Primary study2023
Experimental manifestation of redox-conductivity in metal-organic frameworks and its implication for semiconductor/insulator switching
Li J., Kumar A., Johnson B.A. et al. · Nature Communications · 2023
Reported here: UU-100(Co)
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UU-100(Co)
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2primary papers
2material records
5linked samples
15linked measurements
70linked results
2019–2023publication span
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Electrical Transport2 papers2 measurements · 7 resultsMicroscopy Morphology2 papers2 measurements · 7 resultsDiffraction Structure1 paper3 measurements · 22 resultsElectrochemistry Application1 paper6 measurements · 26 resultsPorosity1 paper1 measurement · 5 resultsSpectroscopy1 paper1 measurement · 3 results
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Primary study2019
Electrocatalytic Hydrogen Evolution from a Cobaloxime-Based Metal-Organic Framework Thin Film
Roy S., Huang Z., Bhunia A. et al. · Journal of the American Chemical Society · 2019
Reported here: UU-100(Co)
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| Paper and reported name | Formula and components | Structure context | Source |
|---|---|---|---|
| UU-100(Co)2023 · Experimental manifestation of redox-conductivity in metal-organic frameworks and its implication for semiconductor/insulator switching | UU-100(Co); Zr-based framework with cobaloxime redox-active linkerZr clusters and cobaloxime Co redox centres in the linker · Cobaloxime-based redox-active linker | 3D · PristineTetragonal unit cell with a = b = 27.3 A, c = 19.6 A, and P4/mbm space group. | 6 · Generality of the redox conductivity with other MOFs · Fig. 4d-f |
| UU-100(Co)2019 · Electrocatalytic Hydrogen Evolution from a Cobaloxime-Based Metal-Organic Framework Thin Film | [Zr6(mu3-O)8(OH)8(cobaloxime)2] model; SI table reports C32Cl2CoN4O18Zr3Hexanuclear zirconium-oxo clusters, Zr6(mu3-O)8(OH)8 · Cobaloxime metallolinker [Co(dcpgH)(dcpgH2)]Cl2 or solvent/chloride-exchanged cobaloxime linker | 3D · Pristine3D tetragonal MOF, likely P4/mbm, determined by cRED/Pawley refinement; rectangular channels with elliptical pores. | 15943 · Results and Discussion · Figure 1; Figure 2 |