Beyond diffusion: ion and electron migration contribute to charge transport in redox-conducting metal-organic frameworks
Johnson B.A., Castner A.T., Agarwala H. et al. · Chemical Science · 2025
Reported here: Zn(NDI)
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2 papers
Johnson B.A., Castner A.T., Agarwala H. et al. · Chemical Science · 2025
Reported here: Zn(NDI)
Li J., Kumar A., Ott S. · Journal of the American Chemical Society · 2024
Reported here: Zn(NDI)
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| Paper and reported name | Formula and components | Structure context | Source |
|---|---|---|---|
| Zn(NDI)2025 · Beyond diffusion: ion and electron migration contribute to charge transport in redox-conducting metal-organic frameworks | Zn(NDI)tetrahedral Zn nodes · naphthalenediimide dipyrazolate linker (NDI) | 3D · PristineZn-based redox-conducting MOF with ca. 16 A wide 1D channels; thin films on FTO assigned by matching PXRD peaks and SEM morphology. | p003 / journal page 5216 · Results and discussion · Fig. 1c |
| Zn(NDI)2024 · Diffusional Electron Transport Coupled to Thermodynamically Driven Electron Transfers in Redox-Conductive Multivariate Metal-Organic Frameworks | Zn(NDI)Infinite chains of tetrahedral Zn2+ ions bridged by pyrazolate head groups. · NDI = naphthalene diimide bis-pyrazolate | 3D · PristineCommon monoclinic MOF crystal structure; preferred thin-film orientation with c-axis parallel to conductive FTO; two prominent (110) and (220) diffraction peaks. | 12001-12002 · Results and Discussion · Figure 1; Figure S9 |