Michael Ko, Lukasz Mendecki and Katherine A. Mirica · ChemComm · 2018
Summarise fundamental and applied progress in layered conductive MOFs, especially synthetic modularity, electrical transport, device integration, and multifunctional applications.
The review’s argument is preserved as a navigable set of section summaries.
Reviews how conductivity can be engineered through carrier concentration and mobility, and classifies transport as hopping, through-space, through-bond and band transport.
Relevance: Core · 7875 · Principles of electrical conductivity in 2D MOFs · Fig. 2
Classifies integration routes as stepwise or direct, covering drop-casting, mechanical compression/abrasion, templated growth and liquid-phase epitaxy.
Relevance: Core · 7877 · Methods of integration of 2D MOFs into electronic devices · Fig. 5
Discusses FET demonstrations and charge-carrier studies, highlighting porosity as a distinguishing feature for analyte-accessible electronics.
Relevance: Supporting · 7882 · MOF-based electronics · Fig. 8
Reviews 2D conductive MOFs as HER, ORR and OER electrocatalysts, while emphasising stability, delamination and mechanistic gaps.
Relevance: Supporting · 7883 · Energy conversion: H2/O2 evolution · Fig. 9
Frames 2D MOFs against graphene and other 2D materials, emphasising layered structure, high surface area, porosity and bottom-up modularity.
Relevance: Core · 7874 · MOFs as a modular class of 2D nanomaterials · Fig. 1
Defines the review as covering layered conductive MOFs, electrical properties, integration into devices and applications in sensing, electrocatalysis, energy storage and transducers.
Relevance: Core · 7874 · Scope of the review
Synthesises review-level evidence that 2D conductive MOFs support chemiresistive and potentiometric sensing through porosity, modular surface chemistry and electronic transduction.
Relevance: Core · 7880 · Electrically-transduced chemical sensing · Fig. 6; Fig. 7
Covers supercapacitor mechanisms, electrochemical ethylene capture/release and the review's final gap analysis for synthesis, structure-property knowledge and device interfaces.
Relevance: Core · 7888 · Conclusions and outlook · Fig. 10; Fig. 11
Connects metal nodes, ligand symmetry, heteroatoms, pore topology and stacking modes to conductive MOF structure and properties.
Relevance: Core · 7876 · Structural features and preparation strategies of 2D conductive MOFs · Fig. 3; Fig. 4
Classification systems are attributed to this review and are not treated as a global material registry.
The review places 2D MOFs within a broader 2D-material synthesis taxonomy, distinguishing atomic/molecular assembly from exfoliation, etching or intercalation routes.
Categories: Bottom-up assembly · Top-down exfoliation or separation
7874 · MOFs as a modular class of 2D nanomaterials
The review treats multifunctionality as arising from combining conductivity with porosity, catalytically active sites and modular host-guest chemistry.
Categories: Chemical sensing · Field-effect transistors · Energy conversion · Energy storage · Catalysis · Electrochemical capture/release
7877 · Structural features and preparation strategies of 2D conductive MOFs · Table 1
Conductivity is framed as a joint problem of generating carriers and preserving mobility by reducing structural and interfacial disorder.
Categories: Thermal or photo-excitation · Doping · Hole or electron injection · Lower defect density · Fewer charge traps · Fewer grain boundaries
7874 · Principles of electrical conductivity in 2D MOFs
The review separates broad but less controlled stepwise methods from direct growth and layer-by-layer approaches with better orientation/thickness control.
Categories: Drop-casting · Mechanical compression/abrasion · Templated bottom-up self-assembly · Liquid-phase epitaxy/layer-by-layer growth
7879 · Methods of integration of 2D MOFs into electronic devices · Fig. 5
Figure 3 links ligand cores to non-planar, non-porous/hexagonal, hexagonal-pore and square-pore MOF topologies.
Categories: Benzoquinone · Benzene · Triphenylene · Phthalocyanine
7876 · Structural features and preparation strategies of 2D conductive MOFs · Fig. 3
The review uses triphenylene ligands to show that heteroatom identity and metal salt jointly control stack registry and pore architecture.
Categories: Slipped parallel · Eclipsed · Staggered · Interpolated layer · AAAA pattern · ABAB pattern
7877 · Structural features and preparation strategies of 2D conductive MOFs · Fig. 4
The review maps conductive MOF behaviour onto established organic and inorganic semiconductor transport concepts and uses Fig. 2 to illustrate three local transport modes.
Categories: Hopping · Through-space · Through-bond · Band transport
7875 · Principles of electrical conductivity in 2D MOFs · Fig. 2
Review-defined families retain their representative materials and conduction descriptions.
Sulphur-rich triphenylene or benzenehexathiolate coordination polymers/MOFs incorporating metal bis(dithiolene)-like motifs.
Conduction: Conduction is discussed with redox-active sulphur ligands, metal-centred redox and strong delocalisation; used heavily in HER and electrochemical capture examples.
Representative materials: Co3HTTP2 · Ni3HTTP2 · Cu3HTTP2 · CoBHT · NiBHT · FeBHT · Cu-BHT
Nodes / linkers: Co · Ni · Cu · Fe · HTTP · BHT · THT
7887 · Electrochemically-controlled capture and release · Fig. 11; Table 1
Hexaaminobenzene or hexaiminobenzene-derived M3HAB2 and M3HIB2 frameworks used for high conductivity, FETs and pseudocapacitive storage.
Conduction: The review highlights gate-dependent conductance, high pellet conductivity and pseudocapacitive redox behaviour depending on material and device form.
Representative materials: Ni3HAB2 · Cu3HAB2 · Ni3HIB2 · Cu3HIB2 · M-HIB
Nodes / linkers: Ni · Cu · Co · HAB · HIB
7883 · MOF-based electronics · Fig. 8; Table 1
Square-pore phthalocyanine-linked MOFs, represented in the review by Ni-Pc MOF films.
Conduction: Review reports approximate room-temperature conductivity and OER performance for directly grown Ni-Pc films.
Representative materials: NiPc-MOF · Ni-Pc MOF
Nodes / linkers: Ni · Phthalocyanine
7876 · Structural features and preparation strategies of 2D conductive MOFs · Fig. 3
Originally insulating or weakly conducting MOFs made conductive by post-synthetic incorporation of redox-active guests such as TCNQ.
Conduction: Conductivity enhancement is attributed to host-guest charge-transfer bridges but carries porosity, stability and phase-separation caveats.
Representative materials: TCNQ@Cu3(BTC)2
Nodes / linkers: Cu · BTC · TCNQ guest
7875 · Principles of electrical conductivity in 2D MOFs
Extended triphenylene-based frameworks built from oxygen or imine/nitrogen-substituted hexatopic ligands coordinated to transition-metal nodes.
Conduction: Review attributes high conductivity to pi-stacked, extended pi-conjugated networks and metal-linker orbital coupling, while noting defects and interfaces can limit experiment.
Representative materials: Cu3HHTP2 · Ni3HHTP2 · Cu3HITP2 · Ni3HITP2 · Co3HHTP2
Nodes / linkers: Cu · Ni · Co · HHTP · HITP
7876 · Principles of electrical conductivity in 2D MOFs · Fig. 4; Table 1
Review-level synthesis principles remain separate from primary-study recipes.
Pre-synthesised MOF powder is dispersed and deposited on a device substrate as a film or coating.
Claimed effects: Rapid, broadly applicable route for proof-of-concept chemiresistors, potentiometric electrodes and electrochemical capture devices.
Controlling variables: Dispersant · Sonication · Suspension stability · Substrate adhesion · Film homogeneity
Representative materials: Cu3HITP2 · Cu3HHTP2 · M3HTTP2
Caveat: Can introduce aggregation, structural defects, non-uniform thickness and weak mechanical stability.
7878 · Drop-casting · Fig. 5A
External redox-active guests are introduced into a MOF to bridge building blocks and promote host-guest charge transfer.
Claimed effects: Can enhance conductivity in otherwise insulating MOFs and served as an early conductivity route.
Controlling variables: Guest molecule identity · Host pore accessibility · Guest loading · Thermal and phase stability
Representative materials: TCNQ-doped Cu3(BTC)2
Caveat: May reduce surface area, porosity and pore volume, and can phase-separate or undermine monolayer control.
7875 · Principles of electrical conductivity in 2D MOFs
Use planar, conjugated and redox-active linkers with metal nodes that support orbital overlap and charge delocalisation.
Claimed effects: Enables intrinsically conductive, molecularly homogeneous MOFs that avoid the penalties of pore-filling dopants.
Controlling variables: Planarity · Pi conjugation · Metal d orbital coupling · Redox-active linker states · Interlayer spacing
Representative materials: Ni3HITP2 · Cu3HITP2 · Cu3HHTP2
Caveat: Specific charge-transport mechanisms in 2D porous MOF networks remain incompletely understood.
7875 · Principles of electrical conductivity in 2D MOFs
Sequential or epitaxial deposition forms stable, homogeneous MOF layers with controlled thickness and orientation on functionalised substrates.
Claimed effects: Most precise integration route in this review for controlling thickness, orientation and structure-property investigations.
Controlling variables: Surface functional groups · Sequential exposure cycles · Substrate crystal orientation · Automation · Surface-coordination chemistry
Representative materials: Cu3HHTP2
Caveat: Requires substrate- and MOF-specific tailoring; sequential deposition can be lengthy and repetitive.
7880 · Liquid-phase epitaxy/layer-by-layer growth · Fig. 5D
MOF powders are compressed into a pellet or pencil-like form and probed directly or abraded onto substrates.
Claimed effects: Solvent-free and compatible with rapid prototyping where solution processing is unsuitable.
Controlling variables: Compression force · Pellet integrity · Solvent avoidance · Device geometry · Porosity retention
Representative materials: Cu3HHTP2 · Cu3HITP2 · Ni3HITP2 · MOF/graphite blends
Caveat: High mechanical force may induce defects, diminish crystallinity and porosity, and reduce device performance.
7879 · Mechanical compression and abrasion · Fig. 5B
Conventional MOF synthesis by combining metal salts and organic linkers in solvent and heating to self-assemble layered frameworks.
Claimed effects: Provides broad access to structurally diverse 2D conductive MOFs, but morphology/orientation control remains limited for many bulk materials.
Controlling variables: Metal salt identity · Organic linker symmetry · Crosslinking heteroatom · Solvent and heating conditions
Representative materials: Cu3HHTP2 · Ni3HITP2 · Co3HHTP2
Caveat: Review stresses that knowledge is still dominated by powders or thin films with limited control over crystallite orientation.
7876 · Structural features and preparation strategies of 2D conductive MOFs
MOFs are grown directly on targeted substrates to integrate material formation and device fabrication.
Claimed effects: Can generate conformal, high-porosity device coatings and reduce post-synthetic processing.
Controlling variables: MOF nucleation sites · Substrate compatibility · Adhesion in solution · Synthesis temperature · Solvent compatibility
Representative materials: Ni3HHTP2 · Ni3HITP2 · M3HHTP2
Caveat: Best suited to MOF/substrate combinations that tolerate synthesis conditions and provide good adhesion.
7879 · Templated bottom-up self-assembly · Fig. 5C
These are the review authors’ synthesis, not newly measured results.
The review reduces conductive-MOF design to increasing charge-carrier concentration while preserving mobility through low defect, trap and grain-boundary density.
Evidence basis: multi_reference
Caveat: The principle is general solid-state transport reasoning applied to MOFs.
7874 · Principles of electrical conductivity in 2D MOFs
Perpendicular grain boundaries, strike-slip faults and layer-layer displacements are highlighted as likely transport barriers in real 2D MOF samples.
Evidence basis: single_reference
Caveat: The defect explanation is plausible but requires material-specific experimental verification.
7876 · Principles of electrical conductivity in 2D MOFs
Drop-casting is useful for rapid proof-of-concept devices but limits precise structure-property analysis because films can be non-uniform and weakly adhered.
Evidence basis: multi_reference
Caveat: Strategic process development can partly mitigate these issues.
7878 · Drop-casting
For electrocatalysis, the review identifies structural tunability, permanent porosity, conductivity, possible hydrolytic stability and guest loading as advantages of 2D conductive MOFs.
Evidence basis: multi_reference
Caveat: The same section later emphasises stability and deposition limitations.
7883 · Energy conversion: H2/O2 evolution
MOF electrocatalysts face major aqueous stability and device-contact challenges under strongly reductive or oxidising potentials.
Evidence basis: multi_reference
Caveat: This is central for Chapter 1 caveats on translating conductivity into electrochemical operation.
7885 · Energy conversion: H2/O2 evolution
The review uses electrochemical ethylene capture/release to illustrate how conductive MOFs can bridge homogeneous redox chemistry and heterogeneous porous materials.
Evidence basis: multi_reference
Caveat: The review notes the ethylene-binding mechanism still requires detailed computational and experimental investigation.
7887 · Electrochemically-controlled capture and release · Fig. 11
The review frames 2D conductive MOFs as promising supercapacitor electrodes because conductivity, surface area and modular redox sites can support EDLC and pseudocapacitive charge storage.
Evidence basis: multi_reference
Caveat: Device fabrication can delaminate films or collapse porosity when compressed.
7886 · Energy storage · Fig. 10
Porosity distinguishes 2D MOF FETs from many other 2D materials by potentially extending analyte-accessible electronics that require high surface area and penetrability.
Evidence basis: multi_reference
Caveat: Structural fidelity, fabrication and epitaxial orientation remain limiting factors.
7883 · MOF-based electronics · Fig. 8
Robust device integration is presented as a critical step for accessing and optimising electronic properties, not merely a post-processing detail.
Evidence basis: review_reasoning
Caveat: Claims compare strategies conceptually rather than through a single controlled meta-analysis.
7877 · Methods of integration of 2D MOFs into electronic devices · Fig. 5
Guest-doping routes can introduce conductivity but are less attractive for precise 2D MOF structure-property work because guests can occlude pores, reduce porosity and phase-separate.
Evidence basis: multi_reference
Caveat: Doping remains historically important and can be effective in selected host systems.
7875 · Principles of electrical conductivity in 2D MOFs
Layer-by-layer liquid-phase epitaxy is treated as the most precise available device-integration route for controlling 2D MOF orientation, morphology and thickness.
Evidence basis: single_reference
Caveat: The method needs substrate-specific tailoring and may require automation.
7880 · Liquid-phase epitaxy/layer-by-layer growth
Ligand substitution, heteroatom identity and metal choice can strongly alter stacking mode, pore diameter and structural defects in layered conductive MOFs.
Evidence basis: multi_reference
Caveat: Most examples remain inferred from powders, films or limited single-crystal cases.
7876 · Structural features and preparation strategies of 2D conductive MOFs · Fig. 4
2D MOFs are framed as a distinct class of functional 2D materials because bottom-up metal-linker self-assembly combines structural modularity, permanent porosity and electronic functionality.
Evidence basis: multi_reference
Caveat: This is a review-level synthesis, not a single primary benchmark.
7874 · MOFs as a modular class of 2D nanomaterials
The review's outlook makes predictive structure-property design the overarching goal, requiring controlled synthesis, single-crystal characterisation, mechanistic understanding and better device interfaces.
Evidence basis: review_reasoning
Caveat: This is a secondary synthesis of multiple limitations rather than a benchmark.
7888 · Conclusions and outlook
Planar, extended 2D pi-conjugated and graphene-like MOFs are identified as among the most conductive known frameworks because in-plane transport is favoured by conjugation and pi-d orbital coupling.
Evidence basis: multi_reference
Caveat: High framework conductivity does not remove sensitivity to defects, interfaces and morphology.
7875 · Principles of electrical conductivity in 2D MOFs
The review states that host-guest interactions in 2D MOF sensors remain poorly characterised, so rational sensor design still lacks conclusive mechanistic evidence.
Evidence basis: multi_reference
Caveat: Several hypotheses exist, including charge transfer and hydrogen bonding.
7882 · Electrically-transduced chemical sensing
Chemiresistive selectivity can depend strongly on the metal node, as Cu3HITP2 responds to ammonia while isostructural Ni3HITP2 did not in the reviewed example.
Evidence basis: single_reference
Caveat: Mechanistic interpretation requires primary paper verification and broader analyte controls.
7880 · Electrically-transduced chemical sensing
The review cautions that precise structural and single-crystal conductivity information is scarce for 2D conductive MOFs.
Evidence basis: single_reference
Caveat: As of this 2018 review, the authors state only one single-crystal structure had been reported.
7877 · Structural features and preparation strategies of 2D conductive MOFs
Ni3HITP2 illustrates a theory-experiment tension: experiments suggest semiconducting behaviour while calculations can predict metallic behaviour depending on bulk or sheet model assumptions.
Evidence basis: multi_reference
Caveat: The review attributes disagreement partly to transport barriers absent from idealised models.
7876 · Principles of electrical conductivity in 2D MOFs
Although hopping, through-space, through-bond and band descriptions are available, the specific mechanism in 2D porous MOF networks remains unresolved in many cases.
Evidence basis: multi_reference
Caveat: Different materials and device forms may sit in different transport regimes.
7875 · Principles of electrical conductivity in 2D MOFs · Fig. 2
Every row remains visibly secondary and links to a primary dossier only where the mapping is verified.
| Material | Property | Reported value | Context and quality | Primary evidence | Review source |
|---|---|---|---|---|---|
| SecondaryCoBHT | HER overpotential | 0.19 V | H2SO4, pH = 1.3, Table 1. Table · Exact Reported | No verified corpus mapping | 7878 · Table 1 · Table 1 |
| SecondaryCu-BHT | FET mobility | 116 cm2 V-1 s-1 | Field-effect transistor benchmark reported in Table 1. Table · Exact Reported | research_0006 | 7878 · Table 1 · Table 1 |
| SecondaryCu3HHTP2 | NH3 chemiresistor limit of detection | 0.5 ppm | Layer-by-layer liquid-phase epitaxial thin films; ammonia range 1-100 ppm. Table · Exact Reported | research_0115 | 7878 · Table 1 · Table 1 |
| SecondaryCu3HHTP2 | Gravimetric capacitance | 120 F g-1 | MOF nanowire capacitor, current density 0.5 A g-1; direct bottom-up integration on carbon nanowires. Text · Exact Reported | research_0026 | 7887 · Energy storage · Table 1 |
| SecondaryCu3HITP2 | NH3 chemiresistor limit of detection | 0.5 ppm | Room-temperature chemiresistive sensing; applied potential 100 mV; range 0.5-10 ppm. Text · Exact Reported | research_0002 | 7880 · Electrically-transduced chemical sensing · Table 1 |
| SecondaryNi3HIB2 and Cu3HIB2 | Pellet conductivity | >800 S cm-1 | Pressed pellets measured by van der Pauw method under vacuum. Text · Approximate | No verified corpus mapping | 7883 · MOF-based electronics · Fig. 8C |
| SecondaryM3HHTP2 MOF transducer | K+ potentiometric limit of detection | 6.31 +/- 0.01 x 10^-7 M | MOF-coated glassy carbon electrode with ion-selective membrane; M = Cu, Ni, Co. Text · Exact Reported | research_0842 | 7882 · Electrically-transduced chemical sensing · Fig. 7B |
| SecondaryM3HHTP2 MOF transducer | NO3- potentiometric limit of detection | 5.01 +/- 0.01 x 10^-7 M | MOF-coated glassy carbon electrode with ion-selective membrane; M = Cu, Ni, Co. Text · Exact Reported | research_0842 | 7882 · Electrically-transduced chemical sensing · Fig. 7B |
| SecondaryM3HHTP2/graphite blends | H2S array limit of detection | 35 ppm | Drawn chemiresistive arrays based on Fe, Co, Cu and Ni MOF/graphite blends; 5-80 ppm study range. Table · Exact Reported | research_0079 | 7878 · Table 1 · Table 1 |
| SecondaryNi-HAB | Gravimetric capacitance | 420 F g-1 | Free-standing electrode with binder and conductive additive; redox pseudocapacitance dominant. Text · Exact Reported | No verified corpus mapping | 7887 · Energy storage · Fig. 10B; Table 1 |
| SecondaryNiHAB | Volumetric capacitance | 760 F cm-3 | Compressed NiHAB pellet, 50 micrometre thick; 90% retention over 12000 cycles reported. Text · Exact Reported | No verified corpus mapping | 7887 · Energy storage · Table 1 |
| SecondaryNi3HITP2 | FET charge mobility | 48.6 cm2 V-1 s-1 | Porous FET, room temperature, p-type behaviour. Text · Exact Reported | research_0015 | 7883 · MOF-based electronics · Fig. 8A; Table 1 |
| SecondaryNi3HITP2 | ORR overpotential | 0.18 V | 0.10 M KOH, pH = 13.0, relative to Pt electrode; thin films directly grown on GCE. Text · Exact Reported | research_0003 | 7884 · Energy conversion: H2/O2 evolution · Fig. 9B; Table 1 |
| SecondaryNi3HITP2 | Gravimetric capacitance | 111 F g-1 | EDLC from compressed MOF powder pellet; discharge rate 0.05 A g-1; 10000-cycle retention reported. Text · Exact Reported | No verified corpus mapping | 7886 · Energy storage · Fig. 10A; Table 1 |
| SecondaryNi3HTTP2 | Electrochemical ethylene capture | 218.2 mmol g-1 | Voltage-actuated M3HTTP2 PCP capture/release device; Table 1 value. Table · Exact Reported | No verified corpus mapping | 7878 · Table 1 · Table 1 |
| SecondaryNi3HTTP2 | HER overpotential | 0.33 V | 0.5 M H2SO4, 10 mA cm-2. Text · Exact Reported | No verified corpus mapping | 7884 · Energy conversion: H2/O2 evolution |
| SecondaryNiAT | HER overpotential | 0.37 V at 10 mA cm-2 | pH = 1.3; Nafion-covered drop-cast GCE; onset 0.15 V also reported. Text · Exact Reported | No verified corpus mapping | 7884 · Energy conversion: H2/O2 evolution |
| SecondaryNi-Pc MOF | OER overpotential | 0.25 V | 1.0 M KOH; directly integrated onto FTO electrodes; 100-200 nm films. Text · Approximate | No verified corpus mapping | 7885 · Energy conversion: H2/O2 evolution · Fig. 9C |
| SecondaryNi3HHTP2/Ni3HITP2 SOFT textiles | H2S sensing limit of detection | 0.23 ppm | Self-organized frameworks on textiles; simultaneous detection, capture and filtering. Text · Exact Reported | No verified corpus mapping | 7881 · Electrically-transduced chemical sensing · Fig. 7A |
| SecondaryNi3HHTP2/Ni3HITP2 SOFT textiles | NO sensing limit of detection | 0.16 ppm | Self-organized frameworks on textiles; humidity 18% RH reported as largely non-disruptive. Text · Exact Reported | No verified corpus mapping | 7881 · Electrically-transduced chemical sensing · Fig. 7A |
Open questions are presented as review-author priorities, not conclusions from the primary database.
MOF decomposition, hydrolysis and delamination under electrochemical operation remain major obstacles.
Proposed direction: Develop robust deposition methods and more stable metal-ligand structures; pair experiments with mechanistic modelling.
7885 · Energy conversion: H2/O2 evolution
Capacitor implementation is limited by delamination, porosity collapse during compression, binders that diminish charge transport, and electrolyte corrosion.
Proposed direction: Use more robust integration approaches such as ink-jet printing, 3D printing and bond-strength engineering.
7887 · Energy storage
Top-down exfoliation has not yet been demonstrated for controlled preparation of conductive 2D MOF nanolayers.
Proposed direction: Advance exfoliation strategies to obtain ultra-thin conductive MOF nanomaterials with enhanced surface-to-volume ratio.
7879 · Drop-casting
FET applications require better structural fidelity, fabrication control and epitaxial orientation.
Proposed direction: Develop controlled film growth and transfer processes that preserve orientation and accessible porosity.
7883 · MOF-based electronics
Crystallite morphology and epitaxial orientation remain poorly controlled except in layer-by-layer strategies.
Proposed direction: Develop synthesis and integration methods that control distribution, thickness and orientation in device-relevant films.
7877 · Structural features and preparation strategies of 2D conductive MOFs
The ultimate goal is predictable and targeted structure-property design for conductive 2D MOFs.
Proposed direction: Combine controlled synthesis, single-crystal characterisation, computational modelling and surface spectroscopy.
7888 · Conclusions and outlook
Host-guest interactions between 2D conductive MOFs and analytes are not well characterised.
Proposed direction: Combine mechanistic spectroscopy, controlled analyte studies and computation to support rational molecular design for sensors.
7882 · Electrically-transduced chemical sensing
Single-crystal layered 2D MOFs and single-crystal conductivity measurements remain rare.
Proposed direction: Improve growth and characterisation of single crystals to anchor structure-property relationships.
7877 · Structural features and preparation strategies of 2D conductive MOFs
Specific charge-transport mechanisms in 2D porous MOF networks are not yet well understood.
Proposed direction: Use semiconductor and 3D MOF design principles as hypotheses, then resolve mechanisms with targeted electrical, spectroscopic and computational studies.
7875 · Principles of electrical conductivity in 2D MOFs
Mappings show which printed review references have a verified counterpart in the frozen primary corpus.
| Reference | Study | Role and context | Corpus mapping |
|---|---|---|---|
| Ref. 582017 | Title unavailable | conductive_mof_review · device_integration_contextReview-level citation used by Ko et al. for structural features, design principles and device integration context. | Unmapped |
| Ref. 632015 | Title unavailable | HER_benchmark · electrocatalysisCited for cobalt dithiolene MOFs grown on HOPG as HER catalysts and for integration/stability caveats. | Unmapped |
| Ref. 652017 | Title unavailable | supercapacitor_benchmark · transport_benchmarkPrimary study cited for the first MOF-only supercapacitor example based on Ni3HITP2 EDLC behaviour. | Unmapped |
| Ref. 672015 | Title unavailable | chemiresistor_benchmark · sensingCited for the first electronically transduced 2D layered MOF chemiresistor and Cu3HITP2 ammonia response. | research_0002 |
| Ref. 682016 | Title unavailable | direct_growth · chemiresistor_benchmarkCited for direct assembly of conductive M3HHTP2 MOFs into graphitic-electrode device chips for gas sensing. | Unmapped |
| Ref. 692014 | Title unavailable | guest_doping · conductivity_benchmarkCited for TCNQ-induced conductivity increase in Cu3(BTC)2 as an early guest-doping route to conductive MOFs. | research_0088 |
| Ref. 702016 | Title unavailable | conductive_mof_design · transport_mechanismUsed across the review for conductivity-design concepts, transport modes and HITP stacking context. | Unmapped |
| Ref. 712012 | Theory of Charge Transport in Carbon Electronic Materials | charge_transport_backgroundGeneral charge-transport background source cited for carrier concentration and hopping transport context. | Unmapped |
| Ref. 922012 | Title unavailable | transport_mechanism · design_principlesCited for approaches applying semiconductor transport principles to MOF-based materials. | Unmapped |
| Ref. 1222014 | Title unavailable | Ni3HITP2_structure · transport_interpretationCited for early Ni3HITP2 work, semiconducting behaviour and stacking-model analysis. | Unmapped |
| Ref. 1232012 | Title unavailable | single_crystal_structure · stackingCited for the single-crystal structural example and ABAB stacking of a Co3HHTP2 MOF. | Unmapped |
| Ref. 1242017 | Title unavailable | conductivity_benchmark · electronic_structureCited for high pressed-pellet conductivities and anisotropic metallic/semiconducting electronic properties. | Unmapped |
| Ref. 1252017 | Title unavailable | temperature_dependent_transportCited for temperature-dependent conductance and complex scattering mechanisms in Co3HTTP2. | Unmapped |
| Ref. 1302017 | Title unavailable | chemiresistor_benchmark · mechanical_abrasionCited for rapid prototyping of MOF/graphite chemiresistive sensing arrays for NH3, H2S and NO. | research_0079 |
| Ref. 1312017 | Title unavailable | textile_sensor · sensing_benchmarkCited for conductive MOF textiles that detect, capture and filter NO and H2S. | Unmapped |
| Ref. 1332018 | Title unavailable | defect_transport · theory_experimentCited for transport barriers, band-structure modulation and defects in 2D conductive MOFs. | Unmapped |
| Ref. 1342015 | Title unavailable | computational_transportCited for calculations predicting metallic conductivity in multilayered materials and differing Ni/Cu sheet behaviour. | Unmapped |
| Ref. 1352017 | Title unavailable | solvothermal_synthesis_backgroundCited as general background for solvothermal MOF production. | Unmapped |
| Ref. 1392015 | Title unavailable | HER_benchmark · thin_filmCited for Langmuir-Blodgett Ni3HTTP2 single-layer sheets as HER electrocatalysts. | Unmapped |
| Ref. 1402014 | Title unavailable | stacking · triphenylene_httpCited for changed stacking modes when triphenylene heteroatom/metal combinations vary. | Unmapped |
| Ref. 1412018 | Title unavailable | OER_benchmark · phthalocyanine_mofCited for directly grown nickel phthalocyanine MOF films as OER catalysts. | Unmapped |
| Ref. 1432017 | Title unavailable | layer_by_layer · chemiresistor_benchmarkCited for layer-by-layer liquid-phase epitaxial Cu3HHTP2 films and ammonia sensing. | research_0115 |
| Ref. 1442015 | Title unavailable | cross_reactive_sensor · mechanical_abrasionCited for cross-reactive MOF chemiresistor arrays and VOC differentiation. | research_0145 |
| Ref. 1452018 | 10.1021/acsami.8b0395610.1021/acsami.8b03956 | potentiometric_sensor · ion_to_electron_transducerCited for M3HHTP2 MOFs as ion-to-electron transducers in potentiometric K+ and NO3- detection. | research_0842 |
| Ref. 1462018 | Title unavailable | HER_benchmark · metal_dependenceCited for coordinated-metal effects and film-thickness dependence in BHT HER catalysis. | Unmapped |
| Ref. 1482017 | Title unavailable | HER_benchmark · redox_switchingCited for reversible NiAT/NiIT redox interconversion, conductivity change and HER performance. | Unmapped |
| Ref. 1492016 | Title unavailable | ORR_benchmark · direct_growthCited for Ni3HITP2 thin films in ORR and binder-free direct growth on glassy carbon electrodes. | research_0003 |
| Ref. 1502017 | Title unavailable | supercapacitor_benchmark · direct_growthCited for direct bottom-up integration of Cu3HHTP2 on carbon nanowires for supercapacitors. | research_0026 |
| Ref. 1512018 | Title unavailable | supercapacitor_benchmark · pseudocapacitanceCited for free-standing HAB electrodes, high gravimetric/volumetric capacitance and redox pseudocapacitance. | Unmapped |
| Ref. 1522017 | Title unavailable | electrochemical_capture · device_integrationCited for voltage-actuated reversible ethylene capture/release in M3HTTP2 PCP/MOF-like devices. | Unmapped |
| Ref. 1532017 | Title unavailable | FET_benchmark · mobilityCited for porous Ni3HITP2 FETs, p-type behaviour and mobility benchmark. | research_0015 |
| Ref. 1542015 | Title unavailable | FET_benchmark · mobilityCited in Table 1 for Cu-BHT field-effect transistor mobility and conductivity. | research_0006 |
| Ref. 1782017 | Title unavailable | electrocatalysis_review · stability_caveatCited for electrochemical transformation context and caveats about MOF stability/delamination. | Unmapped |
| Ref. 1792017 | Title unavailable | electrocatalysis_review · stability_caveatCited with Ref. 178 for hydrolysis, decomposition and delamination concerns under electrochemical operation. | Unmapped |
| Ref. 1822008 | Title unavailable | supercapacitor_backgroundBackground citation for EDLC and pseudocapacitor charge-storage mechanisms. | Unmapped |
| Ref. 1832017 | Title unavailable | mof_catalysis_reviewCited for MOFs bridging homogeneous and heterogeneous catalysis. | Unmapped |
| Ref. 1842017 | Title unavailable | mof_catalysis_contextCited for modular MOFs preserving molecular catalytic units in a heterogeneous framework. | Unmapped |