Wang M., Wang H., Cheng J. · Advanced Materials Technologies · 2024 · 2301678
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
The CNT/GOx@ZIF-8 biosensor can determine salivary glucose in real samples and tracks blood glucose trends with moderate Pearson correlation.
Caveat: Human validation was small, with 21 samples from three volunteers for blood correlation.
p006 · 2.6. Practical Evaluation · Figure 6 · Linked to 3 structured results
The article describes excellent electroconductibility from electrochemical current response, but does not report intrinsic electrical conductivity, mobility, Seebeck coefficient, thermal conductivity or thermoelectric measurements for ZIF-8 or CNT/GOx@ZIF-8.
Caveat: Electrochemical CV and amperometric evidence is application-relevant but not a direct bulk transport measurement.
p004 · 2.4. Electrochemical Characterization · Figure 4a · Linked to 2 structured results
High glucose-sensing performance is attributed to the combined roles of GOx for specific catalysis, CNTs for electron conduction and ZIF-8 for stability and porous enzyme encapsulation.
Caveat: Optimisation data in SI Figure S1 support the chosen composition, but the SI does not provide separate preparation recipes for every control variant.
p004 · 2.4. Electrochemical Characterization · Figure 4b · Linked to 7 structured results
ZIF-8 encapsulation protects GOx and improves operational/storage stability while retaining glucose access through micro- and mesopores.
Caveat: The protective mechanism is inferred from stability comparisons and pore-size arguments; no atomistic transport pathway is directly measured.
p007 · 3. Conclusion · Linked to 5 structured results
CNTs distributed through the CNT/GOx@ZIF-8 nanomesh provide conductive electron pathways from GOx active sites to the electrode, compensating for the insulating ZIF-8 component.
Caveat: The paper reports electrochemical current response rather than intrinsic conductivity, carrier mobility or four-probe transport.
p005 · 2.4. Electrochemical Characterization · Figure 4 · Linked to 4 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| CNT/GOx | CNT/GOx non-MOF compositenone · none | 1D · CompositeCNTs cross-linked by GOx without ZIF-8 coating. | p003 · 2.2. Characterization of CNT/GOx@ZIF-8 · Figure 2a |
| CNT/GOx@ZIF-8Browse family: ZIF-8 / Zn(mIm)₂ | CNT/GOx@ZIF-8 composite nanomesh; exact stoichiometry not reportedZn2+ ZIF-8 nanoparticles · 2-methylimidazole (2-MI) | unknown · CompositeNecklace-like/interlaced conductive nanomesh where GOx-encapsulated ZIF-8 grows along CNTs. | p002 · Introduction |
| CNT@ZIF-8 / CNT/ZIF-8Browse family: ZIF-8 / Zn(mIm)₂ | CNT/ZIF-8 composite; exact stoichiometry not reportedZn2+ ZIF-8 nanoparticles · 2-methylimidazole (2-MI) | unknown · CompositeCNT-ZIF-8 composite control without GOx. | p005 · Figure caption · Figure 3b |
| GOx@ZIF-8Browse family: ZIF-8 / Zn(mIm)₂ | GOx-loaded ZIF-8; exact stoichiometry not reportedZn2+ ZIF-8 nanoparticles · 2-methylimidazole (2-MI) | 3D · CompositeEnzyme-encapsulated ZIF-8 control without CNT conductive network. | p006 · 2.4. Electrochemical Characterization · Figure 4 |
| ZIF-8Browse family: ZIF-8 / Zn(mIm)₂ | Zn(2-methylimidazolate)2 framework; exact formula not reportedZn2+ from Zn(NO3)2.6H2O · 2-methylimidazole (2-MI) | 3D · PristineZeolitic imidazolate framework-8; simulated ZIF-8 XRD used as a reference and ZIF-8 nanoparticles coat the composite nanostructure. | p002 · 2.1. Design and Working Principle of the Biosensor · Figure 1 |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| CNT/GOx electroderesearch_0629__mat__mat_cnt_gox | Electrode · Composite Component · Composite | CNT and GOx control without ZIF-8.screen-printing carbon electrode (SPCE), inferred from electrode comparison | p006 · 2.4. Electrochemical Characterization · Figure 4a,b |
| CNT/GOx@ZIF-8 biosensor electroderesearch_0629__mat__mat_cnt_gox_zif8 | Electrode · Target Sample · Composite | CNT/GOx@ZIF-8 and 5% Nafion drop-cast on SPCE, dried 1 h, rinsed, and immersed in PBS before testing.screen-printing carbon electrode (SPCE) | p009 · Fabrication of CNT/GOx@ZIF-8 Biosensor · Figure 1b |
| CNT/GOx@ZIF-8 nanomeshresearch_0629__mat__mat_cnt_gox_zif8 | Powder · Target Sample · Composite | Washed suspension redispersed in 5 mL ultrapure water for later use. | p009 · 4. Experimental Section |
| CNT@ZIF-8 / CNT/ZIF-8research_0629__mat__mat_cnt_zif8 | Powder · Composite Component · Composite | Control composite without glucose oxidase. | p005 · Figure caption · Figure 3b |
| GOx electrode / GOx in solutionresearch_0629__mat__mat_cnt_gox | Electrode · Model System · Model | GOx-only comparator.screen-printing carbon electrode (SPCE) for electrochemical control; solution for kinetic comparison | p004 · 2.3. Catalytic Properties · Figure 3f |
| GOx@ZIF-8 electroderesearch_0629__mat__mat_gox_zif8 | Electrode · Pristine Control · Guest Loaded | Enzyme-loaded ZIF-8 electrode control without CNTs.screen-printing carbon electrode (SPCE), inferred from electrode comparison | p006 · 2.4. Electrochemical Characterization · Figure 4a,b |
| ZIF-8research_0629__mat__mat_zif8 | Powder · Pristine Control · Pristine Framework | Pristine ZIF-8 control/simulated reference in XRD, pore distribution and catalytic tests. | p004 · Figure caption · Figure 2d,f |