Spectroscopy — A porous proton-relaying metal-organic framework material that accelerates electrochemical hydrogen evolution

4 measurement groups · 9 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

NU-1000_Ni-S · Electrode

Elemental ratios for NU-1000_Ni-S system after 2 min electrodeposition.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
EDS Ni:S ratio	1.7:1.0	—	—	Text Rounded Reported	2 · Results - Electrocatalyst synthesis · Supplementary Table 1
EDS Zr6:Ni ratio	2.0:1.0	—	—	SI Table Rounded Reported	11 · Supplementary Table 1 · Supplementary Table 1
ICP-OES Ni:S ratio	1.6:1.0	—	—	Text Rounded Reported	2 · Results - Electrocatalyst synthesis · Supplementary Table 1
ICP Zr6:Ni ratio	1.6:1.0	—	—	SI Table Rounded Reported	11 · Supplementary Table 1 · Supplementary Table 1

benzoate-modified FTO_NU-1000 · Electrode

Benzoate-modified NU-1000 sample; integration of benzoic acid and H4TBAPy linker peaks.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
benzoates per Zr6 node	4 benzoic acids per Zr6 node	—	estimated from NMR integration	Caption Approximate	8 · Supplementary Figure 10 · Supplementary Figure 10

NU-1000_Ni-S · Electrode

NU-1000_Ni-S sample irradiated with 514.5 nm laser; 60 s acquisition averaged over ten runs.

Geometry: thin-film sample
Context: composite hybrid
Measurement source: 3, 7 · Results - Electrocatalyst synthesis; Methods - Instrumentation · Supplementary Figure 5

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Raman peaks assigned to Ni3S2	176, 190, 217, 300, 319 and 341 cm-1	—	—	Text Rounded Reported	3 · Results - Electrocatalyst synthesis · Supplementary Figure 5

NU-1000_Ni-S · Electrode

S 2p, Ni 2p and survey spectrum for NU-1000_Ni-S film.

Geometry: thin-film electrode
Context: composite hybrid
Measurement source: 2 · Results - Electrocatalyst synthesis · Supplementary Figure 2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Ni 2p broad peak binding energy	centred around 860 eV	—	—	Text Approximate	2 · Results - Electrocatalyst synthesis · Supplementary Figure 2
S 2p sulfide binding energy	ca. 162 eV	—	—	Text Approximate	2 · Results - Electrocatalyst synthesis · Supplementary Figure 2
oxidised sulfur XPS peak	peak at 168 eV	—	—	Text Rounded Reported	2 · Results - Electrocatalyst synthesis · Supplementary Figure 2