Consensus SummaryHigh supportConsensus
The outlook frames performance optimisation as application-specific: conductivity for supercapacitors, redox sites for LIB/SIB, aqueous stability for ZIB, and pore volume/SSA for Li-S and Na-I hosts.
Evidence basis: review_reasoning
Caveat: This is a synthesis of review conclusions, not a quantitative ranking.
p019 · Conclusions and Outlook
Consensus SummaryHigh supportApplication Relevance
For LIBs and related batteries, the review identifies rigid pi-networks, redox-active sites and well-defined channels as the main advantages of 2D c-MOF electrodes.
Evidence basis: multi_reference
Caveat: Primary validation is needed for each chemistry.
p008 · Lithium-Ion Batteries
Author InterpretationHigh supportCaveat
Bulk powder 2D c-MOFs are criticised because buried active sites hinder ion diffusion and lower site utilisation.
Evidence basis: review_reasoning
Caveat: Magnitude depends on particle size and electrode processing.
p010 · Lithium-Ion Batteries
Author InterpretationHigh supportCaveat
The review concludes that polycrystalline bulk powders limit charge transport and conductivity through grain boundaries and defects.
Evidence basis: review_reasoning
Caveat: The scale of the limitation depends on processing and electrode architecture.
p019 · Conclusions and Outlook
Author InterpretationHigh supportApplication Relevance
For electrocatalysis, the review argues that adjustable metal-linker networks give 2D c-MOFs tunable catalytic selectivity compared with conventional carbon catalysts.
Evidence basis: multi_reference
Caveat: Benchmark values are reaction- and composite-specific.
p016 · 2D c-MOFs for Electrochemical Energy Conversion
Consensus SummaryHigh supportCaveat
Despite strong supercapacitor performance, the review says charge-storage mechanisms in 2D c-MOFs remain insufficiently understood.
Evidence basis: review_reasoning
Caveat: Mechanistic studies exist for selected systems but not the broader family.
p007 · Supercapacitors
Author InterpretationHigh supportTransport Mechanism
The review attributes 2D c-MOF conductivity to in-plane charge delocalisation and out-of-plane pi-pi stacking that forms ion-accessible 1D channels.
Evidence basis: review_reasoning
Caveat: Mechanistic importance will vary with metal-linker chemistry and stacking disorder.
p001 · Introduction
Author InterpretationMedium supportStructure Property Link
Fe doping and bimetallic centres are used as examples of electronic-structure modulation that can improve OER and CO2RR performance.
Evidence basis: multi_reference
Caveat: Optimisation appears composition-specific and cannot be generalised without primary data.
p017 · 2D c-MOFs for Electrochemical Energy Conversion
Author InterpretationHigh supportTransport Mechanism
Strong d-p orbital hybridisation between metal nodes and pi-conjugated linkers is presented as the central bonding basis for efficient in-plane electron transport.
Evidence basis: review_reasoning
Caveat: The review does not quantify hybridisation across all frameworks.
p003 · Design Principles of 2D c-MOFs
Author InterpretationHigh supportApplication Relevance
The review presents 2D c-MOFs as promising polar, conductive, porous hosts for iodine and sulfur species where carbon hosts suffer weak affinity for polar intermediates.
Evidence basis: multi_reference
Caveat: Host function depends on pore volume, polarity and conductivity together.
p014 · Lithium-Sulfur Batteries
Author InterpretationHigh supportMeasurement Interpretation
For NiHAB, in situ Raman and XAS are reviewed as evidence that pseudocapacitance is mainly ligand-redox governed and pH-dependent.
Evidence basis: single_reference
Caveat: Specific to NiHAB and selected electrolytes.
p007 · Supercapacitors
Author InterpretationMedium supportStructure Property Link
HAB-based examples are used to argue that ligand selection controls dense active-site packing and miniaturised capacitive performance.
Evidence basis: single_reference
Caveat: Based on selected review examples rather than a systematic meta-analysis.
p006 · Supercapacitors
Consensus SummaryHigh supportStructure Property Link
Linker geometry and symmetry are used to explain lattice topology and pore diameter, which then affect transport and electrolyte access.
Evidence basis: multi_reference
Caveat: The review summarises families rather than deriving a universal geometric rule.
p003 · Design Principles of 2D c-MOFs
Consensus SummaryHigh supportDefinition Scope
Conventional MOFs are framed as poor intrinsic electronic conductors, motivating 2D conductive MOFs for electrochemical applications.
Evidence basis: multi_reference
Caveat: This is a broad review framing statement rather than a new measurement.
p001 · Introduction
Author InterpretationMedium supportStructure Property Link
Nanowire arrays and nanosheets are interpreted as improving electrode/electrolyte charge transfer compared with irregular powders.
Evidence basis: single_reference
Caveat: Examples are application-specific and may depend on substrate and composite design.
p006 · Supercapacitors
Author InterpretationHigh supportSynthesis Strategy
Non-planar ligand strategies are presented as a route to overcome poor solubility of large planar pi-systems and expand the structural repertoire of 2D c-MOFs.
Evidence basis: multi_reference
Caveat: Still positioned as an emerging strategy with limited examples.
p003 · Design Principles of 2D c-MOFs
Consensus SummaryHigh supportApplication Relevance
Sodium-ion storage is framed as requiring electrode materials distinct from LIBs because Na+ is larger and heavier than Li+.
Evidence basis: review_reasoning
Caveat: The review focuses on selected 2D c-MOF examples rather than all SIB chemistries.
p011 · Sodium-Ion Batteries
Author InterpretationMedium supportMeasurement Interpretation
The review treats combined molecular dynamics and experiment as a useful route to connect crystal structure, surface area and ion transport in MOF supercapacitors.
Evidence basis: single_reference
Caveat: Validated for selected Ni-based systems only.
p008 · Supercapacitors
Consensus SummaryMedium supportStructure Property Link
Layer stacking mode is treated as a structural control over band structure, electronic properties and pore-channel dimensions.
Evidence basis: review_reasoning
Caveat: The review states the relationship but does not benchmark stacking-resolved transport values.
p003 · Design Principles of 2D c-MOFs
Consensus SummaryHigh supportCaveat
The review identifies limited structural diversity as a field-level bottleneck because reported 2D c-MOFs rely on a narrow set of pi-conjugated ligands.
Evidence basis: review_reasoning
Caveat: The statement reflects the review authors' field synthesis.
p018 · Conclusions and Outlook
Consensus SummaryHigh supportTransport Mechanism
Effective 2D c-MOF supercapacitors require the simultaneous optimisation of rapid charge transport, surface area, porosity and redox-active sites.
Evidence basis: review_reasoning
Caveat: Balance between EDLC and pseudocapacitance is material-specific.
p005 · Supercapacitors
Author InterpretationHigh supportStructure Property Link
Thin-film 2D c-MOF morphologies are presented as more device-relevant than bulk powders because they expose active sites and can enhance conductivity.
Evidence basis: multi_reference
Caveat: Film mechanical strength and dimensional control remain challenging.
p004 · Synthesis of 2D c-MOFs
Consensus SummaryHigh supportCaveat
Top-down exfoliation is useful for nanosheets but lacks precise control over homogeneous lateral size and thickness.
Evidence basis: review_reasoning
Caveat: The review does not compare size distributions quantitatively.
p005 · Synthesis of 2D c-MOFs
Consensus SummaryHigh supportApplication Relevance
Aqueous ZIB electrolytes are described as enabling much higher ionic conductivity than non-aqueous electrolytes, making stable conductive 2D c-MOF cathodes attractive.
Evidence basis: multi_reference
Caveat: Aqueous stability must still be demonstrated for each framework.
p012 · Zinc-Ion Batteries