8 mg, 0.05 mmol) auxiliary ligand

SolventsMeOH/H2O (3 mL/2 mL)

Additivesbpp (1,3-di-(4-pyridyl)propane), non-coordinating auxiliary ligand

AtmosphereNot specified; sealed or closed vial conditions not explicitly stated.

Temperature140

Time72

Oxidant / reductantCuCl2.2H2O copper/chloride source; no separate redox reagent reported.

Work-upUltrasound 10 min before heating; cooled to room temperature within 24 h; filtered; washed with MeOH; air-dried at ambient temperature.

ActivationNo solvent-exchange/thermal/vacuum activation reported.

Scalability context10 mL glass vial microbatch; yield 32.5%.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	CuCl2.2H2O	4.3 mg, 0.025 mmol	p.443 · Synthesis of Materials
Linker	3-DPNDI	10.5 mg, 0.025 mmol	p.443 · Synthesis of Materials
Additive	bpp	9.8 mg, 0.05 mmol	p.443 · Synthesis of Materials
Solvent	MeOH/H2O	3 mL/2 mL	p.443 · Synthesis of Materials