Spectroscopy — A Novel Electrocatalyst Pd(II)@Ni3(HITP)2 for Ultrasensitive Detection of Chloramphenicol: Experimental and Computational Investigation

Measurement evidence

Spectroscopy

A Novel Electrocatalyst Pd(II)@Ni3(HITP)2 for Ultrasensitive Detection of Chloramphenicol: Experimental and Computational Investigation · He Y., Li N.-H., Wen F. et al. · Chemistry - A European Journal · 2023 · e202203839

2 measurement groups · 10 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

XPS

X-ray photoelectron spectroscopy

Pd(II)@Ni3(HITP)2, PdCl2 loading mass 0.05 mL/mg · Powder

XPS survey and high-resolution C 1s, N 1s, Ni 2p, Pd 3d, Cl 2p for Pd(II)@Ni3(HITP)2.

Geometry: powder
Context: application_with_pristine_control
Measurement source: 3-4 · Characterization and Loading Mechanism · Figure 2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Cl(-I) peak	198.1 eV	—	—	Text Exact Reported	4 · Characterization and Loading Mechanism · Figure 2f
Pd(II) 3d3/2 peak	342.6 eV	—	—	Text Exact Reported	4 · Characterization and Loading Mechanism · Figure 2e
Pd(II) 3d5/2 peak	337.4 eV	—	—	Text Exact Reported	4 · Characterization and Loading Mechanism · Figure 2e

XPS

X-ray photoelectron spectroscopy

Ni3(HITP)2 powder · Powder

XPS survey and high-resolution C 1s, N 1s, Ni 2p for pristine Ni3(HITP)2.

Geometry: powder
Context: pristine/control/model context
Measurement source: 3 · Characterization and Loading Mechanism · Figure S1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
C 1s benzene C peak	284.8 eV	—	—	Text Exact Reported	3 · Characterization and Loading Mechanism · Figure S1b
C-N peak	287.9 eV	—	—	Text Exact Reported	3 · Characterization and Loading Mechanism · Figure S1b
N(III) 1s peak	399.3 eV	—	—	Text Exact Reported	3 · Characterization and Loading Mechanism · Figure S1c
Ni(II) 2p1/2 peak	872.3 eV	—	—	Text Exact Reported	3 · Characterization and Loading Mechanism · Figure S1d
Ni(II) 2p3/2 peak	855.2 eV	—	—	Text Exact Reported	3 · Characterization and Loading Mechanism · Figure S1d
Ni satellite peak	881.1 eV	—	—	Text Exact Reported	3 · Characterization and Loading Mechanism · Figure S1d
Ni satellite peak	863.4 eV	—	—	Text Exact Reported	3 · Characterization and Loading Mechanism · Figure S1d