Electrochemistry Application — Conductive Metal-Organic Frameworks Bearing M−O4 Active Sites as Highly Active Biomass Valorization Electrocatalysts

10 measurement groups · 31 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Bulk electrolysis / chronoamperometry with NMR product quantification

Nuclear magnetic resonance Chronoamperometry

Co-CAT-Carbon Paper · Electrode

10 mM HMF in 1 M KOH; Co-CAT on carbon paper; 1.42 V vs RHE; products quantified by NMR with internal standard.

Geometry: two-compartment glass electrochemical cell
Context: Composite electrode sample
Measurement source: 4-5 · Results and Discussion · Figure 3e and Figure S5

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Co-CAT FDCA yield after 20 hMarked as a best value within this paper	99.3 %	—	—	Text Exact Reported	5 · Results and Discussion · Figure S5
Co-CAT faradaic efficiency after 20 hMarked as a best value within this paper	97.6 %	—	—	Text Exact Reported	5 · Results and Discussion · Figure S5
Co-CAT faradaic efficiency at 1.42 V in Table S1	97.7 % at 1.42 V	—	—	SI Table Exact Reported	14 · Table S1 · Table S1
Co-CAT TOF based on transferred electrons	286 h-1	—	—	Text Exact Reported	5 · Results and Discussion · Figure S5
Co-CAT TOF based on FDCA molecules	48 h-1	—	—	Text Exact Reported	5 · Results and Discussion · Figure S5
Co-CAT turnover number based on transferred electrons	5718	—	—	Text Exact Reported	5 · Results and Discussion · Figure S5
Co-CAT turnover number based on FDCA molecules	953	—	—	Text Exact Reported	5 · Results and Discussion · Figure S5

Bulk electrolysis / chronoamperometry with NMR product quantification

Nuclear magnetic resonance Chronoamperometry

Ni-CAT-Carbon Paper · Electrode

10 mM HMF in 1 M KOH; Ni-CAT on carbon paper; 1.42 V vs RHE unless otherwise specified; products quantified by NMR with internal standard.

Geometry: two-compartment glass electrochemical cell
Context: Composite electrode sample
Measurement source: 5 · Results and Discussion · Figure 3e and Table S2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Ni-CAT FDCA yield after 5 h	98.7 %	—	—	Text Exact Reported	5 · Results and Discussion · Figure 3e
Ni-CAT faradaic efficiency at 1.38 VMarked as a best value within this paper	97.4 %	—	—	Text Rounded Reported	5 · Results and Discussion · Table S2
Ni-CAT calculated faradaic efficiency at 1.38 V after 2.5 h	92.32 %	—	—	SI Table Exact Reported	16 · Table S2 · Table S2
Ni-CAT calculated faradaic efficiency at 1.38 V after 3.5 hMarked as a best value within this paper	97.45 %	—	—	SI Table Exact Reported	16 · Table S2 · Table S2
Ni-CAT faradaic efficiency after 5 h at 1.42 V	86.8 %	—	—	Text Exact Reported	5 · Results and Discussion · Figure 3e
Ni-CAT TOF based on transferred electrons	6493 h-1	—	—	Text Exact Reported	5 · Results and Discussion · Figure 3e
Ni-CAT TOF based on FDCA molecules	1082 h-1	—	—	Text Exact Reported	5 · Results and Discussion · Figure 3e
Ni-CAT turnover number based on transferred electrons	32466	—	—	Text Exact Reported	5 · Results and Discussion · Figure 3e
Ni-CAT turnover number based on FDCA molecules	5411	—	—	Text Exact Reported	5 · Results and Discussion · Figure 3e

Cyclic voltammetry

Voltammetry

Co-CAT-Carbon Paper · Electrode

Three-electrode cell; 1 M KOH with/without 10 mM HMF; carbon-paper-supported Co-CAT.

Geometry: Co-CAT on carbon paper
Context: Composite electrode sample
Measurement source: 4 · Results and Discussion · Figure 3c

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
M-CAT carbon-paper current-density increase versus FTO	almost ten times higher	—	—	Text Approximate	4 · Results and Discussion · Figure 3c,d
Co-CAT redox-active loading increase on carbon paper versus FTO	14.7 times greater	—	—	Text Exact Reported	4 · Results and Discussion · Figure 3c
Co-CAT HMFOR onset potentialMarked as a best value within this paper	1.05 V vs RHE	—	—	SI Table Exact Reported	14 · Table S1 · Table S1

Cyclic voltammetry

Voltammetry

Co-CAT-FTO · Electrode

Three-electrode cell; 1 M KOH, then 1 M KOH plus 10 mM HMF; scan rate 20 mV s-1; Ag/AgCl reference converted to RHE.

Geometry: Co-CAT-FTO working electrode
Context: Composite electrode sample
Measurement source: 3 · Results and Discussion · Figure 3a

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
CoII/III redox wave potential on FTO	1.0 V vs RHE	—	—	Text Rounded Reported	3 · Results and Discussion · Figure 3a

Cyclic voltammetry

Voltammetry

Ni-CAT-Carbon Paper · Electrode

Three-electrode cell; 1 M KOH with/without 10 mM HMF; carbon-paper-supported Ni-CAT.

Geometry: Ni-CAT on carbon paper
Context: Composite electrode sample
Measurement source: 4 · Results and Discussion · Figure 3d

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Ni-CAT active-site loading increase on carbon paper versus FTO	2.7 greater	—	—	Text Exact Reported	4 · Results and Discussion · Figure 3d
Ni-CAT HMFOR onset potential	1.38 V vs RHE	—	—	SI Table Exact Reported	14 · Table S1 · Table S1

Cyclic voltammetry

Voltammetry

Ni-CAT-FTO · Electrode

Three-electrode cell; 1 M KOH, then 1 M KOH plus 10 mM HMF; scan rate 20 mV s-1; Ag/AgCl reference converted to RHE.

Geometry: Ni-CAT-FTO working electrode
Context: Composite electrode sample
Measurement source: 3 · Results and Discussion · Figure 3b

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
NiII/III redox couple potential on FTO	1.35 V vs RHE	—	—	Text Rounded Reported	3 · Results and Discussion · Figure 3b

Long-duration electrolysis with NMR product quantification

Nuclear magnetic resonance

Co-CAT-Carbon Paper · Electrode

5 mM HMF; Co-CAT; 1.12 V vs RHE; 5 days electrolysis.

Geometry: Co-CAT electrode
Context: Composite electrode sample
Measurement source: 5 · Results and Discussion · Figure S6

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Co-CAT faradaic efficiency at 1.12 V after 5 days	31.13 %	—	—	Text Exact Reported	5 · Results and Discussion · Figure S6
Co-CAT FDCA yield at 1.12 V after 5 days	25 %	—	—	Text Rounded Reported	5 · Results and Discussion · Figure S6

Recyclability electrolysis with repeated HMF additions

Ni-CAT-Carbon Paper · Electrode

10 mM HMF added into 1 M KOH each time reactant was almost exhausted; aliquots taken for NMR.

Geometry: Ni-CAT electrode
Context: Composite electrode sample
Measurement source: 10 · Figure S9 · Figure S9

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Ni-CAT recyclability FDCA concentration after cycle 1	9.22 mM	—	—	Figure Axis Exact Reported	10 · Figure S9 · Figure S9b
Ni-CAT recyclability FDCA concentration after cycle 2	18.57 mM	—	—	Figure Axis Exact Reported	10 · Figure S9 · Figure S9b
Ni-CAT recyclability FDCA concentration after cycle 3	27.46 mM	—	—	Figure Axis Exact Reported	10 · Figure S9 · Figure S9b
Ni-CAT recyclability FDCA concentration after cycle 4	36.43 mM	—	—	Figure Axis Exact Reported	10 · Figure S9 · Figure S9b

Linear sweep voltammetry Tafel analysis

Voltammetry Tafel and polarisation analysis

Co-CAT powder on glassy carbon disk · Electrode

Rotating disk configuration at 1600 rpm; LSV scan 0.5 mV/s; HMF transport enhanced.

Geometry: Co-CAT powder on glassy carbon disk
Context: Composite electrode sample
Measurement source: 5 · Results and Discussion · Figure 3f

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Co-CAT Tafel slope	141.16 mV dec-1	—	—	Text Exact Reported	5 · Results and Discussion · Figure 3f

Linear sweep voltammetry Tafel analysis

Voltammetry Tafel and polarisation analysis

Ni-CAT powder on glassy carbon disk · Electrode

Rotating disk configuration at 1600 rpm; LSV scan 0.5 mV/s; HMF transport enhanced.

Geometry: Ni-CAT powder on glassy carbon disk
Context: Composite electrode sample
Measurement source: 5 · Results and Discussion · Figure 3f

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Ni-CAT Tafel slopeMarked as a best value within this paper	42.34 mV dec-1	—	—	SI Table Exact Reported	14 · Table S1 · Table S1