Electrical Transport — Enhancing the Photocatalytic Degradation Efficiency of Dyes of Copper-Based Metal-Organic Frameworks through a Dimension-Induced Structural Strategy

Measurement evidence

Electrical Transport

Enhancing the Photocatalytic Degradation Efficiency of Dyes of Copper-Based Metal-Organic Frameworks through a Dimension-Induced Structural Strategy · Jia R.-Q., Chen Y.-J., Zuo L.-Y. et al. · Inorganic Chemistry · 2023 · 442-453

2 measurement groups · 5 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Electrochemical impedance spectroscopy (EIS)

Impedance spectroscopy

Complex 1 reddish-brown acicular crystals · Single Crystal

Nyquist/EIS spectra of complexes 1-3 used as conductivity/charge separation proxy

Geometry: photoelectrochemical/electrode geometry not specified
Context: pristine
Measurement source: p.448 · Electrochemical Analysis · Figure 3d

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
EIS arc-radius/conductivity comparisonMarked as a best value within this paper	arc radius of 1 similar to 3 and smaller than 2; conductivity of 1 superior to 2 and similar to 3	—	—	Text Qualitative	p.448 · Electrochemical Analysis · Figure 3d

Mott-Schottky analysis

Complex 1 reddish-brown acicular crystals · Single Crystal

Positive slope used to assign n-type semiconductor behaviour; flat-band potential read from Mott-Schottky plot

Geometry: electrode, details not specified
Context: pristine
Measurement source: p.450 · Photocatalytic Mechanism · Figure 7a

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Complex 1 conduction-band potential	~0.86 eV	—	—	Calculated From Reported Approximate	p.450 · Photocatalytic Mechanism · Figure 8
Complex 1 flat-band potential	~0.66 V	—	—	Text Approximate	p.450 · Photocatalytic Mechanism · Figure 7a
Complex 1 semiconductor type	n-type	—	—	Text Qualitative	p.450 · Photocatalytic Mechanism · Figure 7a
Complex 1 valence-band potential	2.71 eV	—	—	Calculated From Reported Rounded Reported	p.450 · Photocatalytic Mechanism · Figure 8