Yuan Y., Zhou Z., Hao X. et al. · Physica Scripta · 2024 · 105604
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
The flexible AgNPs/Ni3(HHTP)2 substrate enables qualitative and quantitative SERS detection of food additives and pesticide residues at low concentrations.
Caveat: Application testing is SERS-specific; Table S3 gives regulatory/safe-level context, but the SI table lists 10^-8 mol/L for thiram/thiabendazole while main text reports 10^-9 M detection.
11 · Conclusion · Linked to 16 structured results
The paper discusses Ni3(HHTP)2 as conductive but does not report a first-hand electrical-transport or thermoelectric measurement for the synthesised samples.
Caveat: Conductivity is invoked from prior literature/background rather than measured here.
2 · Introduction
The AgNPs/Ni3(HHTP)2 composite exhibits better SERS enhancement than AgNPs or Ni3(HHTP)2 alone due to synergistic AgNP and conductive-MOF effects.
Caveat: Control comparison is described qualitatively and supported by SI Figure S9; no quantitative control intensities were extracted from the rendered SI.
8 · SERS Studies · Figure S9 · Linked to 3 structured results
XRD, FTIR, XPS, SEM, and EDX support successful synthesis of Ni3(HHTP)2 films composed of rod-shaped structures.
Caveat: No CIF/refinement or porosity data were reported in the provided documents.
5 · Characterization · Figure 3 · Linked to 5 structured results
SERS enhancement is attributed to AgNP electromagnetic/LSPR enhancement plus possible Ni3(HHTP)2-mediated charge transfer.
Caveat: Charge-transfer explanation is inferential; electrical conductivity is cited as a known property rather than measured in this work.
10 · SERS Enhancement mechanism · Figure 9 · Linked to 7 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| silver nanoparticles | AgNPsmetallic silver nanoparticles | 0D · PristineCitrate-reduced silver nanoparticles, PVP-modified before monolayer-film formation. | 3 · Experimental section |
| AgNPs/Ni3(HHTP)2Browse family: Ni₃(HHTP)₂ / Ni–HHTP | AgNPs/Ni3(HHTP)2Ni2+ in Ni3(HHTP)2 plus metallic Ag nanoparticles · HHTP in Ni3(HHTP)2 | 2D · CompositeComposite SERS substrate formed by loading a monolayer AgNP film on rod-shaped Ni3(HHTP)2. | 2 · Introduction |
| Ni3(HHTP)2Browse family: Ni₃(HHTP)₂ / Ni–HHTP | Ni3(HHTP)2Ni2+ from nickel acetate · 2,3,6,7,10,11-triphenylenehexol (HHTP) | 2D · PristineTwo-dimensional pi-MOF; XRD peaks assigned to (100), (200), (210), and (001) planes. | 2 · Introduction |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| PVP-modified monolayer AgNP filmresearch_0877__mat__mat_agnp | Thin Film · Composite Component · Composite | PVP-modified AgNPs assembled into dense metallic-lustre filmsilicon wafer before transfer; liquid-liquid interface during assembly · monolayer | 4 · Experimental section · Figure S1 |
| flexible PDMS AgNPs/Ni3(HHTP)2 SERS substrateresearch_0877__mat__mat_agnp_ni_hhtp | Thin Film · Target Sample · Composite | flexible substrate stored in a vacuum dryerPDMS · PDMS film cast in 1 mm deep groove; Ni3(HHTP)2 layer approximately 1.28 um; AgNP monolayer | 6 · Results and discussions · Figure S6 |
| AgNPs/Ni3(HHTP)2 SERS substrate on silicon waferresearch_0877__mat__mat_agnp_ni_hhtp | Thin Film · Target Sample · Composite | AgNP monolayer transferred onto Ni3(HHTP)2 and dried at 60 Csilicon wafer · Ni3(HHTP)2 layer approximately 1.28 um; AgNP monolayer | 4 · Experimental section |
| Ni3(HHTP)2 mixed with crystal violet in ethanolresearch_0877__mat__mat_ni_hhtp | Unknown · Paper Level Unspecified · Guest Loaded | Ni3(HHTP)2 and CV mixed for UV-vis adsorption/charge-transfer assessmentethanol solution/dispersion | 4 · Adsorptio measurements of Ni3(HHTP)2 |
| rod-shaped Ni3(HHTP)2 filmresearch_0877__mat__mat_ni_hhtp | Thin Film · Pristine Control · Pristine Framework | blue-black film formed at solution surface, lifted and dried at 60 C overnightlifted/transferred by hydrophilic PDMS film and silicon wafer · approximately 1.28 um | 3 · Experimental section |