Microscopy Morphology — Processable UiO-66 Metal-Organic Framework Fluid Gel and Electrical Conductivity of Its Nanofilm with Sub-100 nm Thickness

4 measurement groups · 11 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

80 nm UiO-66 nanofilm · Thin Film

Olympus OMCLA160TS cantilever; 80 and 150 nm UiO-66 films compared with same height scale.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
RMS roughness, 150 nm film	22 nm	—	—	Text Exact Reported	p006 / SI p6 · Figure S10 caption · Figure S10
RMS roughness, 80 nm filmMarked as a best value within this paper	13 nm	—	—	Text Exact Reported	p006 / SI p6 · Figure S10 caption · Figure S10

UiO-66 fluid gel · Unknown

SEM samples sputtered with Pt for 60 s; TEM samples dispersed in ethanol and drop-cast onto carbon-film copper grids.

Atmosphere: ambient drying for TEM preparation
Context: fluid gel compared with powder and nonflowing gel controls
Measurement source: p002-p004 / 30845-30847 · Materials and Methods; Results and Discussion · Figures 2 and 3d

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
mean particle size by HRTEM	approximately 10 nm	—	—	Text Approximate	p004 / 30847 · Results and Discussion · Figure 3d
SAED d-spacing	11.8 A	—	—	Text Exact Reported	p004 / 30847 · Results and Discussion · Figure 3d
fluid-gel particle size by SEM	smaller than 100 nm	—	upper bound	Text Approximate	p003 / 30846 · Results and Discussion · Figure 2c
fluid-gel colloidal stability	stable for at least 1 month	—	at least	Text Rounded Reported	p003 / 30846 · Results and Discussion · Figure 2d
microcrystalline powder average crystal size	500 nm	—	—	Text Rounded Reported	p003 / 30846 · Results and Discussion · Figure 2a

UiO-66 nanofilm thickness series · Thin Film

Particle size of UiO-66 as a function of film thickness determined by TEM and GIXRD.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source

UiO-66 nanofilm thickness series · Thin Film

Films prepared from UiO-66 fluid gel in DI water at 0.025-0.500 g mL^-1 and spin speeds 1000-5000 rpm for 60 s.

Geometry: spin-coated films on cleaned glass
Context: pristine UiO-66 thin films
Measurement source: p004 / 30847 · Results and Discussion · Figure 4; Figure S4

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
minimum concentration for full substrate coverage	higher than 0.100 g mL-1	—	threshold higher than value	Text Approximate	p004 / 30847 · Results and Discussion · Figure 4; Figure S4
film thickness at 1000 rpm for 0.1 g mL-1 fluid gel	80 nm at 1000 rpm	—	—	Text Rounded Reported	p004 / 30847 · Results and Discussion · Figure 4a,b; Figure S4
film thickness at 5000 rpm for 0.1 g mL-1 fluid gelMarked as a best value within this paper	40 nm at 5000 rpm	—	—	Text Rounded Reported	p004 / 30847 · Results and Discussion · Figure 4b; Figure S4a
controllable film thickness range	40 to 150 nm	—	—	Text Range	p004 / 30847 · Results and Discussion · Figure 4; Figure S4